Method for optimizing catalyst/oil mixing in an FCC reactor feed zone

Patent metadata

Field	Value
Publication number	US-9394488-B2
Application number	US-201313860798-A
Country	US
Kind code	B2
Filing date	Apr 11, 2013
Priority date	Apr 19, 2012
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

A method of improving the uniformity of the contacting of a heavy oil feed with FCC cracking catalyst in the feed zone of an FCC cracking riser in which the heavy oil feed is injected into the catalyst in the riser by means of feed injectors located around the riser, the method comprising minimizing the differences in the temperature profile in the oil/catalyst mixture across the feed zone by varying the oil feed rate to the injectors.

First claim

What is claimed is:

1. A method of improving the uniformity of the contacting of a heavy oil feed with an FCC cracking catalyst in a feed zone of an FCC cracking riser in which the heavy oil feed is injected into the riser by means of feed injectors located around the riser, wherein the heavy oil contacts the catalyst in the feed zone to create an oil/catalyst mixture, the method comprising:
a) Measuring the temperature profile of the oil/catalyst mixture in the feed/mixing zone of the FCC riser in a feed injector step test in which the oil feed rate to each feed injector is varied while the temperature profile information is recorded;
b) Developing a temperature response matrix model from the temperature profile information from Step a), wherein the temperature response matrix model indicates a temperature change with one injector closed from a base case with all injectors fully open;
c) Determining from the temperature response matrix model the optimum feed rate for each injector at which the temperature difference across the feed zone is minimized by using the temperature response matrix model to develop a predictive model from an optimization algorithm; and
d) Adjusting the oil feed rate into the feed zone through each of the individual feed injectors at a flow rate based on the determination from the temperature response matrix model.

2. The method according to claim 1 , wherein at least a portion of the measurements taken in Step a) for the temperature response matrix model are taken with one feed injector closed while the other feed injectors are fully open, and repeating this measurement for each (i.e., closed) feed injector.

3. The method according to claim 1 , wherein the differences in the temperature profile in the oil/catalyst mixture across the feed zone are minimized in response to temperatures measured above the level of the feed injectors.

4. The method according to claim 1 , wherein the temperature profile of the oil/catalyst mixture in the feed zone of the FCC riser is measured at a level above, but not more than 10 meters above, the level of the feed injectors.

5. The method according to claim 4 , wherein the temperature profile of the oil/catalyst mixture in the feed zone of the FCC riser is measured at a level above, but not more than 5 meters above, the level of the feed injectors.

6. The method according to claim 5 , wherein the differences in the temperature profile in the oil/catalyst mixture across the feed zone are measured by the use of wall temperature indicators.

7. The method according to claim 6 , wherein the temperature profile is determined by using data from at least four wall temperature indicators.

8. The method according to claim 1 , wherein the adjusting of the oil feed rate in Step d) results in minimizing the differences in the temperature profile in the oil/catalyst mixture across the feed zone.

9. The method according to claim 1 , wherein the oil feed rate for each feed injector at which the temperature difference across the feed zone is minimized is determined by optimization of the temperature response matrix model of the temperatures measured in Step a) using a spreadsheet optimization.

10. The method according to claim 1 , wherein the oil feed rate for each feed injector is determined by real time optimization of the temperature response matrix model of the temperatures measured in Step a) using a real time optimization model utilizing the measured temperatures in the riser during operation as inputs for the optimization.

11. The method according to claim 10 , wherein the oil feed rate for each feed injector is controlled automatically in response to the real time optimization model.

12. The method according to claim 11 , wherein the flow rate of the oil teed to the feed injectors is controlled real time by means of automated control valves.

13. The method according to claim 12 , wherein the temperature profile in Step a) is determined by using data from at least four wall temperature indicators.

14. The method according to claim 13 , wherein the data from Step a) is input into a logic control device wherein Steps b) and c) are performed, then the logic control device sends an setpoint output to the automated control valves based on the optimization calculations from the temperature response matrix model.

15. The method according to claim 14 , wherein the logic control device is either a programmable logic controller (PLC) or a distributed control system (DCS).

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Du Bing
• Chen Alvin U
• Smalley Christopher G
• Kobayashi Kentaro
• Sugita Masaaki

Classifications

• C10G11/187 Primary

  Controlling or regulating · CPC title

• B01J2208/00902

  Nozzle-type feeding elements · CPC title

• C10G2300/4006

  Temperature · CPC title

• B01J8/085

  Feeding reactive fluids (for solid material, see B01J8/0015) · CPC title

• B01J8/1809

  Controlling processes · CPC title