Optical glass, optical element blank, glass material for press forming, optical element, and process for producing these

Patent metadata

Field	Value
Publication number	US-9656904-B2
Application number	US-201414895290-A
Country	US
Kind code	B2
Filing date	Jun 3, 2014
Priority date	Jun 4, 2013
Publication date	May 23, 2017
Grant date	May 23, 2017

Abstract

An aspect of the present invention relates to an optical glass which contains P 5+ , Al 3+ , Ba 2+ , and R 2+ (R 2+ is one or more selected from the group including of Mg 2+ , Ca 2+ , Sr 2+ , and Zn 2+ ) as essential cationic components and O 2− and F − as essential anionic components, the total content of P 5+ , Al 3+ , Ba 2+ , R 2+ , and R′ + (R′ + is one or more selected from the group including of Li + , Na + , and K + ) in the cationic component being 86% or higher, the Al 3+ /P 5+ molar ratio being 0.70 or higher, the Al 3+ /(Ba 2+ +R 2+ ) molar ratio being 0.40 or higher, and the Ba 2+ /(Ba 2+ +R 2+ ) molar ratio being in the range of 0.50 to 0.85, and which has an Abbe's number νd of 72 or larger but less than 80, the refractive index nd and the Abbe's number νd satisfying: nd≧2.179−0.0085×νd.

First claim

What is claimed is:

1. An optical glass, wherein the optical glass contains P 5+ , Al 3+ , Ba 2+ , and R 2+ , wherein R 2+ is one or more selected from the group consisting of Mg 2+ , Ca 2+ , Sr 2+ , and Zn 2+ , as essential cationic components, and contains O 2− and F − as essential anionic components, a total content of P 5+ , Al 3+ , Ba 2+ , R 2+ , and R′ + , wherein R′ + is one or more selected from the group consisting of Li + , Na + , and K + , in a cationic component proportion being 86% or more, a molar ratio Al 3+ /P 5+ of an Al 3+ content to a P 5+ content being 0.70 or more, a molar ratio Al 3+ /(Ba 2+ +R 2+ ) of the Al 3+ content to a total content of Ba 2 and R 2+ being 0.40 or more and a molar ratio Ba 2+ /(Ba 2+ +R 2+ ) of a Ba 2+ content to a total content of Ba 2+ and R 2+ being in a range of 0.50 to 0.85, and the optical glass has an Abbe's number νd of 72 or more but less than 80, a refractive index nd and the Abbe's number νd satisfying the following formula (A):
nd≧ 2.179−0.0085×ν d   (A).

2. The optical glass according to claim 1 , wherein an O 2− content is in a range of 40 to 70%, and a F − content is in a range of 30 to 60%, in an anionic component proportion.

3. The optical glass according to claim 1 , wherein the total content of Ba 2+ and R 2+ is in a range of 30 to 60%, in the cationic component proportion.

4. The optical glass according to claim 1 , wherein the P 5+ content is in a range of 15 to 35%, in the cationic component proportion.

5. The optical glass according to claim 1 , wherein a molar ratio O 2− /P 5+ of the O 2− content to the P 5+ content is 3.30 or more.

6. The optical glass according to claim 1 , wherein the Al 3+ content is in a range of 18 to 35%, in the cationic component proportion.

7. The optical glass according to claim 1 , wherein a content of RE 3+ (RE 3+ is one or more selected from the group consisting of Y 3+ , La 3+ , Gd 3+ and Lu 3+ ) is 14% or less, in the cationic component proportion.

8. The optical glass according to claim 1 , wherein a liquidus temperature is 850 degrees Celsius or less.

9. The optical glass according to claim 1 , wherein a crystallization temperature Tc and a glass transition temperature Tg satisfy the following formula (1):
120 degrees Celsius≦( Tc−Tg )   (1)

10. An optical element made of an optical glass described in claim 1 .

11. A process for producing a glass material for press forming comprising:
a step of forming an optical glass described in claim 1 into a glass material for press forming.

12. An optical element blank made of an optical glass described in claim 1 .

13. A process for producing an optical element comprising:
a step of making an optical element at least by polishing an optical element blank described in claim 12 .

14. A glass material for press forming made of an optical glass described in claim 1 .

15. A process for producing an optical element blank comprising:
a step of making the optical element blank by performing press-forming using a press-forming mold, in a state where a glass material for press forming described in claim 14 is heated to be softened.

16. A process for producing an optical element comprising:
a step of making an optical element by performing precision press-forming using a press-forming mold, in a state where a glass material for press forming described in claim 14 is heated to be softened.

Assignees

• Hoya Corp

Inventors

• Shiota Yuki

Classifications

• C03B23/03

  by press-bending between shaping moulds · CPC title

• C03C3/23

  containing halogen and at least one oxide, e.g. oxide of boron · CPC title

• C03C3/247 Primary

  containing fluorine and phosphorus · CPC title