Method for manufacturing anodic metal oxide nanoporous templates

Patent metadata

Field	Value
Publication number	US-10156018-B2
Application number	US-201615200647-A
Country	US
Kind code	B2
Filing date	Jul 1, 2016
Priority date	Jul 2, 2015
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

Disclosed is a method for manufacturing anodic metal-oxide nanoporous templates with high-yield and in an environmentally-friendly manner. The method includes anodizing a metal specimen and detaching nanoporous anodic oxide layers, which are formed on more than one surface of the metal specimen due to the anodizing, from the metal specimen, wherein the detaching of the nanoporous anodic oxide layers from the metal specimen includes applying a reverse bias to the metal specimen in the same acidic electrolyte used for anodization.

First claim

What is claimed is:

1. A method for manufacturing anodic metal-oxide nanoporous templates, the method comprising:
simultaneously anodizing multiple surfaces of a metal specimen to form nanoporous anodic oxide layer on each surface by applying forward bias to the metal specimen; and
simultaneously detaching the nanoporous anodic oxide layers from the metal specimen,
wherein the detaching of the nanoporous anodic oxide layers from the metal specimen comprises applying a stair-like reverse bias to the metal specimen;
wherein the anodizing and detaching steps are performed in the same acidic electrolyte; and
wherein, when the forward bias is +25 V, the stair-like reverse bias is applied in three stairs of −15 V, −16 V and −17 V.

2. The method of claim 1 , wherein the simultaneous anodizing of the metal specimen comprises:
simultaneously pre-anodizing the metal specimen by dipping more than one surface of the metal specimen in an acidic electrolyte and by applying a forward bias for anodization of the metal specimen;
simultaneously main-etching the metal specimen to remove more than one of the pre-anodized oxide layers that are generated by the pre-anodizing; and
simultaneously main-anodizing the metal specimen to form main-anodized oxide layers by dipping in an acidic electrolyte more than one surface of the metal specimen, which is textured through the main etching, and by reapplying a forward bias for anodization to the textured metal specimen.

3. The method of claim 2 , further comprising, after simultaneously detaching the main-anodized oxide layers from the metal specimen, sub-etching the metal specimen to simultaneously remove remaining residual oxide layers from more than one surface of the metal specimen.

4. The method of claim 3 , wherein the simultaneous pre-anodizing, the simultaneous main-etching, the simultaneous main-anodizing, the simultaneous detaching of the main-anodic oxide layer, and the simultaneous sub-etching are repeated at least two or more times.

5. The method of claim 1 , further comprising:
before the simultaneous anodizing of the metal specimen, simultaneously electro-polishing more than one surface of the metal specimen.

6. A method for manufacturing anodic metal-oxide nanoporous templates, the method comprising:
providing an aluminum specimen;
simultaneously electro-polishing surfaces of the aluminum specimen in a solution containing perchloric acid and ethanol;
simultaneously pre-anodizing the electro-polished aluminum specimen by dipping the electro-polished metal specimen in a sulfuric acid solution and applying a forward bias for anodization to the electro-polished aluminum specimen;
simultaneously main-etching pre-anodic aluminum oxide (pre-AAO) layers, which are generated by the pre-anodizing, in a chromic acid solution;
simultaneously main-anodizing the aluminum specimen to form main-AAO layers by dipping more than one surface of the aluminum specimen, which is textured through the main etching, in a sulfuric acid solution and reapplying a forward bias for anodization to the textured aluminum specimen; and
applying a stair-like reverse bias to the aluminum specimen to simultaneously detach main-AAO layers, which are generated by the main anodizing, from the aluminum specimen;
wherein the anodizing and detaching steps are performed in the same acidic electrolyte; and
wherein, when the forward bias is +25 V, the stair-like reverse bias is applied in three stairs of −15 V, −16 V and −17 V.

7. The method of claim 6 , further comprising:
after applying the reverse bias to the aluminum specimen, sub-etching the aluminum specimen to simultaneously remove remaining residual oxide layers from more than one surface of the metal specimen.

8. The method of claim 7 , wherein the steps from pre-anodizing through sub-etching are repeated at least two or more times.

9. The method of claim 1 , wherein −15 V is applied for 600 seconds, and −16 V is applied for 500 seconds.

10. The method of claim 6 , wherein −15 V is applied for 600 seconds, and −16 V is applied for 500 seconds.

Assignees

• Univ Korea Res & Bus Found

Inventors

• Joo Jinsoo
• Hong Young Ki

Classifications

• C25D1/20

  Separation of the formed objects from the electrodes {with no destruction of said electrodes} · CPC title

• C25D1/006

  Nanostructures, e.g. using aluminium anodic oxidation templates [AAO] · CPC title

• C25D1/10 Primary

  Moulds; Masks; Masterforms · CPC title

• C25D11/18

  After-treatment, e.g. pore-sealing · CPC title

• C25D11/12

  Anodising more than once, e.g. in different baths · CPC title