Method of electroless deposition of aluminum or aluminum alloy, an electroless plating composition, and an article including the same

Patent metadata

Field	Value
Publication number	US-9803283-B1
Application number	US-201414167733-A
Country	US
Kind code	B1
Filing date	Jan 29, 2014
Priority date	Oct 18, 2013
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

A method for electroless deposition of aluminum on a substrate includes: activating the substrate; providing an aluminum ionic liquid; adding a reducing agent and an additive to the aluminum ionic liquid to form an electroless plating composition, wherein the additive may include a catalyst, an alloying element, or a combination thereof; and immersing the substrate in the electroless plating composition to have an aluminum layer deposited on the substrate. An article includes the electroless deposited aluminum layer.

First claim

What is claimed is:

1. A method for electroless deposition of aluminum on a substrate, the method comprising:
activating the substrate;
providing an aluminum ionic liquid;
adding a reducing agent and an additive to the aluminum ionic liquid to form an electroless plating composition, wherein the additive comprises a catalyst selected from the group consisting of TiCl 2 , TiCl 3 , TiCl 4 , ZrCl 4 , VCl 3 , NbCl 5 , CeCl 3 and combinations thereof; and
immersing the activated substrate in the electroless plating composition.

2. The method of claim 1 , wherein the reducing agent is selected from the group consisting of alkali metal hydrides, alkaline earth metal hydrides, alanate salts of alkali metal, alanate salts of alkaline earth metal, borohydride salts, hydrided alkyl-metal compounds, and a combination thereof.

3. The method of claim 2 , wherein the reducing agent is lithium hydride, di-isobutyl aluminum hydride, NaAlH 4 , LiBH 4 or NaBH 4 .

4. The method of claim 1 , wherein the aluminum ionic liquid comprises 1-ethyl-3-methylimidazolium chloride, N-alkylpyridinium halides, N-alkylimidazolium halides, N,N′-alkylimidazolium halides, N-alkylpyrazolium halides, N,N′-alkylpyrazolium halides, bis(trifluoromethylsulfonyl) amide, trispentafluoroethyl-trifluorophosphate, trifluoroacetate, trifluoromethylsulfonate, dicyanoamide, tricyanomethide, tetracyanoborate, tetraphenylborate, tris(trifluoromethylsulfonyl) methide, thiocyanate, or a combination thereof.

5. The method of claim 1 , wherein the activating of the substrate comprises:
degreasing the substrate;
etching the substrate; and
creating catalytic metal sites on the substrate for deposition.

6. The method of claim 5 , wherein the creating catalytic metal sites on the substrate for deposition comprises depositing iron, palladium, silver, gold, ruthenium, rhodium, osmium, iridium, platinum or combinations thereof on the substrate.

7. The method of claim 1 , wherein the substrate comprises glass, metal, metal oxide, ceramic, organic material, or polymer.

8. The method of claim 1 , wherein the aluminum is uniformly deposited as a layer on the substrate.

9. The method of claim 1 , further comprising adding particulates in the electroless plating composition prior to the immersing the substrate in the electroless plating composition, and the aluminum is deposited as a layer on the substrate with the particulates.

10. The method of claim 1 , wherein the additive further comprises an alloying element.

11. The method of claim 1 , wherein the catalyst is included at about 2 ppm to about 1 wt % based on a total weight of the electroless plating composition.

12. The method of claim 1 , wherein the catalyst is selected from the group consisting of TiCl 2 , TiCl 4 , ZrCl 4 , VCl 3 , NbCl 5 , CeCl 3 and combinations thereof.

Assignees

• Hrl Lab Llc

Inventors

• Martin John H
• Kolodziejska Joanna A
• Vajo John J
• Graetz Jason A
• Roper Christopher S

Classifications

• C23C18/1687 Primary

  with ionic liquid · CPC title

• C23C18/2086

  with use of organic or inorganic compounds other than metals, first · CPC title

• C23C18/31

  Coating with metals · CPC title

• C23C18/1844

  with use of organic or inorganic compounds other than metals, first · CPC title

• C23C18/1893

  with use of organic or inorganic compounds other than metals, first · CPC title