Rheological methods for high block, tack and scrub resistant coating composition

Patent metadata

Field	Value
Publication number	US-10626284-B2
Application number	US-201715664676-A
Country	US
Kind code	B2
Filing date	Jul 31, 2017
Priority date	Dec 15, 2011
Publication date	Apr 21, 2020
Grant date	Apr 21, 2020

Abstract

The present invention is directed to a coating composition or paint comprising a multistage latex with at least first and second stages, wherein the composition or paint is substantially free of volatile organic compounds (VOC) and capable of film formation even in the absence of coalescent agents. The base paint formulation is capable of being tinted at a point-of-sale (i.e. in-store) using a colorant composition of a type and quantity required to produce a paint of desired color and finish. The paints, show improved block resistance, scrub resistance and tack resistance. Rheological techniques as described herein may be used to determine tack resistance, print resistance, and other performance characteristics.

First claim

What is claimed is:

1. A coating composition, comprising:
a latex polymer having a Tg of about −35 to 120° C., which is a multistage composition comprising;
at least a first stage derived from a first mixture of monomers including about 70 to 80 wt % methyl methacrylate, 20 to 30 wt % butyl acrylate, 1 to 2 wt % methacrylic acid, about 1 to 2 wt % ureido functional monomer, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture; and
at least a second stage derived from a second mixture of monomers including about 30 to 40 wt % methyl methacrylate, about 50 to 70 wt % butyl acrylate, about 1 to 2 wt % methacrylic acid, about 2 to 4 wt % diacetone acrylamide, and about 1 to 3 wt % ureido functional monomers, based on the total weight of the monomers in the second mixture;
wherein the first mixture of monomers or the second mixture of monomers comprises:
optionally, about 0.5 wt % fluorosurfactant; and
optionally, about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 5 wt %;

wherein the coating composition has scrub resistance of at least 1000, storage modulus (E′) of about 1.0×10 6 to 1.0 to 10 7 Pa at 60° C. and 0.1 rad/s and tan (δ) of less than about 0.2 at 60° C. and 0.1 rad/s.

2. The composition of claim 1 , wherein the latex polymer is a multistage composition comprising:
at least a first stage with Tg of about 0 to 120° C.; and
at least a second stage with Tg of about −35 to 10° C.

3. The composition of claim 2 , wherein the latex polymer is derived from a mixture of monomers for the first stage or the second stage, wherein the mixture of monomers comprise one or more ethylenically unsaturated monomers selected from acrylic acid, C1-C8 esters of acrylic acid, substituted C1-C8 esters of acrylic acid, methacrylic acid, C1-C8 ester of methacrylic acid, substituted C1-C8 esters of methacrylic acid, styrene, α-methyl styrene, vinyl toluene, vinyl acetate, vinyl propionate, allyl methacrylate, and mixtures thereof.

4. The composition of claim 1 , wherein the latex polymer is a multistage composition including a crosslinking component.

5. The composition of claim 4 , wherein the crosslinking component is selected from 2-(acetoacetoxy)ethyl methacrylate (AAEM), diacetone acrylamide (DAAM), and mixtures thereof.

6. The coating composition of claim 1 , wherein the coating composition has E′ of about 1.0×10 6 to 7.0×10 6 Pa at 60° C. and 0.1 rad/s.

7. The coating composition of claim 1 , wherein the coating composition has tan (δ) of less than about 0.15 at 60° C. and 0.1 rad/s.

8. The coating composition of claim 6 , wherein the coating composition has E′ of about 2.0×10 6 to about 3.0×10 6 Pa at 60° C. and 0.1 rad/s.

9. The coating composition of claim 7 , wherein the coating composition has tan (δ) of about 0.05 to 0.15 at 60° C. and 0.1 rad/s.

10. The coating composition of claim 1 , wherein the coating composition has E′ corresponding to a cheesecloth print resistance rating of at least 8 according to ASTM D2064-91.

11. The coating composition of claim 1 , wherein the coating composition has E′ of about 1.0×10 6 to 1.0×10 8 Pa at 25° C. and 2.1 rad/s.

12. The coating composition of claim 9 , wherein the coating composition has E′ corresponding to a perceived tack rating of about 1 to 2.

13. The coating composition of claim 1 , wherein the difference in Tg of the first and second stage monomers is at least about 50° C.

14. The composition of claim 1 , wherein the coating composition further includes no more than about 10% by weight coalescing agent, and is capable of forming a film at a temperature of 20° C. or less.

15. The composition of claim 1 , wherein the scrub resistance is at least 1100.

16. The composition of claim 1 , wherein the 60° gloss rating is at least 80.

17. The composition of claim 1 , wherein the latex polymer is a multistage composition comprising:
at least a first stage with Tg of about −35 to 10° C.; and
at least a second stage with Tg of about 0 to 120° C.

18. The composition of claim 1 , wherein the first and second mixtures of monomers comprise a ureido-functional monomer.

19. The composition of claim 18 , wherein the first and second mixtures of monomers comprise up to about 5 wt % ureido-functional monomer, based on the total weight of the monomers.

20. The composition of claim 19 , wherein the first mixture of monomers comprises about 1 to 2 wt % ureido-functional monomer, and the second mixture of monomers comprises about 1 to 3 wt % ureido-functional monomer, based on the total weight of the monomers.

21. A coating composition, comprising:
a multistage latex polymer having a Tg of about −35 to 120° C., which is made by a method comprising:
preparing a first mixture of monomers for a first stage, the first mixture comprising about 70 to 80 wt % methyl methacrylate, 20 to 30 wt % butyl acrylate, 1 to 2 wt % methacrylic acid, about 1 to 2 wt % ureido functional monomer, and optionally, about 2 to 4 wt % diacetone acrylamide, based on the total weight of the monomers in the first mixture;
preparing a second mixture of monomers for a second stage, the second mixture comprising about 30 to 40 wt % methyl methacrylate, about 50 to 70 wt % butyl acrylate, about 1 to 2 wt % methacrylic acid, about 2 to 4 wt % diacetone acrylamide, and about 1 to 3 wt % ureido functional monomers, based on the total weight of the monomers in the second mixture;
feeding the first mixture into a reactor vessel;
initiating a free radical polymerization of at least the first mixture; and
feeding the second mixture into the reactor vessel;

wherein the first mixture of monomers or the second mixture of monomers comprises:
optionally, about 0.5 wt % fluorosurfactant; and
optionally, about 0 to 15 wt % of one or more colorant compositions having volatile organic content (VOC) of less than about 5 wt %;

wherein the coating composition has scrub resistance of at least 1000, storage modulus (E′) of about 1.0×10 6 to 1.0 to 10 7 Pa at 60° C. and 0.1 rad/s and tan (δ) of less than about 0.2 at 60° C. and 0.1 rad/s.

22. The coating composition of claim 21 , wherein the multistage latex is capable of forming a film at a temperature of 4° C. or less.

23. The composition of claim 21 , wherein the multistage latex is capable of forming a film at a temperature of 10° C. or less, in the absence of a separate coalescing agent.

24. The composition of claim 21 , wherein the first and second mixtures of monomers comprise a ureido-functional monomer.

25. The composition of claim 24 , wherein the first and second mixtures of monomers comprise up to about 5 wt % ureido-functional monomer, based on the total weight of the monomers.

26. The composition of claim 25 , wherein the first mixture of monomers comprises about 1 to 2 wt % ureido-functional monomer, and the second mixture of monomers comprises about 1 to 3 wt % ureido-functional monomer, based on the total weight of the monomers.

Assignees

• Valspar Sourcing Inc
• Sherwin Williams Co

Inventors

• Ewert Tessie Rose
• Bell Tyler
• Sandoval Robert
• Hibben Mary Jane

Classifications

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C09D7/40

  Additives · CPC title

• C09D133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C08K5/02

  Halogenated hydrocarbons {(C08K5/0091 takes precedence)} · CPC title

• C08L2201/54

  Aqueous solutions or dispersions · CPC title