Fluid cracking process and apparatus for maximizing light olefins or middle distillates and light olefins

Patent metadata

Field	Value
Publication number	US-9452404-B2
Application number	US-201213547807-A
Country	US
Kind code	B2
Filing date	Jul 12, 2012
Priority date	Jul 12, 2012
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

A fluid catalytic cracking apparatus and process is disclosed, providing for efficient conversion of heavy hydrocarbon feeds to light olefins, aromatics, and gasoline. A countercurrent flow reactor operating in bubbling or turbulent fluidization regimes is integrated with a fluid catalytic cracking riser reactor. A heavy hydrocarbon feed is catalytically cracked to naphtha and light olefins in the riser reactor, a co-current flow reactor. To enhance the yields and selectivity to light olefins, cracked hydrocarbon products from the riser reactor, such as C 4 and naphtha range hydrocarbons, may be recycled and processed in the countercurrent flow reactor. The integration of the countercurrent flow reactor with a conventional FCC riser reactor and catalyst regeneration system may overcome heat balance issues commonly associated with two-stage cracking processes, may substantially increase the overall conversion and light olefins yield, and/or may increases the capability to process heavier feedstocks.

First claim

What is claimed:

1. A process for the catalytic cracking of hydrocarbons, comprising:
regenerating a spent catalyst comprising a first cracking catalyst having a first average particle size and density and a second cracking catalyst having a second average particle size and density in a catalyst regeneration vessel to form a regenerated catalyst comprising the first cracking catalyst and the second cracking catalyst, wherein the average particle size of the first cracking catalyst is less than the average particle size of the second cracking catalyst;
contacting in co-current flow a first hydrocarbon feed with a first portion of the regenerated catalyst in a riser reactor to produce a first effluent comprising a first cracked hydrocarbon product and a spent mixed catalyst fraction;
feeding a second portion of the regenerated catalyst to a second cracking reactor;
concurrently in the second cracking reactor:
separating the first cracking catalyst from the second cracking catalyst based on at least one of density and particle size;
contacting in countercurrent flow a second hydrocarbon feed with the second cracking catalyst to produce a second cracked hydrocarbon product;

recovering a second effluent from the second cracking reactor comprising the second cracked hydrocarbon product and the first cracking catalyst as an effluent from the upper portion of the second cracking reactor and
recovering a third effluent comprising spent second catalyst from the bottom of the second cracking reactor
feeding the first effluent and the second effluent to a disengagement vessel to separate the spent mixed catalyst fraction and the separated first cracking catalyst from the first and second cracked hydrocarbon products;
feeding the separated catalysts from the disengagement vessel to the catalyst regeneration vessel as the spent catalyst.

2. The process of claim 1 , further comprising feeding the separated catalysts from the disengagement vessel to a spent catalyst stripper to separate additional hydrocarbons from the separated catalysts before feeding of the separated catalysts to the catalyst regeneration vessel.

3. The process of claim 1 , wherein the first hydrocarbon fraction comprises at least one of a C4 hydrocarbon fraction, a naphtha fraction, and a heavy hydrocarbon fraction.

4. The process of claim 1 , wherein the second hydrocarbon fraction comprises at least one of a C4 hydrocarbon fraction and a naphtha fraction.

5. The process of claim 4 , wherein the C4 hydrocarbon fraction is fed to the second cracking reactor at an elevation below the naphtha fraction.

6. The process of claim 1 , further comprising contacting the second effluent with a third hydrocarbon fraction intermediate the second cracking reactor and the disengagement vessel to quench the second effluent, crack the third hydrocarbon fraction, or a combination thereof.

7. The process of claim 6 , further comprising controlling a temperature of the quenched effluent by adjusting a flow rate of the third hydrocarbon fraction.

8. The process of claim 6 , wherein the third hydrocarbon fraction comprises light cycle oil.

9. The process of claim 1 , further comprising contacting the second effluent with a quench medium.

10. The process of claim 1 , wherein the riser reactor operates with a superficial gas velocity in the range of 3 m/s to 10 m/s proximate the inlet and in the range of 10 m/s to 25 m/s proximate the outlet.

11. The process of claim 1 , wherein the second cracking reactor operates with a superficial gas velocity in the range of 0.01 m/s to 1.0 m/s, and wherein the superficial gas velocity in the second cracking reactor is sufficient to separate the first cracking catalyst from the second cracking catalyst.

12. The process of claim 1 , wherein the first cracking catalyst comprises Y-type zeolite catalyst and the second cracking catalyst comprises a ZSM-5 catalyst.

13. The process of claim 1 , wherein the second cracking reactor comprises a lower stripping zone, an intermediate reaction zone, and an upper catalyst separation zone, the process further comprising operating the second cracking reactor such that the intermediate reaction zone has a catalyst bed density in the range from about 480 kg/m 3 to about 800 kg/m 3 .

14. The process of claim 13 , further comprising feeding a stripping medium comprising steam or an inert gas to the stripping zone to separate cracked hydrocarbons from the second cracking catalyst.

15. The process of claim 1 , further comprising feeding fresh or make-up first cracking catalyst to the catalyst regeneration vessel.

16. The process of claim 1 , further comprising feeding fresh or make-up second cracking catalyst to at least one of the catalyst regeneration vessel and the second cracking reactor.

17. The process of claim 1 , further comprising feeding fresh or make-up second cracking catalyst to the second cracking reactor.

Assignees

• Marri Rama Rao
• Soni Dalip Singh
• Kumar Pramod
• Lummus Technology Inc

Inventors

• Marri Rama Rao
• Soni Dalip Singh
• Kumar Pramod

Classifications

• C10G11/18 Primary

  according to the "fluidised-bed" technique · CPC title

• C10G51/06

  plural parallel stages only · CPC title

• C10G11/182

  Regeneration · CPC title

• C10G2300/1044

  Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C · CPC title

• B01J8/0055

  using cyclones · CPC title