Method of producing silica particles

Patent metadata

Field	Value
Publication number	US-9416015-B2
Application number	US-90640510-A
Country	US
Kind code	B2
Filing date	Oct 18, 2010
Priority date	Jun 23, 2010
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

The invention provides a method of producing silica particles, the method including preparing an alkali catalyst solution containing an alkali catalyst in a solvent including an alcohol, at a concentration of from about 0.6 mol/L to about 0.85 mol/L; and supplying tetraalkoxysilane into the alkali catalyst solution, and concurrently supplying an alkali catalyst into the alkali catalyst solution at a rate of from about 0.1 mol to about 0.4 mol per mole of the total amount of supply of the tetraalkoxysilane supplied in one minute.

First claim

What is claimed is:

1. A method of producing silica particles, the method comprising: preparing an alkali catalyst solution containing an alkali catalyst in a solvent including an alcohol, at a concentration of from about 0.6 mol/L to about 0.85 mol/L; and supplying tetraalkoxysilane into the alkali catalyst solution, and concurrently supplying an alkali catalyst into the alkali catalyst solution at a rate of from about 0.1 mol to about 0.4 mol per mol of the total amount of supply of the tetraalkoxysilane supplied in one minute, wherein the silica particles produced are atypically shaped having an average degree of circularity of from about 0.5 to about 0.85.

2. The method of producing silica particles of claim 1 , wherein the solvent further includes at least one selected from the group consisting of water, a ketone, a cellosolve, and an ether.

3. The method of producing silica particles of claim 1 , wherein the solvent is at least one selected from the group consisting of acetone, methyl ethyl ketone, and methyl isobutyl ketone.

4. The method of producing silica particles of claim 1 , wherein the solvent is at least one selected from the group consisting of methylcellosolve, ethylcellosolve, butylcellosolve and cellosolve acetate.

5. The method of producing silica particles of claim 1 , wherein the solvent is at least one selected from the group consisting of dioxane and tetrahydrofuran.

6. The method of producing silica particles of claim 2 , wherein an amount of alcohol with respect to the at least one selected from the group consisting of water, a ketone, a cellosolve, and an ether is about 80% by weight or greater.

7. The method of producing silica particles of claim 1 , wherein the alkali catalyst is at least one catalyst selected from the group consisting of ammonia, urea, monoamine, and a quaternary ammonium salt.

8. The method of producing silica particles of claim 1 , wherein the tetraalkoxysilane is selected from the group consisting of tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane, and tetrabutoxysilane.

9. The method of producing silica particles of claim 1 , wherein an amount of supply of the tetraalkoxysilane is from about 0.001 mol/(mol·min) to about 0.01 mol/(mol·min) relative to number of moles of the alcohol in the alkali catalyst solution.

10. The method of producing silica particles of claim 1 , wherein upon supplying the tetraalkoxysilane, a temperature of the alkali catalyst solution is from about 5° C. to about 50° C.

11. The method of producing silica particles of claim 1 , further comprising removing the solvent.

12. The method of producing silica particles of claim 11 , further comprising drying a residue obtained by removing the solvent.

13. The method of producing silica particles of claim 12 , wherein a drying temperature is about 200° C. or lower.

14. The method of producing silica particles of claim 1 , further comprising hydrophobizing a surface of the silica particles.

15. The method of producing silica particles of claim 14 , wherein a hydrophobization treating agent is used for the hydrophobizing, and the hydrophobization treating agent is an organosilicon compound having an alkyl group.

16. The method of producing silica particles of claim 15 , wherein the alkyl group is at least one selected from the group consisting of a methyl group, an ethyl group, a propyl group, and a butyl group.

17. The method of producing silica particles of claim 15 , wherein an addition amount of the hydrophobization treating agent is from about 1% by weight to about 100% by weight with respect to the silica particles.

Assignees

• Yoshikawa Hideaki
• Zenitani Yuka
• Okuno Hiroyoshi
• Nozaki Shunsuke
• Kawashima Shinichiro
• Takeuchi Sakae
• Fuji Xerox Co Ltd

Inventors

• Yoshikawa Hideaki
• Zenitani Yuka
• Okuno Hiroyoshi
• Nozaki Shunsuke
• Kawashima Shinichiro
• Takeuchi Sakae

Classifications

• C01B33/141

  Preparation of hydrosols or aqueous dispersions · CPC title

• C01B33/148 Primary

  Concentration; Drying; Dehydration; Stabilisation; Purification {(C01B33/1465 takes precedence)} · CPC title

• C01B33/145

  Preparation of hydroorganosols, organosols or dispersions in an organic medium · CPC title

• C01B33/146

  After-treatment of sols ({preparation of hydrosols or aqueous dispersions from hydroorganosols, organosols or dispersions in an organic medium C01B33/141}; preparation of hydroorganosols, organosols or dispersions in an organic medium from hydrosols {or aqueous dispersions} C01B33/145) · CPC title