Anisotropic rare earth magnet powder, method for producing the same, and bonded magnet

Patent metadata

Field	Value
Publication number	US-9640319-B2
Application number	US-201013514943-A
Country	US
Kind code	B2
Filing date	Oct 8, 2010
Priority date	Dec 9, 2009
Publication date	May 2, 2017
Grant date	May 2, 2017

Abstract

The anisotropic rare earth magnet powder of the present invention includes powder particles having R 2 TM 14 B 1 -type crystals of a tetragonal compound of a rare earth element (R), boron (B), and a transition element (TM) having an average crystal grain diameter of 0.05 to 1 μm, and enveloping layers containing at least a rare earth element (R′) and copper (Cu) and enveloping surfaces of the crystals. Owing to the presence of the enveloping layers, coercivity of the anisotropic rare earth magnet powder can be remarkably enhanced without using a scarce element such as Ga and Dy.

First claim

The invention claimed is:

1. An anisotropic rare earth magnet powder including powder particles comprising:
agglomerates of R 2 TM 14 B 1 -type crystals of a tetragonal compound consisting of a rare earth element (hereinafter referred to as “R”), boron (hereinafter referred to as “B”), and a transition element (hereinafter referred to as “TM”), the crystals having an average crystal grain diameter of 0.05 to 1 μm, and
enveloping layers containing at least neodymium (Nd) and copper (Cu), wherein
surfaces of the R 2 TM 14 B 1 -type crystals are enveloped by the enveloping layers, and,

when the whole powder particles are taken as 100 atomic %, the powder particles contain:
about 0.05 atomic % to about 2 atomic % of Cu;
11.5 to 15 atomic % of all the rare earth element (Rt),
5.5 to 8 atomic % of B; and

wherein the powder particles have an atomic ratio of Cu, which is a ratio of a total number of Cu atoms to a total number of atoms of all the rare earth element (Rt), falling within the range of 1 to 6%, and
coercivity (iHc) of the magnet powder is 1130 kA/m or more.

2. The anisotropic rare earth magnet powder according to claim 1 , wherein the enveloping layers comprise a diffusion layer in which at least Nd and Cu are diffused into crystal grain boundaries of the R 2 TM 14 B 1 -type crystals.

3. A method for producing the anisotropic rare earth magnet powder according to claim 1 , comprising:
a mixing step of obtaining a mixed raw material of a magnet raw material capable of generating agglomerates of R 2 TM 14 B 1 -type crystals of a tetragonal compound of R, B and TM, and a diffusion raw material to serve as a supply source of at least Nd and Cu; and
a diffusion step of heating the mixed raw material to diffuse at least Nd and Cu onto surfaces or into crystal grain boundaries of the R 2 TM 14 B 1 -type crystals.

4. The method for producing anisotropic rare earth magnet powder according to claim 3 , wherein the magnet raw material contains an approximate theoretical composition of the R 2 TM 14 B 1 containing 11.6 to 12.7 atomic % of R and 5.5 to 7 atomic % of B when the entire magnet raw material is taken as 100 atomic %.

5. The method for producing anisotropic rare earth magnet powder according to claim 3 , wherein the magnet raw material is obtained through:
a disproportionation step of causing a base alloy to absorb hydrogen and undergo a disproportionation reaction; and
a recombination step of dehydrogenating and recombining the base alloy after the disproportionation step.

6. The method for producing anisotropic rare earth magnet powder according to claim 5 , wherein the magnet raw material is obtained further through a low-temperature hydrogenation step of allowing the base alloy to absorb hydrogen in 600° C. or less, before the disproportionation step.

7. A bonded magnet, comprising:
the anisotropic rare earth magnet powder according to claim 1 ; and
a resin bonding the powder particles of the anisotropic rare earth magnet powder together.

8. The anisotropic rare earth magnet powder according to claim 1 , wherein
the powder particles contain no more than 3 atomic % of at least one of the group consisting of Ti, V, Zr, Nb, Ni, Cr, Mn, Mo, Hf, W, Ta, Ga, Si, Zn and Sn, when the whole powder particles are taken as 100 atomic %.

9. The anisotropic rare earth magnet powder according to claim 1 , wherein
the powder particles contain 0.1 to 10 atomic % of Co, when the whole powder particles are taken as 100 atomic %.

10. The anisotropic rare earth magnet powder according to claim 1 , wherein
the powder particles contain, when the whole powder particles are taken as 100 atomic %:
no more than 3 atomic % of at least one of the group consisting of Ti, V, Zr, Nb, Ni, Cr, Mn, Mo, Hf, W, Ta, Ga, Si, Zn and Sn; and
0.1 to 10 atomic % of Co.

11. An anisotropic rare earth magnet powder including powder particles comprising:
agglomerates of R 2 TM 14 B 1 -type crystals of a tetragonal compound consisting of a rare earth element (hereinafter referred to as “R”), boron (hereinafter referred to as “B”), and a transition element (hereinafter referred to as “TM”), the crystals having an average crystal grain diameter of 0.05 to 1 μm, and
enveloping layers containing at least neodymium (Nd), copper (Cu), and aluminum (Al), wherein
surfaces of the R 2 TM 14 B 1 -type crystals are enveloped by the enveloping layers, and,

when the whole powder particles are taken as 100 atomic %, the powder particles contain:
about 0.05 atomic % to about 2 atomic % of Cu;
11.5 to 15 atomic % of all the rare earth element (Rt);
5.5 to 8 atomic % of B; and
0.1 to 5 atomic % of Al;

wherein the powder particles have an atomic ratio of Cu, which is a ratio of a total number of Cu atoms to a total number of atoms of all the rare earth element (Rt), falling within the range of 0.6 to 11.8%; and
coercivity (iHc) of the magnet powder is 1130 kA/m or more.

12. The anisotropic rare earth magnet powder according to claim 11 , wherein
the powder particles contain no more than 3 atomic % of at least one of the group consisting of Ti, V, Zr, Nb, Ni, Cr, Mn, Mo, Hf, W, Ta, Ga, Si, Zn and Sn, when the whole powder particles are taken as 100 atomic %.

13. The anisotropic rare earth magnet powder according to claim 11 , wherein
the powder particles contain 0.1 to 10 atomic % of Co, when the whole powder particles are taken as 100 atomic %.

14. The anisotropic rare earth magnet powder according to claim 11 , wherein
the powder particles contain, when the whole powder particles are taken as 100 atomic %:
no more than 3 atomic % of at least one of the group consisting of Ti, V, Zr, Nb, Ni, Cr, Mn, Mo, Hf, W, Ta, Ga, Si, Zn and Sn; and
0.1 to 10 atomic % of Co.

Assignees

• Honkura Yoshinobu
• Mishima Chisato
• Yamazaki Masao
• Aichi Steel Corp

Inventors

• Honkura Yoshinobu
• Mishima Chisato
• Yamazaki Masao

Classifications

• H01F1/0578 Primary

  bonded together · CPC title

• H01F1/0572

  with a protective layer · CPC title

• B22F9/023

  Hydrogen absorption · CPC title

• C22C38/002

  containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60 · CPC title

• H01F41/0293 Primary

  diffusion of rare earth elements, e.g. Tb, Dy or Ho, into permanent magnets · CPC title