Cathode system for electrodeposition of metals on microspheres

Patent metadata

Field	Value
Publication number	US-10844507-B2
Application number	US-201815965317-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Jun 21, 2017
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

The present disclosure relates to an apparatus for electroplating an element. The apparatus may comprise a cathode cage assembly. The cathode cage assembly may include a cage member and at least one electrically conductive wire extending along at least a portion of the cage member. The wire may be arranged to form at least one volume within the cage member for retaining an element within the cage member. The cage member and the wire permit a degree of movement of the element during an electroplating process while retaining the element within the volume.

First claim

What is claimed is:

1. An apparatus for electroplating an element, the apparatus comprising:
a cathode cage assembly, the cage assembly including:
a cage member;
a plurality of wires, with least one of the wires being an electrically conductive wire configured to receive an electrical current during an electroplating operation, the wires extending along at least a portion of the cage member, the wires being arranged to form at least one volume within the cage member for retaining an element within the cage member while permitting rotation of the element in random directions; and
wherein the cage member and the wires permit random rotational movement of the element during an electroplating process while still retaining the element in electrical contact with the at least one wire while positioned within the volume.

2. The apparatus of claim 1 , wherein the wires extend parallel to a length of the cage member.

3. The apparatus of claim 1 , wherein the wires extend perpendicular to a length of the cage member.

4. The apparatus of claim 1 , wherein the cage member comprises a non-electrically conductive material.

5. The apparatus of claim 1 , wherein the cage member is formed from at least one of plastic material or ceramic material.

6. The apparatus of claim 1 , wherein the cage member includes:
a plurality of parallel extending, elongated frame sections;
a plurality of ribs arranged non-parallel to the elongated frame sections;
a top section at one end of the frame sections;
a bottom wall at a second end of the frame sections; and
wherein the wires, the elongated frame sections and the ribs define a plurality of adjacent, but spaced apart, internal volumes for containing the element and at least one additional element within separate volumes.

7. The apparatus of claim 1 , further comprising an anode shaped to substantially surround a major portion of the cage member.

8. The apparatus of claim 7 , wherein the cage member has a circumferential shape and the anode has an annular configuration.

9. The apparatus of claim 7 , further comprising a DC power source for applying a DC voltage across the wire and the anode.

10. The apparatus of claim 9 , further comprising:
a reservoir;
an electrolyte bath contained by the reservoir, wherein the cage member and the element are disposed in the electrolyte bath; and
a sonicator for applying ultrasonic energy to the electrolyte bath.

11. An apparatus for electroplating an element, the apparatus comprising:
a cathode cage assembly, the cage assembly including:
a tubular cage member;
a plurality of lengths of spaced apart, electrically conductive wires extending parallel to one another, and extend through portions of the tubular cage member to form a plurality of adjacent but separate volumes within the cage member, the separate volumes each retaining a respective, separate element therein; and
wherein the separate volumes permit a degree of movement of the element, relative to the cage member and to the electrically conductive wires, during an electroplating process while retaining the elements within their respective said volumes.

12. The apparatus of claim 11 , wherein the plurality of conductive wires are arranged to run parallel to a length of the cage member.

13. The apparatus of claim 11 , wherein the plurality of conductive wires are arranged to run perpendicular to a length of the cage member.

14. The apparatus of claim 11 , wherein the plurality of lengths of the electrically conductive wire are formed from a single length of wire which is looped a plurality of times at two ends of the cage member.

15. The apparatus of claim 11 , wherein the plurality of lengths of the electrically conductive wire are formed from independent sections of wire and tied together at one end.

16. The apparatus of claim 11 , further comprising:
a reservoir;
an electrolyte bath contained in the reservoir, the cage member being at least partially submerged in the electrolyte bath; and
a sonicator for applying ultrasonic energy to the electrolyte bath.

17. A method for forming a cage assembly for use in electroplating spherical mandrels with a uniform metallic coating, the method comprising:
providing a cage member formed from an electrically non-conductive material;
securing a plurality of electrically conductive wires to the cage member in a spaced apart configuration, wherein the electrically conductive wires are arranged generally parallel to one another such the electrically conductive wires and portions of the cage member cooperate to form a plurality of adjacent but separate volumes;
each said separate volume further being dimensioned to capture a respective one of the spherical mandrels therein while permitting a degree of movement of the spherical mandrels during an electroplating operation.

18. The method of claim 17 , further comprising at least one of:
arranging the plurality of electrically conductive wires parallel to a length of the cage member; or
arranging the plurality of electrically conductive wires perpendicular to the cage member.

19. An apparatus for electroplating an element, the apparatus comprising:
a cathode cage assembly, the cage assembly including:
a cage member;
at least one electrically conductive wire extending along at least a portion of the cage member, the wire being arranged to form at least one volume within the cage member for retaining an element within the cage member;
wherein the cage member and the wire permit a degree of movement of the element during an electroplating process while retaining the element within the volume; and

wherein the cage member further includes:
a plurality of parallel extending, elongated frame sections;
a plurality of ribs arranged non-parallel to the elongated frame sections;
a top section at one end of the frame sections;
a bottom wall at a second end of the frame sections; and
wherein the wire, the elongated frame sections and the ribs define a plurality of adjacent, but spaced apart, internal volumes for containing the element and at least one additional element within separate volumes.

Assignees

• L Livermore Nat Security Llc

Inventors

• Bunn Thomas L
• Horwood Corie

Classifications

• C25D7/00

  Electroplating characterised by the article coated · CPC title

• C25D5/20 Primary

  Electroplating using ultrasonic waves · CPC title

• C25D17/12 Primary

  Shape or form (C25D17/14 takes precedence) · CPC title

• C25D17/08

  Supporting} racks {, i.e. not for suspending · CPC title

• C25D21/10

  Agitating of electrolytes; Moving of racks · CPC title