Methods for preparing alkali cellulose and cellulose ether

Patent metadata

Field	Value
Publication number	US-9371398-B2
Application number	US-201213398273-A
Country	US
Kind code	B2
Filing date	Feb 16, 2012
Priority date	Feb 21, 2011
Publication date	Jun 21, 2016
Grant date	Jun 21, 2016

Abstract

Provided is a method for efficiently preparing alkali cellulose having a uniform alkali distribution. More specifically, provided are a methods for preparing alkali cellulose comprising a contact filtration step of bringing a pulp into contact with an alkali metal hydroxide solution on a moving filtration plane for vacuum filtration to collect a contact product remaining on the filtration plane, and a draining step of draining the contact product; and a method of preparing cellulose ether by using the alkali cellulose. Also provided is an apparatus for preparing alkali cellulose comprising a continuous horizontal vacuum filter type contactor.

First claim

The invention claimed is:

1. A method for preparing alkali cellulose, comprising:
a) introducing a pulp onto a moving filtration plane;
b) a contact filtration step comprising
bringing the pulp into contact with an alkali metal hydroxide solution on a moving filtration plane for vacuum filtration,
filtering the alkali metal hydroxide solution through the moving filtration plane by vacuuming a back side of the moving filtration plane to collect a contact product remaining on the moving filtration plane,
adjusting a height level of the pulp using two or more screw-type or blade-type leveling devices placed along a path of the moving filtration plane, and
gathering the pulp towards a middle of the moving filtration plane from both sides of the moving filtration plane with the two or more screw-type or blade-type leveling devices;

c) a draining step comprising draining the collected contact product to obtain a cake,
wherein bringing the pulp into contact with the alkali metal hydroxide solution comprises spraying the alkali metal hydroxide solution from two or more spray ports placed along the path of the moving filtration plane, wherein adjusting and gathering is performed prior to or after bringing the pulp into contact with the alkali metal hydroxide solution, and
wherein the screw-type or blade type leveling device adjusts the height level to 100 mm or less.

2. The method for preparing alkali cellulose according to claim 1 , wherein a weight ratio of alkali metal hydroxide contained in the cake to a solid component in the pulp is adjusted by changing a moving speed of the filtration plane or a contact distance of the pulp and the alkali metal hydroxide solution.

3. The method for preparing alkali cellulose according to claim 1 , wherein a weight ratio of alkali metal hydroxide contained in the cake to a solid component in the pulp is in a range of from 0.3 to 1.5.

4. A method for preparing cellulose ether, comprising a step of reacting the alkali cellulose prepared by the method according to claim 1 with an etherification agent.

5. The method for preparing alkali cellulose according to claim 1 , wherein each of the screw-type leveling device comprises a bilaterally symmetrical screw having a plane of symmetry at the middle.

6. The method for preparing alkali cellulose according to claim 1 , wherein each of the blade-type leveling devices comprises two blades which keep a middle part of a width of the filtration plane open, each blade having an angle exceeding 0° but less than 90° when the angle of the moving direction is regarded as 0° and the angle of a width direction of the filtration plane is regarded as 90°.

7. The method for preparing alkali cellulose according to claim 1 , wherein one of the screw-type or blade-type leveling devices is placed after introduction of the pulp onto the moving filtration plane but before the contact with the sprayed alkali metal hydroxide for adjusting the height level of the pulp introduced onto the moving filtration plane and for gathering the pulp introduced onto the moving filtration plane into the middle of both sides of the filtration plane.

8. An apparatus for preparing alkali cellulose, comprising:
a continuous horizontal vacuum filter type contactor comprising:
a horizontal filtration plane moving in a horizontal direction for vacuum filtration through the filtration plane by vacuuming a back side of the filtration plane,
a pulp inlet for introducing pulp onto the moving filtration plane,
two or more spray ports placed along a path of the filtration plane configured to spray an alkali metal hydroxide solution to the pulp thus introduced,
two or more screw-type or blade-type leveling devices placed along the path of the filtration plane wherein the two or more screw-type or blade-type leveling devices are configured to adjust a height level of the pulp introduced onto the filtration plane or the pulp brought into contact with the alkali metal hydroxide solution and to gather the pulp introduced onto the filtration plane or the pulp brought into contact with the alkali metal hydroxide solution to a middle from both sides of the filtration plane,
a vacuum pump enabling vacuum suction of the back side of the moving filtration plane,
an outlet for collecting a contact product remaining on the filtration plane after bringing the pulp into contact with the alkali metal hydroxide solution on the moving filtration plane for vacuum filtration, and
a drainer for draining the contact product collected from the outlet to obtain a cake, and
wherein the screw-type or blade type leveling device adjusts the height level to 100 mm or less.

9. The apparatus for preparing alkali cellulose according to claim 8 , wherein each of the screw-type leveling devices comprises a bilaterally symmetrical screw having a plane of symmetry at the middle.

10. The apparatus for preparing alkali cellulose according to claim 8 , wherein each of the blade type leveling devices comprises two blades which keep a middle part of a width of the filtration plane open, each blade having an angle exceeding 0° but less than 90° when the angle of the moving direction is regarded as 0° and the angle of a width direction of the filtration plane is regarded as 90°.

11. The apparatus for preparing alkali cellulose according to claim 8 , wherein one of the screw-type or blade-type leveling devices is placed between the pulp inlet and the most upstream spray port of the two or more spray ports in the moving direction for adjusting the height level of the pulp introduced onto the moving filtration plane and for gathering the pulp introduced onto the moving filtration plane into the middle of both sides of the filtration plane.

Assignees

• Narita Mitsuo
• Shinetsu Chemical Co

Inventors

• Narita Mitsuo

Classifications

• C08B11/193

  Mixed ethers, i.e. ethers with two or more different etherifying groups · CPC title

• C08B11/00

  Preparation of cellulose ethers {(rendering cellulose suitable for etherification C08B1/06)} · CPC title

• C08B1/10

  Apparatus for the preparation of alkali cellulose · CPC title

• C08B1/08 Primary

  Alkali cellulose · CPC title