Ferrite powder for bonded magnets, method for producing the same and ferrite bonded magnet

Patent metadata

Field	Value
Publication number	US-10453596-B2
Application number	US-201515515892-A
Country	US
Kind code	B2
Filing date	Sep 30, 2015
Priority date	Sep 30, 2014
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

There is provided a ferrite powder for bonded magnets capable of producing ferrite bonded magnets with high BH max , excellent in MFR when converted to a compound, with high p-iHc, wherein an average particle size of particles obtained by a dry laser diffraction measurement is 5 μm or less, a specific surface area is 1.90 m 2 /g or more and less than 3.00 m 2 /g, a compression density is 3.40 g/cm 3 or more and less than 3.73 g/cm 3 , and a compressed molding has a coercive force of 2800 Oe or more and less than 3250 Oe.

First claim

The invention claimed is:

1. A strontium ferrite powder for bonded magnets, wherein
an average particle size of particles obtained by a dry laser diffraction measurement is 5 μm or less,
a specific surface area is 1.90 m 2 /g or more and less than 3.00 m 2 /g,
a compression density is 3.40 g/cm 3 or more and less than 3.73 g/cm 3 ,
a compressed molding has a coercive force of 2800 Oe or more and less than 3250 Oe, and
a cumulative distribution value at a particle size of 0.62 μm in a cumulative particle size distribution curve is 12% or more by volume.

2. The strontium ferrite powder for bonded magnets according to claim 1 , wherein a cumulative distribution value at a particle size of 0.74 μm in a cumulative particle size distribution curve is 17% or more by volume.

3. The strontium ferrite powder for bonded magnets according to claim 1 , wherein a frequency distribution at a particle size of 0.40 μm in a frequency distribution curve is 11 or more.

4. The strontium ferrite powder for bonded magnets according to claim 1 , wherein a frequency distribution at a particle size of 0.48 μm in a frequency distribution curve is 16 or more.

5. The strontium ferrite powder for bonded magnets according to claim 1 , wherein when the strontium ferrite powder for bonded magnets and a nylon resin powder are kneaded to obtain a compound with 92.7 mass % content of the strontium ferrite powder for bonded magnets, fluidity of the compound is 42.5 g/10 min or more.

6. The strontium ferrite powder for bonded magnets according to claim 1 , wherein when the strontium ferrite powder for bonded magnets and a nylon resin powder are kneaded to obtain a compound with 92.7 mass % content of the strontium ferrite powder for bonded magnets and the compound is molded to obtain a bonded magnet, iHc of the bonded magnet is 2,200 Oe or more and less than 3,000 Oe.

7. A ferrite bonded magnet produced by molding the strontium ferrite powder for bonded magnets of claim 1 .

8. The ferrite bonded magnet containing the strontium ferrite powder for bonded magnets of claim 1 .

9. A method for producing a ferrite powder for bonded magnets, comprising:
granulating a plurality of ferrite raw materials including iron oxide, and obtaining a first granulated material;
sintering the obtained first granulated material at a first temperature, and obtaining a coarse powder of a sintered product;
granulating a plurality of ferrite raw materials including iron oxide, and obtaining a second granulated material;
sintering the obtained second granulated material at a second temperature lower than the first temperature, and obtaining fine powder of the sintered product;
mixing the obtained coarse powder and fine powder, to obtain a mixed powder; and
adding a mechanical pulverizing force to the obtained mixed powder to obtain a pulverized mixture, and applying annealing to the obtained pulverized mixture,
wherein the first temperature is 1220° C. or more and less than 1250° C., and the second temperature is 900° C. or more and 1000° C. or less, and when a mixing ratio of the coarse powder and the fine powder is expressed by [mass of the coarse powder/mass of (coarse powder+fine powder)]×100%, it is 56 mass % or more and less than 75 mass %,
wherein the mechanical pulverizing force is the force caused by a pulverization processing in which a vibration ball mill with a capacity of 2 to 4 L and power of 0.3 to 0.5 kW, is loaded with steel balls having a diameter of 8 to 14 mm as media, so that pulverization is performed at a rotation number of 1700 to 1900 rpm and an amplitude of 7 to 9 mm, for 20 to 100 minutes as a processing time, or the force equivalent thereto.

Assignees

• Dowa Electronics Materials Co Ltd
• Dowa F Tec Co Ltd

Inventors

• Tsuboi Satoru
• Mishima Yasunobu
• Ayabe Keisuke
• Senda Masayasu

Classifications

• H01F1/11

  in the form of particles {(for magnetic record carriers G11B5/70626)} · CPC title

• C04B2235/3201

  Alkali metal oxides or oxide-forming salts thereof · CPC title

• H01F1/113 Primary

  in a bonding agent · CPC title

• C01P2006/11

  Powder tap density · CPC title

• C04B2235/3274

  Ferrites · CPC title