Beta-delithiated layered nickel oxide electrochemically active cathode material and a battery including said material

Patent metadata

Field	Value
Publication number	US-11799082-B2
Application number	US-202117393084-A
Country	US
Kind code	B2
Filing date	Aug 3, 2021
Priority date	Mar 28, 2014
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

The invention is directed towards an electrochemically active cathode material. The electrochemically active cathode includes beta-delithiated layered nickel oxide and an electrochemically active cathode material selected from the group consisting of manganese oxide, manganese dioxide, electrolytic manganese dioxide (EMD), chemical manganese dioxide (CMD), high power electrolytic manganese dioxide (HP EMD), lambda manganese dioxide, gamma manganese dioxide, beta manganese dioxide, and mixtures thereof. The beta-delithiated layered nickel oxide has an X-ray diffraction pattern. The X-ray diffraction pattern of the beta-delithiated layered nickel oxide includes a first peak from about 14.9°2θ to about 16.0°2θ; a second peak from about 21.3°2θ to about 22.7°2θ; a third peak from about 37.1°2θ to about 37.4°2θ; a fourth peak from about 43.2°2θ to about 44.0°2θ; a fifth peak from about 59.6°2θ to about 60.6°2θ; and a sixth peak from about 65.4°2θ to about 65.9°2θ.

First claim

The invention claimed is:

1. A battery comprising:
a cathode comprising an electrochemically active cathode material comprising a beta-delithiated layered nickel oxide, the beta-delithiated layered nickel oxide having an X-ray diffraction pattern comprising a peak from about 14.9° 2θ to about 16.0° 2θ and a peak from about 10.8° 2θ to about 12.0° 2θ;
an anode;
a separator between said cathode and said anode; and
an electrolyte.

2. The battery of claim 1 , wherein the cathode further comprises an additional electrochemically active cathode material selected from the group of manganese oxide, manganese dioxide, and mixtures thereof.

3. The battery of claim 1 , wherein the electrolyte comprises an aqueous electrolyte.

4. The battery of claim 1 , wherein the electrolyte comprises KOH.

5. The battery of claim 1 , wherein the anode comprises an electrochemically active anode material, the electrochemically active anode material selected from the group consisting of zinc, zinc oxide, zinc hydroxide, cadmium, iron, metal hydride, alloys thereof, and mixtures thereof.

6. The battery of claim 2 , wherein the additional electrochemically active cathode material is a manganese dioxide selected from the group consisting of electrolytic manganese dioxide (EMD), chemical manganese dioxide (CMD), high power electrolytic manganese dioxide (HP EMD), lambda manganese dioxide, gamma manganese dioxide, beta manganese dioxide, and a mixture thereof.

7. The battery of claim 6 , wherein the additional electrochemically active cathode material comprises electrolytic manganese dioxide (EMD).

8. The battery of claim 1 , the beta-delithiated layered nickel oxide comprising a chemical formula, the chemical formula comprising Li x A y Ni 1+a-z M 2 O 2 ·nH 2 O wherein:
x is from about 0.02 to about 0.20;
y is from about 0.03 to about 0.20;
a is from about 0 to about 0.2;
z is from about 0 to about 0.2;
n is from about 0 to about 1;
A comprises potassium, rubidium, cesium, or any combination thereof; and
M comprises an alkaline earth metal, a transition metal, a non-transition metal, or any combination thereof.

9. The battery of claim 8 , wherein A comprises potassium.

10. The battery of claim 8 , wherein a is from about 0.09 to about 0.20.

11. The battery of claim 8 , wherein a is from about 0.09 to about 0.10.

12. The battery of claim 8 , wherein the beta-delithiated layered nickel oxide comprises water such that n is greater than 0.

13. The battery of claim 1 , wherein the cathode further comprises a conductive additive.

14. The battery of claim 1 , wherein the battery further comprises:
a housing, the housing comprising an outer surface; and
a label, the label comprising a voltage tester;
wherein the label is affixed to the outer surface of the housing.

Assignees

• Duracell Us Operations Inc

Inventors

• Nelson Jennifer A
• Anglin David Lloyd
• Brundu Mariarosa
• Christian Paul Albert
• Richards Thomas C

Classifications

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/06 Primary

  Electrodes for primary cells · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/244

  Zinc electrodes · CPC title

• H01M4/32

  Nickel oxide or hydroxide electrodes · CPC title