Aqueous silica dispersion

Patent metadata

Field	Value
Publication number	US-9637639-B2
Application number	US-201013505655-A
Country	US
Kind code	B2
Filing date	Nov 1, 2010
Priority date	Nov 5, 2009
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

The present invention relates to a method of producing a dispersion comprising a) mixing an aqueous dispersion of silanized colloidal silica particles with at least one organic compound containing at least two hydroxyl groups to provide an aqueous dispersion of silanized colloidal silica particles and said at least one organic compound, wherein the mixing is performed in the substantial absence of any monofunctional alcohol b) withdrawing water from the formed aqueous dispersion until the remainder of water in the dispersion is below about 10 wt %. The invention also relates to a dispersion obtainable therefrom and the use of the dispersion.

First claim

The invention claimed is:

1. A stable dispersion comprising silanised colloidal silica particles having a weight ratio of silane to silica ranging from about 0.1 to about 1.5, and at least one organic compound containing at least two hydroxyl groups, wherein the silanised colliodal silcia particles is substantially unmodified with respect to monofunctional alcohol such that less than about 10 wt % of the silanised colloidal silica particles are modified by a monofunctional alcohol, wherein the dispersion is substantially free of any monofunctional alcohol, wherein the water content in the dispersion is below about 10 wt %, wherein a viscosity of the dispersion is increased less than 2 times over a period of 2 months, and further wherein the dispersion does not appear in an inhomogeneous form.

2. The dispersion according to claim 1 , wherein the water content in the dispersion is below 5 wt %.

3. The dispersion according to claim 1 , wherein said at least one organic compound is a polyol.

4. The dispersion according to claim 1 , wherein the weight ratio of silica to organic compound ranges from about 1:20 to about 4:1.

5. The dispersion according to claim 3 , wherein said polyol has a molecular weight of from about 62 to about 200 g/mole.

6. A method of performing condensation polymerization wherein said polymerization is performed in the presence of the dispersion according to claim 1 .

7. A lacquer or coating composition comprising the dispersion according to claim 1 .

8. A method of producing a polymeric material comprising reacting
a) the dispersion according to claim 1 ; and
b) at least one component selected from an isocyanate, a dicarboxylic acid, an epoxide, a siloxane or a diamine.

9. A method according to claim 8 , in which the polymeric material is polyurethane, polyester, epoxy resins, polysiloxane, or a polyamide.

10. The dispersion according to claim 1 , wherein the inhomogeneous form is a precipitated form.

11. A stable dispersion comprising (A) silanised colloidal silica particles and (B) at least one organic compound containing at least two hydroxyl groups, said silanised colloidal silica particles being substantially unmodified with respect to monofunctional alcohol, said silanized colloidal silica particles having a weight ratio of silane to silica ranging from about 0.2 to about 1.5, said at least one organic compound having a molecular weight ranging from about 62 to about 200 g/mol, said dispersion being substantially free of any monofunctional alcohol such that less than about 10 wt % of the silica particles are modified by a monofunctional alcohol, said dispersion having a water content below about 10 wt %, wherein the dispersion exhibits a viscosity increase of less than 2 times over a period of 2 months and does not appear in an inhomogeneous form.

12. The dispersion according to claim 11 , wherein the inhomogeneous form is a precipitated form.

13. A method of producing a stable dispersion comprising
a) mixing an aqueous dispersion of silanised colloidal silica particles having a weight ratio of silane to silica ranging from about 0.1 to about 1.5 with at least one organic compound containing at least two hydroxyl groups to provide an aqueous dispersion of silanised colloidal silica particles and said at least one organic compound, said silanised colliodal silcia particles being substantially unmodified with respect to mono functional alcohol such that less than about 10 wt % of the silica particles are modified by a monofunctional alcohol, wherein the mixing is performed in the substantial absence of any monofunctional alcohol
b) withdrawing water from the formed aqueous dispersion until the remainder of water in the dispersion is below about 10 wt %, wherein the produced stable dispersion comprising silanised colloidal silica having a weight ratio of silane to silica from about 0.1 to about 1.5 and at least one organic compound containing at least two hydroxyl groups, wherein the silanised colloidal silica particles are substantially unmodified with respect to monofunctional alcohol such that less than about 10% by weight of the silansied colloidal silica particles are modified by monofunctional alcohol, the stable dispersion is substantially free of any monofunctional alcohol, the water content in the stable dispersion is below about 10 wt %, a viscosity of the stable dispersion is increased less than 2 times over a period of 2 months, and further the stable dispersion does not appear in an inhomogeneous form.

14. A method according to claim 13 , wherein said at least one organic compound is a polyol.

15. A method according to claim 14 , wherein the polyol has a molecular weight of from about 62 to about 200 g/mole.

16. A method according to claim 14 , wherein the weight ratio of silica to organic compound ranges from about 1:20 to about 4:1.

Assignees

• Greenwood Peter Harry Johan
• Lagnemo Hans
• Akzo Nobel Chemicals Int Bv

Inventors

• Greenwood Peter Harry Johan
• Lagnemo Hans

Classifications

• C08K3/36

  Silica · CPC title

• C09C1/3063

  Treatment with low-molecular organic compounds · CPC title

• C01B33/145 Primary

  Preparation of hydroorganosols, organosols or dispersions in an organic medium · CPC title

• C08K9/06

  with silicon-containing compounds · CPC title

• C01P2006/22

  Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability · CPC title