Methods and Apparatuses for Making Nanomaterials in Space

Patent metadata

Field	Value
Publication number	US-2023234856-A1
Application number	US-202318094494-A
Country	US
Kind code	A1
Filing date	Jan 9, 2023
Priority date	Jan 25, 2022
Publication date	Jul 27, 2023
Grant date	—

Abstract

Methods and apparatuses for making nanomaterials are disclosed. The methods involve passing one or more source materials through a high pressure and high temperature chamber with an open throat, and then allowing the reactants to expand into a lower pressure, lower temperature zone. The source material is non-stoichiometric and fuel-rich so that excess un-combusted primary source material can form the nanomaterials. In some cases, the apparatus may be in the form of a modified rocket engine. The methods may be used to make various materials including: carbon nanotubes, boron nitride nanomaterials, titanium dioxide, and any materials that are currently produced by flame synthesis, including but not limited to electrocatalysts. The methods may also be used to make nanomaterials outside the Earth's atmosphere. The methods can include making, coating, or repairing structures in space, such as antennae.

First claim

What is claimed is:

1 . A method of making nanomaterials in outer space, said method comprising:
a) introducing at least two materials into the chamber of an apparatus that is located beyond the Earth's atmosphere, wherein when the materials are in said chamber, they are at a first pressure and a first temperature, said first pressure and said first temperature being relatively high, said apparatus having a throat having a reduced size opening, said throat being downstream from said chamber, wherein said apparatus further comprises a reduced pressure and temperature zone downstream from said throat, said zone having an exit, wherein at least one of said materials comprises a primary source material for the nanomaterials to be formed; b) passing said materials into said throat; c) passing said materials into said reduced pressure and temperature zone wherein said materials expand at a lower pressure than said first pressure; d) forming nanomaterials in said apparatus; and e) collecting said nanomaterials at the exit from said zone.

2 . The method of claim 1 wherein the chamber is a combustion chamber.

3 . The method of claim 2 wherein the chamber and said reduced pressure and temperature zone are provided in the form of a rocket engine comprising a nozzle, wherein said reduced pressure and temperature zone is a nozzle.

4 . The method of claim 2 wherein at least one of said materials comprises a fuel and at least one of said materials comprises an oxidizer.

5 . The method of claim 4 wherein said primary source material comprises a carbon source, and said nanomaterials comprise carbon nanotubes.

6 . The method of claim 5 wherein the carbon source comprises a carbon-containing fuel, wherein the ratio of fuel and oxidizer is non-stoichiometric and fuel-rich so that when combusted, excess un-combusted carbon is created that will provide the primary source material for the nanomaterials.

7 . The method of claim 6 further comprising a step of introducing a catalyst or catalyst precursor into the chamber prior to step (b), and said carbon source and catalyst or catalyst precursor participate in a reaction.

8 . The method of claim 7 wherein the catalyst or catalyst precursor comprises a metal or an alloy of two or more metals.

9 . The method of claim 1 wherein said primary source material comprises a boron source, and said nanomaterials comprise boron nitride compounds.

10 . The method of claim 1 wherein said primary source material comprises a source of titanium, and said nanomaterials comprise titanium dioxide nanoparticles.

11 . The method of claim 4 wherein the fuel comprises a hydrocarbon, the oxidizer comprises one or more of the following: air or oxygen, and said nanomaterials formed comprise at least one of catalysts and electrocatalysts.

12 . A method according to claim 1 for making an antenna in space, wherein the step (e) of collecting said nanomaterials at the exit from said zone comprises: providing a frame for an antenna, directing the nanomaterials exiting from the zone onto said frame, and forming an antenna on said frame wherein the surface of said antenna at least partially comprises said nanomaterials.

13 . The method of claim 12 wherein said primary source material comprises a carbon source, and said nanomaterials comprise carbon nanotubes.

14 . A method according to claim 1 for repairing a structure in space, wherein the step (e) of collecting said nanomaterials at the exit from said zone comprises directing the nanomaterials exiting from the zone onto said structure to repair said structure.

Assignees

• Us Gov Air Force

Inventors

• Maruyama Benji

Classifications

• C01G23/07

  Producing by vapour phase processes, e.g. halide oxidation · CPC title

• H01Q1/368

  using carbon or carbon composite · CPC title

• C01B21/064

  with boron · CPC title

• C01B35/146 Primary

  Compounds containing boron and nitrogen, e.g. borazoles (ammonium tetrafluoborates C01B35/063; ammonium borates C01B35/12) · CPC title

• C01B32/162 Primary

  characterised by catalysts · CPC title