Amorphous silica and process for producing same

Patent metadata

Field	Value
Publication number	US-10173902-B2
Application number	US-201013502850-A
Country	US
Kind code	B2
Filing date	Oct 20, 2010
Priority date	Oct 20, 2009
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

Provided are amorphous silica particles for application to industrial fields where there are increasing desires for high purity and colorlessness. The amorphous silica particles are produced through the steps of hydrolysis of an alkoxide, vacuum drying, and firing. The amorphous silica particles have been reduced in coloration and in Fe content, which is causative of coloration of the silica, and can meet the desires. The amorphous silica is characterized by having an Fe content of 20 ppm or less.

First claim

The invention claimed is:

1. A cured product comprising a gap between parts of the cured product and cured underfill encapsulant that fills the gap to the end, wherein the cured underfill encapsulant comprises an epoxy resin and a fired amorphous silica having a Fe content of 20 ppm or less and a variation coefficient in the particle diameter of 8% or less, and the gap is a gap between a semiconductor chip and a substrate or a gap among solder balls, and wherein the fired amorphous silica has a ratio (A 1 /A 2 ) of a maximum absorbance (A 1 ) of a peak of isolated silanol group to a maximum absorbance (A 2 ) of a peak of silanol group derived from adsorbed water of 0.2 or less in an infrared absorption spectrum.

2. The cured product according to claim 1 , wherein the fired amorphous silica has a ratio (A 1 /A 0 ) of the maximum absorbance (A 1 ) of the peak of isolated silanol group to a maximum absorbance (A 0 ) of a peak of siloxane bond of 0.001 or less in the infrared absorption spectrum.

3. The cured product according to claim 1 , wherein the underfill encapsulant further comprises an acid anhydride curing agent or a thermal cationic curing catalyst.

4. The cured product according to claim 1 , wherein the fired amorphous silica has an average particle diameter of 0.1 μm or larger and 2 μm or smaller.

5. A process for producing an electronic part, comprising:
pouring an underfill encapsulant, which comprises an epoxy resin and a fired amorphous silica having a Fe content of 20 ppm or less and a variation coefficient in the particle diameter of 8% or less, into gaps of an object material to be sealed,
filling the gap with the underfill encapsulant to the end, and
curing the underfill encapsulant to obtain the electronic part, wherein the gap is a gap between a semiconductor chip and a substrate or a gap among solder balls, and wherein the fired amorphous silica has a ratio (A 1 /A 2 ) of a maximum absorbance (A 1 ) of a peak of isolated silanol group to a maximum absorbance (A 2 ) of a peak of silanol group derived from adsorbed water of 0.2 or less in an infrared absorption spectrum.

6. The process for producing an electronic part according to claim 5 , wherein the fired amorphous silica has a ratio (A 1 /A 0 ) of the maximum absorbance (A 1 ) of the peak of isolated silanol group to a maximum absorbance (A 0 ) of a peak of siloxane bond of 0.001 or less in the infrared absorption spectrum.

7. The process for producing an electronic part according to claim 5 , wherein the underfill encapsulant further comprises an acid anhydride curing agent or a thermal cationic curing catalyst.

8. The process for producing an electronic part according to claim 5 , wherein the fired amorphous silica has an average particle diameter of 0.1 μm or larger and 2 μm or smaller.

9. The cured product according to claim 1 , wherein the underfill encapsulant is capable of permeating a gap between a semiconductor chip and a substrate or a gap among solder balls.

10. The process for producing an electronic part according to claim 5 , wherein the underfill encapsulant is capable of permeating a gap between a semiconductor chip and a substrate or a gap among solder balls.

Assignees

• Iriguchi Jiro
• Yamamoto Yasuhiro
• Shimizu Shuji
• Ono Yuji
• Nippon Catalytic Chem Ind

Inventors

• Iriguchi Jiro
• Yamamoto Yasuhiro
• Shimizu Shuji
• Ono Yuji

Classifications

• H10W74/15

  on active surfaces of flip-chip devices, e.g. underfills · CPC title

• H10W74/012

  of encapsulations on active surfaces of flip-chip devices, e.g. forming underfills · CPC title

• C01B33/145 Primary

  Preparation of hydroorganosols, organosols or dispersions in an organic medium · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08G59/42

  Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof · CPC title