Plasma assisted atomic layer deposition of multi-layer films for patterning applications
US-2016336178-A1 · Nov 17, 2016 · US
US10978302B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10978302-B2 |
| Application number | US-201815974172-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 8, 2018 |
| Priority date | Nov 29, 2017 |
| Publication date | Apr 13, 2021 |
| Grant date | Apr 13, 2021 |
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A method for forming features over a wafer with a carbon based deposition is provided. The carbon based deposition is pretuned, wherein the pretuning causes a non-uniform removal of some of the carbon based deposition. An oxide deposition of a silicon oxide based material is deposited through an atomic layer deposition process, wherein the depositing the oxide deposition causes a non-uniform removal of some of the carbon based deposition, which is complementary to the non-uniform removal of some of the carbon based deposition by the pretuning.
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What is claimed is: 1. A method for forming features over a wafer with a carbon based deposition, comprising: pretuning the carbon based deposition, wherein the pretuning causes a first non-uniform removal of some of the carbon based deposition; and depositing an oxide deposition of a silicon oxide based material through an atomic layer deposition process, wherein the depositing the oxide deposition causes a second non-uniform removal of some of the carbon based deposition, which is complementary to the first non-uniform removal of some of the carbon based deposition by the pretuning. 2. The method, as recited in claim 1 , wherein the second non-uniform removal of some of the carbon based deposition by the oxide deposition is complementary to the first non-uniform removal of some of the carbon based deposition by the pretuning in that the combination of the second non-uniform removal of some of the carbon based deposition by the depositing the oxide deposition and the first non-uniform removal of some of the carbon based deposition by the pretuning results in a more uniform removal of the carbon based deposition than the second non-uniform removal of some of the carbon based deposition by the depositing the oxide deposition. 3. The method, as recited in claim 2 , wherein the more uniform removal is a more uniform removal across the wafer. 4. The method, as recited in claim 1 , further comprising: removing the carbon based deposition; and etching an etch layer below the oxide deposition, using the oxide deposition as a mask. 5. The method, as recited in claim 1 , wherein the pretuning the carbon based deposition, comprises: providing a pretuning gas comprising oxygen and at least one of Ar or nitrogen, transforming the pretuning gas into a plasma, which causes a non-uniform removal of some of the carbon based deposition; and stopping the pretuning gas. 6. The method, as recited in claim 5 , wherein the pretuning gas comprises oxygen and argon, wherein a ratio of the oxygen to argon is between 2:1 to 1:2. 7. The method, as recited in claim 1 , wherein the pretuning removes less than 20 {acute over (Å)} thickness of the carbon based deposition. 8. The method, as recited in claim 7 , wherein the depositing the oxide deposition and the pretuning provide a removal range across the wafer of the carbon based deposition of less than 10 {acute over (Å)}. 9. The method, as recited in claim 1 , wherein the pretuning removes the carbon based deposition in a dome shaped profile and wherein the depositing the oxide deposition removes the carbon based deposition in a bowl shaped profile. 10. The method, as recited in claim 1 , wherein the depositing the oxide deposition comprises: providing a lower energy oxide deposition of a plurality of cycles, wherein each cycle comprises: flowing a precursor gas; flowing an oxidation gas; providing a first RF power to transform the oxidation gas into a plasma; and providing a higher energy oxide deposition of a plurality of cycles, wherein each cycle comprises: flowing a precursor gas; flowing an oxidation gas; and providing a second RF power to transform the oxidation gas into a plasma, wherein the second RF power is higher than the first RF power. 11. The method, as recited in claim 1 , further comprising providing at least one of a feedback or feedforward input to optimize the pretuning. 12. The method, as recited in claim 1 , further comprising forming a carbon based deposition over the wafer.
by chemical means · CPC title
of organic photoresist masks · CPC title
using masks for insulating materials · CPC title
the material being a silicon oxide, e.g. SiO2 · CPC title
the compound comprising silicon and nitrogen · CPC title
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