Preparation of a synthetic quartz glass grain

Patent metadata

Field	Value
Publication number	US-10618833-B2
Application number	US-201616062705-A
Country	US
Kind code	B2
Filing date	Dec 16, 2016
Priority date	Dec 18, 2015
Publication date	Apr 14, 2020
Grant date	Apr 14, 2020

Abstract

The invention relates to a process for the preparation of a quartz glass grain comprising the process steps i.) Providing a silicon dioxide granulate from a pyrogenically produced silicon dioxide powder, ii.) Making a glass melt out of silicon dioxide granulate, iii.) Making a quartz glass body out of at least part of the glass melt and iv.) Reducing the size of the quartz glass body to obtain the quartz glass grain. The invention further relates to a quartz glass grain which is obtainable by this process. The invention further relates to opaque quartz glass bodies, which are obtainable by further processing of the quartz glass grain.

First claim

The invention claimed is:

1. A process for the preparation of a quartz glass grain comprising:
providing a silicon dioxide granulate, wherein the silicon dioxide granulate has been prepared from pyrogenically produced silicon dioxide powder;
making a glass melt out of the silicon dioxide granulate in a melting crucible;
making a quartz glass body out of at least part of the glass melt; and
reducing the size of the quartz glass body to obtain the quartz glass grain.

2. The process according to claim 1 , wherein the melting crucible has at least one inlet and an outlet and wherein the inlet is arranged above the outlet.

3. The process according to claim 1 , wherein the reduction in size of the quartz glass body takes place by high voltage discharge pulses.

4. The process according to claim 1 , wherein the quartz glass grain comprises at least one of:
an OH content of less than 500 ppm;
a chlorine content of less than 60 ppm;
an aluminium content of less than 200 ppb;
a BET surface area of less than 1 m 2 /g;
a bulk density in a range from 1.1 to 1.4 g/cm 3 ;
a particle size D 50 for melting in a range from 50 to 500 μm;
a particle size D 50 for the slurry in a range from 0.5 to 5 μm;
a metal content of metals different to aluminium of less than 2 ppm; and
viscosity (p=1013 hPa) in a range from log 10 (η(1250° C.)/dPas)=11.4 to log 10 (η(1250° C.)/dPas)=12.9 or log 10 (η(1300° C.)/dPas)=11.1 to log 10 (η(1300° C.)/dPas)=12.2 or log 10 (η(1350° C.)/dPas)=10.5 to log 10 (η(1350° C.)/dPas)=11.5;
wherein the ppm and ppb are each based on the total weight of the quartz glass grain.

5. The process according to claim 1 , wherein the silicon dioxide granulate comprises at least one of:
a BET surface area in a range from 20 to 50 m 2 /g;
a mean particle size in a range from 50 to 500 μm;
a bulk density in a range from 0.5 to 1.2 g/cm 3 ;
a carbon content of less than 50 ppm;
an aluminium content of less than 200 ppb;
a tamped density in a range from 0.7 to 1.0 g/cm 3 ;
a pore volume in a range from 0.1 to 2.5 mL/g;
an angle of repose in a range from 23 to 26°;
a particle size distribution D 10 in a range from 50 to 150 μm;
a particle size distribution D 50 in a range from 150 to 300 μm; and
a particle size distribution D90 in a range from 250 to 620 μm,
wherein the ppm and ppb are each based on the total weight of the silicon dioxide granulate.

6. The process according to claim 1 , wherein the silicon dioxide powder is prepared from a compound selected from the group consisting of siloxanes, silicon alkoxides and silicon halides.

7. The process according to claim 1 , wherein the quartz glass grain comprising at least one of:
an OH content of less than 500 ppm;
a chlorine content of less than 60 ppm;
an aluminium content of less than 200 ppb;
a BET surface area of less than 1 m 2 /g;
a bulk density in a range from 1.1 to 1.4 g/cm 3 ;
a particle size D 50 for melting in a range from 50 to 500 μm;
a particle size D 50 for the slurry in a range from 0.5 to 5 mm;
a metal content of metals different to aluminium of less than 2 ppm; and
viscosity (p=1013 hPa) in a range from log 10 (η(1250° C.)/dPas)=11.4 to log 10 (η(1250° C.)/dPas)=12.9 or log 10 (η(1300° C.)/dPas)=11.1 to log 10 (η(1300° C.)/dPas)=12.2 or log 10 (η(1350° C.)/dPas)=10.5 to log 10 (η(1350° C.)/dPas)=11.5;
wherein the ppm and ppb are each based on the total weight of the quartz glass grain.

8. The process of claim 1 further comprising:
processing the quartz glass grain to an opaque formed body.

9. The process according to claim 8 , wherein the process comprises a sintering.

10. The process according to claim 8 , wherein the opaque formed body comprises at least one of:
an opacity of more than 5;
a BET surface area of less than 1 m 2 /g;
a cylindrical form;
a sheet;
an OH content of less than 500 ppm;
a chlorine content of less than 60 ppm;
an aluminium content of less than 200 ppb;
an ODC content of less than 5*10 18 /cm 3 ;
a carbon content of less than 5 ppm; and
a total metal content of metals different to aluminium of less than 2 ppm;
wherein the ppm and ppb are each based on the total weight of the formed body.

11. The process of claim 8 , wherein the glass grain is used for preparing opaque products comprising quartz glass, wherein the quartz glass grain comprises:
an OH content of less than 500 ppm;
a chlorine content of less than 60 ppm; and
an aluminium content of less than 200 ppb;
wherein the ppm and ppb are each based on the total weight of the quartz glass grain.

Assignees

• Heraeus Quarzglas

Inventors

• Arndt Martin
• Otter Matthias
• Lehmann Walter
• Hünermann Michael
• Nielsen Nils Christian
• Whippey Nigel Robert
• Gromann Boris
• Kpebane Abdoul-Gafar

Classifications

• C03C3/06

  with more than 90% silica by weight, e.g. quartz {(C03C3/045 takes precedence)} · CPC title

• C03B19/066 Primary

  for the production of quartz or fused silica articles (other processes specially adapted for the production of quartz or fused silica articles C03B20/00) · CPC title

• C03B2201/23

  doped with hydroxyl groups · CPC title

• C03C1/04

  Opacifiers, e.g. fluorides or phosphates; Pigments · CPC title

• C03C2203/10

  Melting processes · CPC title