High block, tack and scrub resistant coating composition

Patent metadata

Field	Value
Publication number	US-10647871-B2
Application number	US-201715594953-A
Country	US
Kind code	B2
Filing date	May 15, 2017
Priority date	Dec 15, 2011
Publication date	May 12, 2020
Grant date	May 12, 2020

Abstract

The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance.

First claim

What is claimed is:

1. A coating composition, comprising:
an in-store tintable liquid base paint formulation, comprising
a multistage latex polymer having at least a first stage with a Tg of greater than about 0 to 120° C. and at least about 1% by weight acrylic acid monomer; and at least a second stage with a Tg of −35 to 10° C.; and
a fluorosurfactant; and

about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 50 g/L; which colorants are added to the base paint formulation at a point-of-sale to achieve a desired color;
wherein the coating composition displays a scrub resistance of at least about 800 scrubs.

2. The composition of claim 1 , made by a process comprising the steps of:
providing a container with a quantity of the in-store tintable base paint formulation and headspace sufficient to receive a quantity of one or more low VOC colorants;
providing instructions for dispensing the low VOC colorant into the base paint formulation at a point-of-sale, and in a particular amount, to obtain a coating composition of a desired color.

3. The composition of claim 1 , wherein the multistage latex polymer is made by a method comprising:
preparing a first mixture of monomers for a first stage, the first mixture comprising about 65 to 75 wt % methyl methacrylate, 15 to 20% butyl acrylate, 2 to 4 wt % acrylic acid, about 0.5 to 1.5 wt % ureido-functional monomer, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture;
preparing a second mixture of monomers for a second stage, the second mixture comprising about 30 to 40 wt % methyl methacrylate, about 45 to 55 wt % butyl acrylate, about 1 to 3 wt % methacrylic acid, about 2 to 4 wt % diacetone acrylamide, and about 0.5 to 1.5 wt % ureido-functional monomers, based on the total weight of the monomers in the second mixture;
feeding the first mixture into a reactor vessel;
initiating a free radical polymerization of at least the first mixture; and
feeding the second mixture into the reactor vessel.

4. The composition of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 4° C. or less.

5. The composition of claim 1 , wherein the multistage latex is capable of forming a film at a temperature of 10° C. or less, in the absence of a separate coalescing agent.

6. The composition of claim 1 , wherein the composition further includes no more than about 15 wt % coalescing agent, and is capable of forming a film at a temperature of 25° C. or less.

7. The composition of claim 1 , wherein the monomers forming the first stage or second stage comprise one or more ureido-functional monomers.

8. The composition of claim 3 , wherein the monomers forming the first stage or second stage further comprise one or more polyfunctional acrylate monomers.

9. The composition of claim 1 , wherein the difference in Tg of the first and second stage monomers (ΔTg) is less than about 60° C.

10. The composition of claim 1 , wherein the difference in Tg of the first and second stage monomers (ΔTg) is less than about 50° C.

11. The composition of claim 1 , wherein the composition exhibits block resistance rating of at least 6.

12. The composition of claim 1 , wherein the composition exhibits average scrub resistance of at least about 1000 scrubs.

13. The composition of claim 1 , wherein the composition exhibits tack resistance force of less than 1.1 lbF.

14. The composition of claim 12 , wherein the composition exhibits average scrub resistance of at least about 1200 scrubs.

15. The composition of claim 1 , wherein the composition exhibits 20° gloss of at least 45.

16. The composition of claim 1 , wherein the composition exhibits 60° gloss of at least 75.

17. The composition of claim 1 , wherein the composition exhibits Konig hardness of at least 9.

18. The composition of claim 1 , wherein the composition exhibits print resistance of at least 8 as determined by ASTM D2064.

19. The composition of claim 1 , wherein the fluorosurfactant is present in an amount of up to about 0.5 wt %.

20. The composition of claim 19 , wherein the fluorosurfactant is present in an amount of 0.1 to 0.3 wt %.

21. The composition of claim 1 , wherein the multistage latex polymer has at least a first stage with a Tg of 25° C. to 75° C.

22. The composition of claim 21 , wherein the monomers forming the first stage or second stage comprise diacetone acrylamide.

23. The composition of claim 9 , wherein the monomers forming the first stage or second stage comprise diacetone acrylamide.

24. A coating composition, comprising:
an in-store tintable liquid base paint formulation, comprising
a multistage latex polymer having at least a first stage with a Tg of greater than about 0 to 120° C. and at least about 1% by weight acrylic acid monomer; and at least a second stage with a Tg of −35 to 10° C.; wherein the difference in Tg of the first and second stage monomers (ATg) is less than about 60° C.; and
a fluorosurfactant; and

about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 50 g/L; which colorants are added to the base paint formulation at a point-of-sale to achieve a desired color;
wherein the coating composition displays a scrub resistance of at least about 800 scrubs, and a block resistance rating of at least 6.

25. The composition of claim 24 , wherein the multistage latex polymer has at least a first stage with a Tg of 25° C. to 75° C.

26. The composition of claim 24 , wherein the monomers forming the first stage or second stage comprise diacetone acrylamide.

27. The composition of claim 24 , wherein the composition exhibits tack resistance force of less than 1.1 lbF.

28. A coating composition, comprising:
an in-store tintable liquid base paint formulation, comprising
a multistage latex polymer having at least a first stage with a Tg of 25° C. to 75° C. and at least about 1% by weight acrylic acid monomer; and at least a second stage with a Tg of −35 to 10° C.; wherein the monomers forming the first stage or second stage comprise diacetone acrylamide; and
a fluorosurfactant; and

about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 50 g/L; which colorants are added to the base paint formulation at a point-of-sale to achieve a desired color;
wherein the coating composition displays a scrub resistance of at least about 800 scrubs, and a block resistance rating of at least 6.

Assignees

• Valspar Sourcing Inc

Inventors

• Bell Tyler
• Sandoval Robert
• Hibben Mary Jane
• Wildman Michael C

Classifications

• C09D133/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C09D133/08

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C09D133/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C09D133/06 Primary

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title