Rheological methods for high block, tack and scrub resistant coating composition

Patent metadata

Field	Value
Publication number	US-11649368-B2
Application number	US-202117462226-A
Country	US
Kind code	B2
Filing date	Aug 31, 2021
Priority date	Dec 15, 2011
Publication date	May 16, 2023
Grant date	May 16, 2023

Abstract

The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance. Rheological techniques as described herein may be used to determine tack resistance, print resistance, and other performance characteristics.

First claim

What is claimed is:

1. A paint container containing a coating composition comprising:
an in-store tintable base paint formulation comprising:
a multistage latex polymer derived from monomers comprising a crosslinking component comprising diacetone acrylamide (DAAM);
wherein the multistage latex polymer comprises at least two stages with different Tg values, where the difference in Tg values is about 35° C. to 65° C.; and

wherein the base paint formulation contains less than 50 g/L VOC.

2. The paint container of claim 1 , wherein the paint container comprises a paint can.

3. The paint container of claim 1 , wherein the coating composition is not made using fluorosurfactant.

4. The paint container of claim 1 , wherein the coating composition has scrub resistance of at least 1000, storage modulus (E′) of about 1.0×10 6 to 1.0 to 10 7 Pa at 60° C. and 0.1 rad/s and tan (6) of less than about 0.2 at 60° C. and 0.1 rad/s.

5. The paint container of claim 1 , wherein the multistage latex polymer comprises:
at least a first stage with Tg of about 0 to 120° C.; and
at least a second stage with Tg of about −35 to 10° C.

6. The paint container of claim 1 , wherein the multistage latex polymer comprises:
at least a first stage with Tg of about −35 to 10° C.; and
at least a second stage with Tg of about 0 to 120° C.

7. The paint container of claim 1 , wherein the multistage latex polymer is derived from a multistage composition comprising:
at least a first stage derived from a first mixture of monomers including about 70 to 80 wt % methyl methacrylate, 20 to 30 wt % butyl acrylate, 1 to 2 wt % methacrylic acid, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture; and
at least a second stage derived from a second mixture of monomers including about 30 to 40 wt % methyl methacrylate, about 50 to 70 wt % butyl acrylate, about 1 to 2 wt % methacrylic acid, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the second mixture;
wherein the first mixture of monomers and/or the second mixture of monomers comprises the diacetone acrylamide.

8. The paint container of claim 1 , wherein the composition has E′ corresponding to a cheesecloth print resistance rating of at least 8 according to ASTM D2064-91.

9. The paint container of claim 1 , wherein the composition has E′ of about 1.0×10 6 to 1.0×10 8 Pa at 25° C. and 2.1 rad/s.

10. The paint container of claim 1 , wherein the composition has E′ corresponding to a perceived tack rating of about 1 to 2.

11. The paint container of claim 1 , wherein the difference in Tg values is at least about 50° C.

12. The paint container of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 4° C. or less.

13. The paint container of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 10° C. or less, in the absence of a separate coalescing agent.

14. The paint container of claim 1 , wherein the composition further includes no more than about 10% by weight coalescing agent, and is capable of forming a film at a temperature of 20° C. or less.

15. The paint container of claim 1 , wherein the composition exhibits a scrub resistance of at least 800.

16. The paint container of claim 15 , wherein the composition includes about 5 to 15 wt % of colorant.

17. The paint container of claim 1 , wherein the composition exhibits a scrub resistance of at least 1,100.

18. The paint container of claim 17 , wherein the composition is a deeply colored paint formulation.

19. The paint container of claim 17 , wherein the composition is a pigmented high gloss or semi-gloss paint.

20. The paint container of claim 1 , wherein the composition exhibits a 60° gloss rating of at least 80.

21. The paint container of claim 1 , wherein the composition includes about 8 to 12 wt % of colorant.

22. The paint container of claim 1 , wherein the composition is a pigmented high gloss or semi-gloss paint.

23. The paint container of claim 1 , wherein the multistage latex polymer is derived from a multistage composition comprising a ureido-functional monomer.

Assignees

• Swimc Llc

Inventors

• Ewert Tessie Rose
• Bell Tyler
• Sandoval Robert
• Hibben Mary Jane

Classifications

• C08L2201/54

  Aqueous solutions or dispersions · CPC title

• C08K5/02

  Halogenated hydrocarbons {(C08K5/0091 takes precedence)} · CPC title

• C09D113/02 Primary

  Latex · CPC title

• C09D5/08

  Anti-corrosive paints · CPC title

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title