Method for manufacturing an Sn:Sb intermetallic phase

Patent metadata

Field	Value
Publication number	US-11139474-B2
Application number	US-201615353250-A
Country	US
Kind code	B2
Filing date	Nov 16, 2016
Priority date	Nov 16, 2015
Publication date	Oct 5, 2021
Grant date	Oct 5, 2021

Abstract

A method for preparing a material having an Sn:Sb intermetallic phase includes at least the steps of mixing chemical elements Sn and Sb, and treating the mixture with microwaves. An electrode is manufactured by using the material having an Sn:Sb intermetallic phase; forming the material in a form of powder; mixing the powder with carbon, a binder and a solvent to form an ink; coating a current collector with the ink; and drying the electrode.

First claim

The invention claimed is:

1. Method for preparing a material having an Sn:Sb intermetallic phase, wherein the material comprises at most 5 wt % of impurities, relative to a total weight of the material and wherein the material comprises at most 10 wt % of Sn and/or of Sb not belonging to the intermetallic phase, relative to a total weight of the material, said method comprising at least the following steps:
a/ mixing precursors consisting essentially of chemical elements Sn and Sb in solid form, and
b/ treating the mixture from step a/ with microwaves,
wherein the chemical elements Sn and Sb are in contract with a susceptor material for carrying out the treatment of step b/ with microwaves, and a specific energy of the treatment carried out in step b/ is greater than or equal to 24,000 J per g of susceptor, and
wherein, with m (MP) denoting a total weight of the chemical elements Sn and Sb, and m (S) denoting a weight of susceptor, these weights satisfy the relation: 0.1 m (MP) ≤m (S) ≤3000 m (MP) .

2. Method according to claim 1 , wherein the chemical elements Sn and Sb are used in a molar proportion selected from the group consisting of 30/70, 40/60, 50/50, 60/40, and 70/30.

3. Method according to claim 1 , wherein a duration of step b/ is greater than or equal to 60 s and less than or equal to 600 s.

4. Method according to claim 1 , wherein the specific energy of the treatment carried out in step b/ is greater than or equal to 30,000 J per g of susceptor.

5. Method according to claim 1 , wherein the susceptor material is a solid.

6. Method according to claim 5 , wherein the susceptor material is selected from the group consisting of carbon and CuO.

7. Method according to claim 6 , wherein the susceptor material is carbon and a duration of microwave treatment is from 90 s to 150 s.

8. Method according to claim 6 , wherein the susceptor material is CuO and a duration of microwave treatment is from 300 s to 600 s.

9. Method according to claim 1 , wherein the chemical elements Sn and Sb are used in a form of powder or pellets.

10. Method according to claim 1 , wherein the method is carried out in a substrate made of one of the following materials: alumina (Al 2 O 3 ), silica (SiO 2 ).

11. Method according to claim 1 , wherein the material having an Sn:Sb intermetallic phase corresponds to one selected from the group consisting of: Sn:Sb (3:7), Sn:Sb (2:3), Sn:Sb (1:1), Sn:Sb (3:2), and Sn:Sb (7:3).

12. Method for manufacturing an electrode, said method comprising at least:
(1) manufacturing a material having an Sn:Sb intermetallic phase according to claim 1 ,
(2) forming the material from step (1) in a form of powder,
(3) mixing the powder from step (2) with carbon, a binder and a solvent to form an ink,
(4) coating a current collector with the ink, and
(5) drying the electrode.

Assignees

• Hutchinson
• Centre Nat Rech Scient
• Univ Montpellier

Inventors

• Ayme-Perrot David
• Sonntag Philippe
• Antitomaso Philippe
• Monconduit Laure
• Morato-Lallemand Francoise
• Girard Philippe

Classifications

• C22C1/047

  comprising intermetallic compounds {(C22C1/0441 takes precedence)} · CPC title

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• B22F1/09

  Mixtures of metallic powders · CPC title

• C22C1/04

  by powder metallurgy (C22C1/08 takes precedence) · CPC title

• C22C1/0483 Primary

  Alloys based on the low melting point metals Zn, Pb, Sn, Cd, In or Ga · CPC title