Optical glass, glass material for press molding, optical element, method for producing glass material for press molding, and method for producing optical element

Patent metadata

Field	Value
Publication number	US-9481600-B2
Application number	US-201314414249-A
Country	US
Kind code	B2
Filing date	Jul 18, 2013
Priority date	Jul 18, 2012
Publication date	Nov 1, 2016
Grant date	Nov 1, 2016

Abstract

Provided are an optical fluorophosphate glass having excellent optical characteristics and also excellent processability, a glass material for press molding and an optical element each including the glass, and methods for producing the glass material and the optical element. The optical glass includes P 5+ as a cationic component and O 2− and F − as anionic components, wherein the optical glass has a content of F − of 40 anionic % or less, an abrasion factor F A of 420 or higher, and a fragility index value B of 4500 μm −1/2 or lower.

First claim

The invention claimed is:

1. An optical glass comprising P 5+ , Al 3+ , alkali metal ions, and alkaline earth metal ions as cationic components and O 2− and F − as anionic components, wherein
a content of P 5+ is 20 to 45 cationic %,
a content of Al 3+ is 16 to 30 cationic %,
a total content of R + of the alkali metal ions exceeds 0 cationic % and is 12 cationic % or less,
a total content of R 2+ of the alkaline earth metal ions is 20 cationic % or more,
a content of Rb + is 0 to 3 cationic %,
a content of Cs + is 0 to 3 cationic %,
a content of Zn 2+ is 0 to 3 cationic %,
a content of F − of 40 anionic % or less,
a mole ratio (R + /P 5+ ) of the total content R + of the alkali metal ions to the content of P 5+ is 0.070 to 0.50, and
the optical glass has an abrasion factor FA of 420 or higher, a fragility index value B of 4000 μm −1/2 or lower, and an Abbe number νd of 70 or lower.

2. The optical glass according to claim 1 , wherein
the content of F − is 18 to 40 anionic %, and
a content of O 2− is 60 to 82 anionic %.

3. The optical glass according to claim 1 , wherein a mole ratio (O 2− /P 5+ ) of a content of O 2− to the content of P 5+ is 3.5 or higher.

4. The optical glass according to claim 1 , wherein a mole ratio (Li + /R + ) of a content of Li + to the total content R + of the alkali metal ions exceeds 0.

5. The optical glass according to claim 1 , wherein a mole ratio (R 2+ /P 5+ ) of the total content R 2+ of the alkaline earth metal ions to the content of P 5+ is 0.7 to 1.4.

6. The optical glass according to claim 1 , wherein the optical glass has a glass transition temperature of 580° C. or lower.

7. The optical glass according to claim 1 , wherein
the optical glass does not have a crystallization peak temperature Tc, or
the optical glass has a crystallization peak temperature Tc, and the difference (Tc−Tg) between the crystallization peak temperature Tc and a glass transition temperature Tg is 80° C. or more.

8. The optical glass according to claim 1 , wherein the optical glass has a liquidus temperature of 850° C. or lower.

9. The optical glass according to claim 1 , wherein the optical glass has a deviation ΔPg,F of a partial dispersion ratio Pg,F of 0.0158 or more.

10. The optical glass according to claim 1 , wherein the optical glass is to be subjected to a polishing process.

11. A glass material for press molding, comprising the optical glass according to claim 1 .

12. An optical element blank comprising the optical glass according to claim 1 .

13. An optical element comprising the optical glass according to claim 1 .

14. A method for producing a glass material for press molding, comprising a step of processing a molded glass article comprising the optical glass according to claim 1 .

15. A method for producing an optical element, comprising a step of processing a molded glass article comprising the optical glass according to claim 1 .

16. An optical glass comprising:
P 5+ , Al 3+ , alkali metal ions, and alkaline earth metal ions as cationic components; and
O 2− and F − as anionic components, wherein
a content of P 5+ is 20 to 45 cationic %,
a content of Al 3+ is 16 to 30 cationic %,
a total content R + of the alkali metal ions exceeds 0 cationic % and is 12 cationic % or less,
a total content R 2+ of the alkaline earth metal ions is 20 cationic % or more,
a content of Rb + is 0 to 3 cationic %,
a content of Cs + is 0 to 3 cationic %,
a content of Zn 2+ is 0 to 3 cationic %,
a content of F − is 18 to 40 anionic %,
a content of O 2− is 60 to 82 anionic %,
a mole ratio (R + /P 5+ ) of the total content R + of the alkali metal ions to the content of P 5+ is 0.070 to 0.50,
a mole ratio (O 2− /P 5+ ) of the content of O 2− to the content of P 5+ is 3.5 or higher, and
the optical glass has an Abbe number νd of 70 or lower.

Assignees

• Hoya Corp

Inventors

• Tanno Yoshitake
• Shiota Yuki

Classifications

• C03C3/247 Primary

  containing fluorine and phosphorus · CPC title

• G02B1/02

  made of crystals, e.g. rock-salt, semi-conductors (G02B1/08 takes precedence) · CPC title