Near-infrared absorption glass, element and filter

Patent metadata

Field	Value
Publication number	US-9321673-B2
Application number	US-201213622084-A
Country	US
Kind code	B2
Filing date	Sep 18, 2012
Priority date	Feb 17, 2012
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

The invention provides a near-infrared absorption glass, a near-infrared absorption element and a near-infrared absorption filter each with good chemical stability and transmissivity property in the visible range. When such glass is 1 mm thick, the transmissivity of such glass is more than 80% at 400 nm, and more than 85% at 500 nm. The near-infrared absorption glass comprises cations such as P 5+ , Al 3+ , Li + , R 2+ and Cu 2+ as well as anions such as O 2− and F − , wherein the R 2+ refers to Mg 2+ , Ca 2 , Sr 2+ and Ba 2+ , and wherein the content of the said Li + is 1-15%. Furthermore, the water resistant stability D W of the said near-infrared absorption glass is Class 1 and the acid resistant stability D A is above Class 4.

First claim

What is claimed is:

1. A near-infrared absorption glass comprising P 5+ , Al 3+ , Li + , R 2+ , Cu 2+ , O 2− and F − , wherein the R 2+ is 54-65% by cation weight and comprises a combination of Mg 2+ , Ca 2+ , Sr 2+ and Ba 2+ ; wherein F − and O 2− comprise 100% of the anion content and O 2− comprises 40-55% by anion weight; and wherein the near-infrared absorption glass comprises: a transmissivity of more than 80% at 400 nm, more than 85% at 500 nm, and more than 58% at 600 nm, further wherein the transmissivity is measured through a near-infrared absorption glass having a thickness of 1 mm; a water resistant stability D W of the near-infrared absorption glass is Class 1; and an acid resistant stability D A is above Class 4.

2. The near-infrared absorption glass of claim 1 , wherein the transmissivity is more than 88% at 400 nm, and more than 90% at 500 nm.

3. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 15-35% of P 5+ , 5-20% of Al 3+ , 1-15% of Li + , 0-10% of Na + and 0.1-8% of Cu 2+ .

4. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 15-35% of P 5+ , 5-20% of Al 3+ , 1-10% of Li + , 0-10% of Na + and 0.1-8% of Cu 2+ .

5. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 15-35% of P 5+ , 5-20% of Al 3+ , 2-5% of Li + , 0-10% of Na + and 0.1-8% of Cu 2+ .

6. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 20-30% of P 5+ , 10-15% of Al 3+ , 1-15% of Li + , 0-5% of Na + and 1.2-5% of Cu 2+ .

7. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 20-30% of P 5+ , 10-15% of Al 3+ , 1-10% of Li + , 0-5% of Na + and 1.2-5% of Cu 2+ .

8. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 20-30% of P 5+ , 10-15% of Al 3+ , 2-5% of Li + , 0-5% of Na + and 1.2-5% of Cu 2+ .

9. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 21-25% of P 5+ , 10-15% of Al 3+ , 1-15% of Li + , 0.5-3% of Na + and 1.2-5% of Cu 2+ .

10. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 21-25% of P 5+ , 10-15% of Al 3+ , 1-10% of Li + , 0.5-3% of Na + and 1.2-5% of Cu 2+ .

11. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 21-25% of P 5+ , 10-15% of Al 3+ , 2-5% of Li + , 0.5-3% of Na + and 1.2-5% of Cu 2+ .

12. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 15-35% of P 5+ , 5-20% of Al 3+ , 1-15% of Li + , 0-10% of Na + , 0-3% of K + , 0.1-8% of Cu 2+ , 0.1-10% of Mg 2+ , 1-20% of Ca 2+ , 15-35% of Sr 2+ and 10-30% of Ba 2+ .

13. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 20-30% of P 5+ , 10-15% of Al 3+ , 1-10% of Li + , 0-5% of Na + , 0-3% of K + , 1.2-5% of Cu 2+ , 2-8% of Mg 2+ , 5-15% of Ca 2+ , 21-30% of Sr 2+ and 15-30% of Ba 2+ .

14. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 21-25% of P 5+ , 10-15% of Al 3+ , 2-5% of Li + , 0.5-3% of Na + , 1.8-3% of Cu 2+ , 3-7% of Mg 2+ , 7-11% of Ca 2+ , 23-28% of Sr 2+ and 21-30% of Ba 2+ .

15. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by cation weight: 21-25% of P 5+ , 10-15% of Al 3+ , 2-5% of Li + , 0.5-3% of Na + , 1.8-3% of Cu 2+ , 3-7% of Mg 2+ , 7-11% of Ca 2+ , 23-28% of Sr 2+ and 21-25% of Ba 2+ .

16. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by anion weight: 48-57% of F − and 43-52% of O 2− .

17. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises F − and O 2− , wherein F − is more than 50% but no more than 57% by anion weight, and wherein O 2− is no less than 43% but less than 50% by anion weight.

18. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by anion weight: 51-55% of F − and 45-49% of O 2− .

19. The near-infrared absorption glass of claim 1 , wherein the near-infrared absorption glass comprises by anion weight: 51-53% of F − and 47-49% of O 2− .

20. A near-infrared absorption element comprising the near-infrared absorption glass of claim 1 .

21. A near-infrared absorption filter comprising the near-infrared absorption glass of claim 1 .

Assignees

• Cdgm Glass Co Ltd

Inventors

• Sun Wei
• Deng Yu

Classifications

• C03C4/082

  for infrared absorbing glass · CPC title

• C03C3/247 Primary

  containing fluorine and phosphorus · CPC title

• C03C4/08

  for glass selectively absorbing radiation of specified wave lengths · CPC title

• G02B5/22 Primary

  Absorbing filters {(G02B5/201 - G02B5/208 take precedence)} · CPC title