High block, tack and scrub resistant coating composition

Patent metadata

Field	Value
Publication number	US-10273378-B2
Application number	US-201615012240-A
Country	US
Kind code	B2
Filing date	Feb 1, 2016
Priority date	Dec 15, 2011
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance.

First claim

What is claimed is:

1. A coating composition, comprising:
an in-store tintable liquid base paint formulation, comprising
a multistage latex polymer having at least a first stage with a Tg of greater than about 0 to 120° C. and at least a second stage with a Tg of −35 to 10° C.; and
up to about 0.5 wt % fluorosurfactant; and

about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 5 wt %; which colorants are added to the base paint formulation at a point-of-sale to achieve a desired color,

wherein the coating composition has scrub resistance of at least about 600 scrubs, and wherein the coating composition includes at least about 1 wt % ureido-functional monomer separately in each of the first stage and the second stage.

2. The composition of claim 1 , made by a process comprising the steps of:
providing a container with a quantity of the in-store tintable base paint formulation and headspace sufficient to receive a quantity of one or more low VOC colorants;
providing instructions for dispensing the low VOC colorant into the base paint formulation at a point-of-sale, and in a particular amount, to obtain a coating composition of a desired color.

3. The composition of claim 1 , wherein the multistage latex polymer is made by a method comprising:
preparing a first mixture of monomers for a first stage, the first mixture comprising about 70 to 80 wt % methyl methacrylate, 20 to 30 wt % butyl acrylate, 1 to 2 wt % methacrylic acid, about 1 wt % ureido-functional monomer, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture;
preparing a second mixture of monomers for a second stage, the second mixture comprising about 30 to 40 wt % methyl methacrylate, about 60 to 70 wt % butyl acrylate, about 1 to 2 wt % methacrylic acid, about 2 to 4 wt % diacetone acrylamide, and about 1 wt % ureido-functional monomers, based on the total weight of the monomers in the second mixture;
feeding the first mixture into a reactor vessel;
initiating a free radical polymerization of at least the first mixture; and
feeding the second mixture into the reactor vessel.

4. The composition of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 4° C. or less.

5. The composition of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 10° C. or less, in the absence of a separate coalescing agent.

6. The composition of claim 1 , wherein the composition further includes no more than about 10 wt % coalescing agent, and is capable of forming a film at a temperature of 20° C. or less.

7. The composition of claim 1 , wherein the difference in Tg of the first and second stage monomers is at least about 50° C.

8. The composition of claim 1 , wherein the composition exhibits block resistance rating of at least 6.

9. The composition of claim 1 , wherein the composition exhibits tack resistance force of less than 1.1 lbF.

10. The composition of claim 1 , wherein the colorant comprises:
a colorant component;
a surfactant package comprising at least one latex-compatible surfactant; and
a carrier,

wherein the colorant has less than about 20 g/L VOC.

11. The composition of claim 1 , wherein the composition comprises about 0.1 to 0.3 wt % fluorosurfactant, based on the total weight of the composition.

12. The composition of claim 1 , wherein the multistage latex polymer is made by a method comprising:
preparing a first mixture of monomers for a first stage, the first mixture comprising about 70 wt % methyl methacrylate, about 23 wt % butyl acrylate, about 2 wt % methacrylic acid, about 1 wt % ureido-functional monomer, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture;
preparing a second mixture of monomers for a second stage, the second mixture comprising about 30 wt % methyl methacrylate, about 60 wt % butyl acrylate, about 2 wt % methacrylic acid, about 2 to 4 wt % diacetone acrylamide, and about 1 wt % ureido-functional monomers, based on the total weight of the monomers in the second mixture;
feeding the first mixture into a reactor vessel;
initiating a free radical polymerization of at least the first mixture; and
feeding the second mixture into the reactor vessel.

Assignees

• Valspar Sourcing Inc
• Sherwin Williams Co

Inventors

• Bell Tyler
• Sandoval Robert
• Hibben Mary Jane
• Lee Jay
• Lesiak Jake

Classifications

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C09D7/80

  Processes for incorporating ingredients · CPC title

• C09D7/40

  Additives · CPC title

• C09D133/26 Primary

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title