Galvanic nickel electroplating bath for depositing a semi-bright nickel

Patent metadata

Field	Value
Publication number	US-9752244-B2
Application number	US-201414421568-A
Country	US
Kind code	B2
Filing date	Mar 20, 2014
Priority date	May 8, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention is related to a galvanic nickel or nickel alloy electroplating bath for depositing a semi-bright nickel or nickel alloy coating characterized in that the electroplating bath comprises at least one compound having the general formula (I)

wherein R 1 =C 1 -C 18 hydrocarbon moiety substituted with a SO 3 − group, C 1 -C 18 hydrocarbon moiety substituted with a carboxylic group or C 1 -C 18 hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group;
R 2 =NR 3 R 4 moiety, OR 5 moiety, or cyclic NR 6 moiety, wherein
R 3 , R 4 , R 5 =hydrogen or C 1 -C 18 hydrocarbon moiety or C 1 -C 18 hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group, wherein R 3 , R 4 and R 5 are identical or different;
R 6 =C 3 -C 8 hydrocarbon moiety or C 3 -C 8 hydrocarbon moiety, wherein at least one carbon atom is substituted by a heteroatom; and
n=1-3.

First claim

The invention claimed is:

1. Galvanic nickel electroplating bath for depositing a semi-bright nickel coating characterized in that the electroplating bath comprises at least one compound having the general formula (I)

wherein
R 1 =C 1 -C 18 hydrocarbon moiety substituted with a SO 3 − group or C 1 -C 4 hydrocarbon moiety substituted with a carboxylic group, or a salt thereof;
R 2 =NR 3 R 4 moiety, OR 5 moiety, or cyclic NR 6 moiety, wherein R 3 , R 4 , R 5 =hydrogen or C 1 -C 18 hydrocarbon moiety or C 1 -C 18 hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group, wherein R 3 , R 4 and R 5 are identical or different;
R 6 =C 3 -C 8 hydrocarbon moiety or C 3 -C 8 hydrocarbon moiety, wherein at least one carbon atom is substituted by a heteroatom; and
n=1-3, and
wherein the pH-value of the electroplating bath ranges from 2 to 6.

2. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath further comprises an alkali metal or ammonium benzoate at a concentration ranging from 0.005 to 5 g/l.

3. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath comprises at least one compound having the general formula (I), wherein
R 1 =C 1 -C 8 hydrocarbon moiety substituted with a SO 3 − group or C 1 -C 4 hydrocarbon moiety substituted with a carboxylic group;
R 2 =NR 3 R 4 moiety, OR 5 moiety, or cyclic NR 6 moiety, wherein R 3 , R 4 , R 5 =hydrogen or C 1 -C 18 hydrocarbon moiety or C 1 -C 18 hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group, wherein R 3 , R 4 and R 5 are identical or different;
R 6 =C 4 -C 8 hydrocarbon moiety or C 3 -C 8 hydrocarbon moiety, wherein at least one carbon atom is substituted by a heteroatom; and
n=1 or 2.

4. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath comprises at least one compound having the general formula (I), wherein
R 1 =C 1 -C 8 hydrocarbon moiety substituted with a SO 3 − group or C 1 -C 4 hydrocarbon moiety substituted with a carboxylic group;
R 2 =NR 3 R 4 moiety, OR 5 moiety, or cyclic NR 6 moiety, wherein R 3 , R 4 , R 5 =hydrogen or C 1 -C 8 , hydrocarbon moiety or C 1 -C 8 , hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group, wherein R 3 , R 4 and R 5 are identical or different;
R 6 =C 4 or C 5 hydrocarbon moiety or C 4 -C 5 hydrocarbon moiety, wherein at least one carbon atom is substituted by a sulfur or oxygen atom; and
n=1.

5. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath comprises at least one compound having the general formula (I), wherein
R 1 =n-ethyl-SO 3 − , n-propyl-SO 3 − , n-butyl-SO 3 − , CH 2 —COOH or a salt thereof, moiety;
R 2 =NH 2 , N(ethyl) 2 , O(ethyl), OH moiety, or cyclic NR 6 moiety, wherein R 6 =C 4 or C 5 hydrocarbon moiety or C 4 -C 5 hydrocarbon moiety, wherein at least one carbon atom is substituted by a sulfur or an oxygen atom; and
n=1.

6. Galvanic nickel electroplating bath according to claim 1 characterized in that the working temperature ranges from 40° C. to 70° C.

7. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath comprises the at least one compound having the general formula (I) at a concentration ranging from 0.005 to 10 g/l.

8. Galvanic nickel electroplating bath according to claim 1 characterized in that the at least one moiety C(O)R 2 is in ortho, meta and/or para position at the aromatic ring.

9. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath further comprises chloral hydrate at a concentration ranging from 0.005 to 5 g/l.

10. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath further comprises at least one compound selected from brighteners, leveling agents, internal stress reducers, and wetting agents, at a concentration ranging from 0.001 to 8 g/l.

11. Galvanic nickel electroplating bath according to claim 1 characterized in that the electroplating bath comprises additionally at least one bright nickel additive which is, if used without at least one compound having the general formula (I), unsuitable for depositing semi-bright nickel deposits.

12. Galvanic nickel electroplating bath according to claim 1 characterized in that R 1 =CH 2 —COOH or a salt thereof.

13. Galvanic nickel electroplating bath according to claim 1 characterized in that R 1 =C 1 -C 4 hydrocarbon moiety substituted with a SO 3 − group.

14. Method for depositing a semi-bright nickel coating on an electrically conductive work piece comprising the following method steps:
i) bringing the work piece into contact with the galvanic nickel electroplating bath according to claim 1 ;
ii) bringing at least one anode into contact with the galvanic nickel electroplating bath;
iii) applying a voltage across the work piece and the at least one anode; and
iv) electrodepositing a semi-bright nickel coating on the work piece.

15. A process for depositing a bright nickel coating, comprising the following method steps:
i) bringing the work piece into contact with the galvanic nickel electroplating bath according to claim 1 , wherein additionally a primary brightener is added to the galvanic nickel electroplating bath;
ii) bringing at least one anode into contact with the galvanic nickel electroplating bath;
iii) applying a voltage across the work piece and the at least one anode; and
iv) electrodepositing a bright nickel coating on the work piece.

16. Galvanic nickel electroplating bath for depositing a semi-bright nickel coating characterized in that the electroplating bath comprises at least one compound having the general formula (I)

wherein R 1 =C 1 -C 4 hydrocarbon moiety substituted with a SO 3 − group or CH 2 —COOH or a salt thereof;
R 2 =NR 3 R 4 moiety, OR 5 moiety, or cyclic NR 6 moiety, wherein R 3 , R 4 , R 5 =hydrogen or C 1 -C 18 hydrocarbon moiety or C 1 -C 18 hydrocarbon moiety substituted with at least an aromatic and/or a heteroaromatic group, wherein R 3 , R 4 and R 5 are identical or different;
R 6 =C 3 -C 8 hydrocarbon moiety or C 3 -C 8 hydrocarbon moiety, wherein at least one carbon atom is substituted by a heteroatom; and
n=1-3.

Assignees

• Atotech Deutschland Gmbh

Inventors

• Schulz Klaus-Dieter
• Hartmann Philip
• Wachter Philipp
• Briese Mike
• Brunner Heiko
• Richter Richard
• Kohlmann Lars

Classifications

• C25D3/18 Primary

  Heterocyclic compounds · CPC title

• C25D3/562 Primary

  containing more than 50% by weight of iron or nickel or cobalt · CPC title

• C25D3/12 Primary

  of nickel or cobalt · CPC title

• C07D413/06

  linked by a carbon chain containing only aliphatic carbon atoms · CPC title

• C07D401/06

  linked by a carbon chain containing only aliphatic carbon atoms · CPC title