Conversion of plastics to olefin and aromatic products using temperature control

Patent metadata

Field	Value
Publication number	US-9447332-B2
Application number	US-201313764923-A
Country	US
Kind code	B2
Filing date	Feb 12, 2013
Priority date	Feb 12, 2013
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

A method of producing olefins and aromatic compounds from a feedstock includes introducing a hydrocarbon feedstock and a catalyst composition that is suitable for converting the feedstock to at least one of olefins and aromatic compounds within a reactor. The reactor has a reactor flow path having a length L between the inlet and outlet. The temperature in the reactor is monitored in at least one location that is at or adjacent to the inlet at a temperature-monitoring distance that is from 0.3 L or less from the inlet. In response to the monitored temperatures one or more parameters are modified. At least a portion of the feedstock is allowed to be converted to at least one of olefins and aromatic compounds within the reactor, which are removed as a product stream.

First claim

We claim:

1. A method of producing olefins and aromatic compounds from a feedstock, the method comprising:
introducing a plastic feedstock and a catalyst composition comprising a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst that is suitable for converting the feedstock to at least one of olefins and aromatic compounds within a reactor through pyrolysis, the amount of ZSM-5 zeolite catalyst of the catalyst composition making up from 10 wt. % to 50 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst, the reactor having at least one inlet for introducing the feedstock and the catalyst composition and having at least one outlet for removing reaction products from the reactor that is spaced from the at least one inlet along a reactor flow path having a length L between the at least one inlet and at least one outlet;
monitoring the temperature in the reactor at at least one location that is at or adjacent to said at least one inlet at a temperature-monitoring distance that is from 0.3 L or less from the at least one inlet, the monitored temperature being correlated to a desired product yield when the monitored temperature is maintained within a temperature range of from 450° C. to 730° C.; and
in response to a change in one or more monitored temperatures from said at least one location, modifying one or more of the following parameters (a) through (d) to maintain the monitored temperature within the range of from 450° C. to 730° C. that is correlated to the desired product yield to simultaneously increase production of both light gas olefins and aromatics:
a) the relative amount of the fluidized catalytic cracking (FCC) catalyst and the ZSM-5 zeolite catalyst of the catalyst composition introduced into the at least one inlet;
b) the flow rate of the catalyst composition into the at least one inlet;
c) the flow rate of plastic feedstock into the at least one inlet; and
d) heat input to the reactor;
allowing at least a portion of the feedstock to be converted through pyrolysis to olefins and aromatic compounds within the reactor; and
removing a product stream containing at least one of olefins and aromatic compounds from the at least one outlet of the reactor.

2. The method of claim 1 , wherein:
the parameter (a) is modified.

3. The method of claim 1 , wherein:
monitoring the temperature includes monitoring the temperature in the reactor at at least two locations that are at or adjacent to said at least one inlet at a temperature-monitoring distance that is from 0.3 L or less from the at least one inlet, the at least two locations being spaced apart at least one of longitudinally or laterally from each other within the reactor.

4. The method of claim 3 , wherein:
the at least two locations are spaced apart longitudinally.

5. The method of claim 3 , wherein:
the at least two locations are spaced apart laterally.

6. The method of claim 1 , wherein:
monitoring the temperature includes monitoring the temperature in the reactor at at least three locations that are at or adjacent to said at least one inlet at a temperature-monitoring distance that is from 0.3 L or less from the at least one inlet, the at least three locations being spaced apart at least one of longitudinally or laterally from each other within the reactor.

7. The method of claim 1 , wherein:
monitoring the temperature includes monitoring the temperature at at least one other location that is at a temperature-monitoring distance that is greater than 0.3 L from the at least one inlet.

8. The method of claim 1 , wherein:
the temperature-monitoring distance is from 0.2 L or less from the at least one inlet.

9. The method of claim 1 , wherein:
the temperature-monitoring distance is from 0.1 L or less from the at least one inlet.

10. The method of claim 1 , wherein:
the plastic feedstock and catalyst composition are introduced into the at least one inlet as separate feeds.

11. The method of claim 1 , wherein:
the plastic feedstock and catalyst composition are introduced into the at least one inlet as a mixture.

12. The method of claim 1 , wherein:
the monitored temperatures from the at least one location are weighted and the weighted temperatures are correlated to a desired product yield and used in modifying the one or more parameters (a) through (d).

13. The method of claim 1 , wherein:
the feedstock comprises at least one of polyolefins, polyethylene, polypropylene, polystyrene, polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyamide, polycarbonate, polyurethane, polyester, natural and synthetic rubber, tires, filled polymers, composites, plastic alloys, and plastics dissolved in a solvent.

14. A method of producing olefins and aromatic compounds from a feedstock, the method comprising:
introducing a plastic feedstock and a catalyst composition within a reactor, the catalyst composition comprising a non-fresh fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst is from 10 wt. % to 50 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst, the reactor having at least one inlet for introducing the feedstock and the catalyst composition and having at least one outlet for removing reaction products from the reactor that is spaced from the at least one inlet along a reactor flow path having a length L between the at least one inlet and at least one outlet;
monitoring the temperature in the reactor at at least one location that is adjacent to said at least one inlet at a temperature-monitoring distance that is from 0.3 L or less from the at least one inlet, the monitored temperature being correlated to a desired product yield when the monitored temperature is maintained within a temperature range of from 450° C. to 730° C.; and
in response to a change in one or more monitored temperatures from said at least one location, modifying one or more of the following (a) through (d) to maintain the monitored temperature within the temperature range of from 450° C. to 730° C. that is correlated to the desired product yield to simultaneously increase production of both light gas olefins and aromatics:
a) the relative amount of the fluidized catalytic cracking (FCC) catalyst and the ZSM-5 zeolite catalyst of the catalyst composition introduced into the at least one inlet;
b) the flow rate of the catalyst composition into the at least one inlet:
c) the flow rate of feedstock into the at least one inlet; and
d) heat input to the reactor;
allowing at least a portion of the feedstock to be converted to olefins and aromatic compounds within the reactor; and
removing a product stream containing at least one of olefins and aromatic compounds from the at least one outlet of the reactor.

15. The method of claim 14 , wherein:
monitoring the temperature includes monitoring the temperature in the reactor at at least two locations that are at or adjacent to said at least one inlet at a temperature-monitoring distance that is from 0.3 L or less from the at least one inlet, the at least two locations being spaced apart at least one of longitudinally or laterally from each other within the reactor.

16. The method of claim 15 , wherein:
one or more of (a) through (d) are modified to maintain a weighted average temperature of the at least two locations of at least 550° C.

17. The method of claim 15 , wherein:
one or more of (a) through (d) are modified to maintain a weighted average temperature of the at least two locations of from 450° C. to 730° C.

Assignees

• Saudi Basic Ind Corp

Inventors

• Narayanaswamy Ravichander
• Ramamurthy Krishna Kumar
• Sreenivasan P S

Classifications

• B01J2219/00218

  Dynamically variable (in-line) parameter values · CPC title

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title

• C10G2400/30

  Aromatics · CPC title

• B01J2219/00198

  at the reactor inlet · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title