Coating system and method for e-coating and degasification of e-coat fluid during e-coat
US-2021172083-A1 · Jun 10, 2021 · US
US2017260641A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2017260641-A1 |
| Application number | US-201415529285-A |
| Country | US |
| Kind code | A1 |
| Filing date | Nov 25, 2014 |
| Priority date | Nov 25, 2014 |
| Publication date | Sep 14, 2017 |
| Grant date | — |
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An apparatus and method for uniform metallization on substrate are provided, achieving highly uniform metallic film deposition at a rate far greater than a conventional film growth rate in electrolyte solutions. The apparatus includes an immersion bath ( 3021 ), at least one set of electrode ( 3002 ), a substrate holder ( 3003 ), at least one ultra/mega sonic device ( 3004 ), a reflection plate ( 3005 ), and a rotating actuator ( 3030 ). The immersion bath contains at least one metal salt electrolyte ( 3020 ). The at least one set of electrode ( 3002 ) connects to an independent power supply. The substrate holder ( 3003 ) holds at least one substrate and electrically connects with a conductive side of the substrate. The conductive side of the substrate is exposed to face the electrode. The at least one ultra/mega sonic device ( 3004 ) and the reflection plate ( 3005 ) are disposed parallel for generating ultra/mega sonic standing wave in the immersion bath. The rotating actuator ( 3030 ) rotates the substrate holder ( 3003 ) along its axis in the standing wave field, so as to result in a uniform overall power intensity distribution across the substrate in an accumulated time.
Opening claim text (preview).
1 . An apparatus for uniform metallization on substrate comprising: an immersion bath containing at least one metal salt electrolyte; at least one set of electrode connecting to an independent power supply; a substrate holder holding at least one substrate and electrically connecting with a conductive side of the substrate, the conductive side of the substrate exposed to face the electrode; at least one ultra/mega sonic device and a reflection plate disposed parallel for generating ultra/mega sonic standing wave in the immersion bath; and a rotating actuator rotating the substrate holder along its axis in the standing wave field, so as to result in a uniform overall power intensity distribution across the substrate in an accumulated time. 2 . The apparatus of claim 1 , further comprising a horizontal actuator oscillating the substrate holder along propagation direction of the ultra/mega sonic standing wave. 3 . The apparatus of claim 2 , wherein the amplitude of the substrate oscillation equals to N · λ 4 , N = 1 , 2 , 3 … where λ is the wavelength of the ultra/mega sonic standing wave and N is an integer. 4 . The apparatus of claim 1 , further comprising a horizontal actuator oscillating the substrate holder along a direction tilted an angle θ relative to normal direction of propagation direction of the ultra/mega sonic standing wave. 5 . The apparatus of claim 4 , wherein the amplitude of the substrate oscillation equals to N · λ 4 sin θ , N = 1 , 2 , 3 … where λ is the wavelength of the ultra/mega sonic standing wave and N is an integer, θ is the angle between the substrate oscillation direction and the normal direction of propagation direction of the ultra/mega sonic standing wave. 6 . The apparatus of claim 4 , wherein the θ is 0-45 degrees. 7 . The apparatus of claim 1 , further comprising a vertical actuator moving the substrate holder up and down to load or unload the substrate into or out of the immersion bath. 8 . The apparatus of claim 1 , further comprising a vertical actuator oscillating the substrate holder along a direction that an angle θ is formed between the substrate holder oscillation direction and normal direction of propagation direction of the ultra/mega sonic standing wave. 9 . The apparatus of claim 8 , wherein the amplitude of the substrate oscillation equals to N · λ 4 sin θ , N = 1 , 2 , 3 … where λ is the wavelength of the ultra/mega sonic standing wave and N is an integer, θ is the angle between the substrate oscillation direction and the normal direction of propagation direction of the ultra/mega sonic standing wave. 10 . The apparatus of claim 8 , wherein the vertical actuator moves the substrate holder up and down to load or unload the substrate into or out of the immersion bath. 11 . The apparatus of claim 8 , wherein the vertical actuator oscillates the substrate holder along the direction perpendicular to the horizontal plane. 12 . The apparatus of claim 8 , wherein the vertical actuator oscillates the substrate holder along the direction tilted an angle relative to the normal direction of the horizontal plane. 13 . The apparatus of claim 12 , wherein the substrate and the electrode are set with a tilted angle relative to the horizontal plane. 14 . The apparatus of claim 1 , wherein each set of electrode includes one piece of electrode or more pieces of electrodes with independent power control. 15 . The apparatus of claim 1 , further comprising at least one layer of permeable membrane being set between the substrate and the electrode. 16 . The apparatus of claim 1 , wherein the rotation speed of the rotating actuator is in the range of 10 to 100 rpm. 17 . The apparatus of claim 1 , wherein the ultra/mega sonic device and the reflection plate are mounted on opposite sidewalls of the immersion bath and tilt an angle θ relative to the substrate oscillation direction, and the substrate is set parallel to the horizontal plane, the substrate oscillation direction is perpendicular to the horizontal plane. 18 . The apparatus of claim 1 , wherein the ultra/mega sonic device and the reflection plate are mounted on opposite sidewalls of the immersion bath and perpendicular to the horizontal plane, the substrate and the electrode are set with a tilted angle relative to the horizontal plane, the substrate is oscillated along a direction tilted the angle relative to the normal direction of the horizontal plane. 19 . The apparatus of claim 1 , further comprising an adjusting mechanism for adjusting the surface of the reflection plate to be parallel to the surface of the ultra/mega sonic device. 20 . The apparatus of claim 19 , wherein the adjusting mechanism includes an oscillating actuator for oscillating the reflection plate along propagation direction of the ultra/mega sonic standing wave, the oscillation amplitude is equal to N times of half wavelength of the ultra/mega sonic standing wave, N is an integer number from 1 to 10. 21 . The apparatus of claim 20 , wherein the frequency of the oscillating actuator is 1 to 10 HZ. 22 . An apparatus for uniform metallization on substrate comprising: an immersion bath containing at least one metal salt electrolyte; at least one set of electrode connecting to an independent power supply; a substrate holder holding at least one substrate and electrically connecting with a conductive side of the substrate,
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