Cement set activators for set-delayed cement compositions and associated methods

Patent metadata

Field	Value
Publication number	US-9909051-B2
Application number	US-201514951133-A
Country	US
Kind code	B2
Filing date	Nov 24, 2015
Priority date	Mar 9, 2012
Publication date	Mar 6, 2018
Grant date	Mar 6, 2018

Abstract

Disclosed herein are cement compositions and methods of using set-delayed cement compositions in subterranean formations. A method of cementing in a subterranean formation, may comprise providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder, activating the set-delayed cement composition with a cement set activator, wherein the cement set activator comprises at least one activator selected from the group consisting of nanosilica, a polyphosphate, and combinations thereof, introducing the set-delayed cement composition into a subterranean formation, and allowing the set-delayed cement composition to set in the subterranean formation.

First claim

What is claimed is:

1. An activated set-delayed cement composition comprising:
water;
pumice;
hydrated lime;
a set retarder selected from the group consisting of diethylenetriaminepentamethylenephosphonate, nitrilotrismethylenetriphosphonate, methylene phosphonates, methylene phosphonic acid derivatives, and combinations thereof; and
a cement set activator comprising a combination of a polymeric metaphosphate salt and a monovalent salt.

2. The composition of claim 1 wherein the cement set activator is present in the activated set-delayed cement composition in an amount of about 0.1% to about 20% by weight of the activated set-delayed cement composition.

3. The composition of claim 1 wherein the monovalent salt comprises sodium sulfate.

4. The composition of claim 1 wherein a ratio of the monovalent salt to the polymeric metaphosphate salt is from about 2:1 to about 1:25.

5. The composition of claim 1 wherein the activated set-delayed cement composition further comprises a dispersant.

6. The composition of claim 1 wherein the cement set activator further comprises nanosilica, wherein the nanosilica has been stabilized by at least one nanosilica stabilizer selected from the group consisting of: sodium oxide, potassium oxide, lithium oxide, an amine, and any combination thereof.

7. The composition of claim 1 wherein the activated set-delayed cement composition further comprises a polycarboxylated ether dispersant.

8. The composition of claim 1 wherein the activated set-delayed cement composition is free of Portland cement.

9. The composition of claim 1 wherein the hydrated lime is present from about 10% to about 50% by weight of the pumice.

10. An activated set-delayed cement composition comprising:
water;
pumice;
hydrated lime;
a phosphonic acid derivative set retarder;
a polycarboxylated ether dispersant; and
a cement set activator comprising a combination of a polyphosphate and a monovalent salt.

11. The composition of claim 10 wherein the cement set activator is present in the activated set-delayed cement composition in an amount of about 0.1% to about 20% by weight of the activated set-delayed cement composition.

12. The composition of claim 10 wherein the polyphosphate comprises sodium hexametaphosphate, and wherein the monovalent salt comprises sodium sulfate.

13. The composition of claim 10 wherein the ratio of the monovalent salt to the polyphosphate is from about 2:1 to about 1:25.

14. The composition of claim 10 wherein the cement set activator further comprises nanosilica, wherein the nanosilica has been stabilized by at least one nanosilica stabilizer selected from the group consisting of: sodium oxide, potassium oxide, lithium oxide, an amine, and any combination thereof.

15. The composition of claim 10 wherein the phosphonic acid derivative set retarder comprises at least one retarder selected from the group consisting of a methylene phosphonic acid derivative and a methylene phosphonate.

16. The composition of claim 10 wherein the activated set-delayed cement composition is free of Portland cement.

Assignees

• Halliburton Energy Services Inc

Inventors

• Pisklak Thomas J
• Agapiou Kyriacos
• Otieno Pauline A
• Morgan Ronnie G
• Boul Peter J
• Brothers Lance E

Classifications

• C09K2208/10

  Nanoparticle-containing well treatment fluids · CPC title

• C04B2111/1037

  Cement free compositions, e.g. hydraulically hardening mixtures based on waste materials, not containing cement as such · CPC title

• C04B28/10

  Lime cements or magnesium oxide cements · CPC title

• C04B22/16

  containing phosphorus in the anion, e.g. phosphates · CPC title

• C04B14/06

  Quartz; Sand · CPC title