Methods and fuel processing apparatuses for upgrading a pyrolysis oil stream and a hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-9523042-B2
Application number	US-201213563011-A
Country	US
Kind code	B2
Filing date	Jul 31, 2012
Priority date	Jul 31, 2012
Publication date	Dec 20, 2016
Grant date	Dec 20, 2016

Abstract

Methods and fuel processing apparatuses for upgrading a pyrolysis oil stream and a hydrocarbon stream are provided herein. In an embodiment, a method for upgrading a pyrolysis oil stream and a hydrocarbon stream includes providing a pyrolysis oil stream and providing a hydrocarbon stream separate from the pyrolysis oil stream. The pyrolysis oil stream and the hydrocarbon stream are mixed in a mixing zone and in the absence of a particulate cracking catalyst. The pyrolysis oil stream and the hydrocarbon stream are introduced in a substantially common direction into the mixing zone to form a mixture of the pyrolysis oil stream and the hydrocarbon stream. The mixture of the pyrolysis oil stream and the hydrocarbon stream are catalytically cracked in the presence of the particulate cracking catalyst.

First claim

What is claimed is:

1. A method for upgrading a pyrolysis oil stream and a hydrocarbon stream, the method comprising the steps of:
providing the pyrolysis oil stream;
providing the hydrocarbon stream separate from the pyrolysis oil stream;
mixing the pyrolysis oil stream and the hydrocarbon stream in a mixing zone located adjacent a spray head of an injection nozzle and in the absence of a particulate cracking catalyst, wherein the pyrolysis oil stream and the hydrocarbon stream are introduced in a substantially common direction into the mixing zone to form a mixture of the pyrolysis oil stream and the hydrocarbon stream; and
catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream in the presence of the particulate cracking catalyst;
wherein the pyrolysis oil stream is maintained at a temperature of less than or equal to about 80° C. up to introduction into the mixing zone; and
wherein the pyrolysis oil stream and the hydrocarbon stream are comingled for a period of less than or equal to about 2 seconds upon mixing before catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream.

2. The method of claim 1 , wherein catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream comprises comingling the particulate cracking catalyst and the mixture of the pyrolysis oil stream and the hydrocarbon stream in a reaction zone.

3. The method of claim 2 , further comprising introducing the mixture of the pyrolysis oil stream and the hydrocarbon stream into the reaction zone in the substantially common direction in which the pyrolysis oil stream and the hydrocarbon stream are introduced into the mixing zone.

4. The method of claim 1 , wherein the hydrocarbon stream is provided at a higher temperature than the pyrolysis oil stream.

5. The method of claim 1 , further comprising mixing a carrier gas and the pyrolysis oil stream prior to mixing the pyrolysis oil stream and the hydrocarbon stream.

6. The method of claim 1 , wherein providing the pyrolysis oil stream comprises pyrolyzing a biomass stream to produce the pyrolysis oil stream.

7. The method of claim 6 , wherein the pyrolysis oil stream produced from pyrolyzing the biomass stream is mixed with the hydrocarbon stream in the absence of intervening upgrading processing of the pyrolysis oil stream.

8. The method of claim 1 , wherein the pyrolysis oil stream and the hydrocarbon stream are mixed at a weight ratio of the pyrolysis oil stream to the hydrocarbon stream of from about 0.005:1 to about 0.2:1.

9. A method for upgrading a pyrolysis oil stream and a hydrocarbon stream in a fluid catalytic cracking unit including a reaction chamber and a feed distributor in fluid communication with the reaction chamber, the method comprising the steps of:
providing the hydrocarbon stream separate from the pyrolysis oil stream to the feed distributor, wherein the feed distributor comprises a pyrolysis oil feed line and a hydrocarbon feed line having respective outlets into a mixing zone for separately supporting flow of the hydrocarbon stream and the pyrolysis oil stream into the mixing zone and wherein the pyrolysis oil feed line and the hydrocarbon feed line extend in a substantially common direction to the respective outlets;
mixing the hydrocarbon stream and the pyrolysis oil stream in the mixing zone located adjacent a spray head of an injector nozzle and in the absence of a particulate cracking catalyst to form a mixture of the pyrolysis oil stream and the hydrocarbon stream; and
introducing the mixture of the pyrolysis oil stream and the hydrocarbon stream through the spray head of the injector nozzle into a reaction zone within the reaction chamber; and
catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream in the presence of the particulate cracking catalyst in the reaction zone within the reaction chamber;
wherein the pyrolysis oil stream is maintained at a temperature of less than or equal to about 80° C. up to introduction into the mixing zone; and
wherein the pyrolysis oil stream and the hydrocarbon stream are comingled for a period of less than or equal to about 2 seconds upon mixing before catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream.

10. The method of claim 9 , wherein the mixture of the pyrolysis oil stream and the hydrocarbon stream are introduced into the reaction chamber in the substantially common direction in which the pyrolysis oil stream and the hydrocarbon stream are introduced into the mixing zone.

11. The method of claim 9 , wherein the mixing zone is located outside of the reaction chamber, and wherein introducing the mixture of the pyrolysis oil stream and the hydrocarbon stream comprises introducing the mixture of the pyrolysis oil stream and the hydrocarbon stream from outside of the reaction chamber into the reaction chamber.

12. The method of claim 11 , wherein the mixing zone is located in the feed distributor, and wherein the mixture of the pyrolysis oil stream and the hydrocarbon stream is introduced into the reaction chamber from the mixing zone in the feed distributor into the reaction chamber.

13. The method of claim 9 , further comprising mixing a carrier gas and the pyrolysis oil stream in the feed distributor prior to mixing the pyrolysis oil stream and the hydrocarbon stream.

14. The method of claim 9 , wherein the hydrocarbon feed line is concentric about the pyrolysis oil feed line, and wherein the pyrolysis oil stream is provided through the pyrolysis oil feed line into the mixing zone.

15. The method of claim 9 , wherein the fluid catalytic cracking unit further comprises a separator vessel in fluid communication with the reaction zone, wherein catalytically cracking the mixture of the pyrolysis oil stream and the hydrocarbon stream produces an effluent comprising spent particulate cracking catalyst and a gaseous component, and wherein the gaseous component is separated from the spent particulate cracking catalyst in the separator vessel.

16. The method of claim 15 , wherein the fluid catalytic cracking unit further comprises a catalyst regenerator, and wherein the particulate cracking catalyst separated from the gaseous component is introduced into the catalyst regenerator.

Assignees

• Baird Lance Awender
• Palmas Paolo
• Uop Llc

Inventors

• Baird Lance Awender
• Palmas Paolo

Classifications

• C10G51/04

  including only thermal and catalytic cracking steps · CPC title

• B01J4/002

  Nozzle-type elements (nozzle-type reactors B01J19/26) · CPC title

• B01J2204/002

  the feeding side being of particular interest · CPC title

• C10G11/187

  Controlling or regulating · CPC title

• C10G2300/1011

  Biomass · CPC title