Metal-coated reactive powders and methods for making the same

Patent metadata

Field	Value
Publication number	US-11542605-B1
Application number	US-202016842883-A
Country	US
Kind code	B1
Filing date	Apr 8, 2020
Priority date	Sep 21, 2014
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

The disclosed process is capable of depositing thin layers of a wide variety of metals onto powders of magnesium, aluminum, and their alloys. A material is provided that comprises particles containing a reactive metal coated with a noble metal that has a less-negative standard reduction potential than the reactive metal. The coating has a thickness from 1 nanometer to 100 microns, for example. A method of forming an immersion deposit on a reactive metal comprises: combining a reactive metal, an ionic liquid, and a noble metal salt; depositing the noble metal on the reactive metal by a surface-displacement reaction, thereby generating the immersion deposit on the reactive metal; and removing the ionic liquid from the immersion deposit. The material may be present in an article or object (e.g., a sintered part) containing from 0.25 wt % to 100 wt % of a coated reactive metal as disclosed herein.

First claim

What is claimed is:

1. A method of forming an immersion deposit on a reactive metal, wherein said immersion deposit comprises one or more noble metals, said method comprising:
(a) obtaining a reactive metal, an ionic liquid, and one or more noble metal salts containing one or more noble metals, wherein said one or more noble metal salts are in a form of a solid, a liquid, or a gas;
(b) combining said reactive metal, said ionic liquid, and said one or more noble metal salts to form a reaction mixture, wherein at least one of said one or more noble metals has a higher standard reduction potential than said reactive metal;
(c) selecting effective reaction conditions to deposit said at least one of said one or more noble metals on said reactive metal by a surface-displacement reaction without hydrogen evolution, thereby generating said immersion deposit on said reactive metal; and
(d) removing said ionic liquid from said immersion deposit,
wherein at least one of said one or more noble metals is surface-reacted with hydrogen during step (c) to form a noble-metal hydride contained in said immersion deposit.

2. The method of claim 1 , wherein said immersion deposit has a thickness from 1 nanometer to 100 microns.

3. The method of claim 2 , wherein said immersion deposit has a thickness from 1 nanometer to 1 micron.

4. The method of claim 1 , wherein said immersion deposit has a thickness of a single atomic layer.

5. The method of claim 1 , wherein said immersion deposit on said reactive metal is in a form of a plurality of powder particles that are from 10 nanometers to 1 centimeter in average diameter.

6. The method of claim 1 , wherein said immersion deposit includes from 1 to 10 coating layers, and wherein each of said coating layers has a thickness from 1 nanometer to 20 microns.

7. The method of claim 6 , wherein said immersion deposit includes multiple coating layers containing noble metals that have increasing standard reduction potentials in a direction away from said reactive metal.

8. The method of claim 1 , wherein said reactive metal is selected from the group consisting of alkali metals, alkaline earth metals, aluminum, silicon, titanium, zirconium, hafnium, zinc, and combinations or alloys thereof.

9. The method of claim 8 , wherein said reactive metal is selected from aluminum, magnesium, or an alloy containing greater than 50 at % of aluminum and/or magnesium.

10. The method of claim 1 , wherein said one or more noble metals are selected from the group consisting of aluminum, zirconium, titanium, zinc, nickel, cobalt, copper, silver, gold, palladium, platinum, rhodium, molybdenum, uranium, niobium, tungsten, tin, lead, tantalum, chromium, iron, indium, rhenium, ruthenium, osmium, iridium, and combinations or alloys thereof.

11. The method of claim 1 , wherein said reactive metal has a standard reduction potential less than the standard reduction potential of a standard hydrogen electrode.

12. The method of claim 1 , wherein said immersion deposit further contains a salt, carbon, an organic additive, an inorganic additive, or a combination thereof.

13. The method of claim 1 , wherein said ionic liquid is selected from the group consisting of aluminum chloride, 1-ethyl-3-methylimidazolium chloride, N-alkylpyridinium halides, N-alkylimidazolium halides, N,N′-alkylimidazolium halides, N-alkylpyrazolium halides, N,N′-alkylpyrazolium halides, and combinations thereof.

14. The method of claim 1 , wherein said ionic liquid includes an anion selected from the group consisting of halides, bis(trifluoromethylsulfonyl) amide, tris(pentafluoroethyl)trifluorophosphate, trifluoroacetate, trifluoromethylsulfonate, dicyanoamide, tricyanomethide, tetracyanoborate, tetraphenylborate, tris(trifluoromethylsulfonyl)methide, thiocyanate, and combinations thereof.

15. The method of claim 1 , wherein said one or more noble metal salts are dissolved in a solvent prior to step (b).

16. The method of claim 1 , wherein step (d) utilizes a technique selected from the group consisting of filtering, decanting, washing, diluting, centrifuging, drying, and combinations thereof.

17. The method of claim 1 , wherein an oxide-removing ionic liquid is introduced to remove residual oxides from said reactive metal, and wherein said oxide-removing ionic liquid is different than said ionic liquid obtained in step (a).

18. The method of claim 17 , wherein said oxide-removing ionic liquid is removed by a technique selected from the group consisting of filtering, decanting, washing, diluting, centrifuging, drying, and combinations thereof.

19. The method of claim 1 , wherein said method does not employ an external electric field.

Assignees

• Hrl Lab Llc

Inventors

• Martin John H
• Gross Adam F

Classifications

• C23C18/1689

  After-treatment · CPC title

• C22C21/10

  with zinc as the next major constituent · CPC title

• C22C9/00

  Alloys based on copper · CPC title

• C23C18/1687

  with ionic liquid · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title