Methods for preparing alkali cellulose and cellulose ether

Patent metadata

Field	Value
Publication number	US-9611333-B2
Application number	US-61536706-A
Country	US
Kind code	B2
Filing date	Dec 22, 2006
Priority date	Dec 27, 2005
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

The invention is a method for efficiently preparing alkali cellulose having a uniform alkali distribution therein. More specifically, pulp and an excess alkali metal hydroxide solution are introduced continuously in a screw conveyor type contactor and brought into contact with each other in the screw conveyor type reactor. By changing at least one factor selected from the group consisting of a rotation speed of the screw conveyor, a screw pitch and a length of immersion zone, a ratio of an alkali to cellulose in the alkali cellulose obtained by draining is controlled. The alkali cellulose thus obtained is etherified into the corresponding cellulose ether.

First claim

The invention claimed is:

1. A method for preparing a cellulose ether, comprising the steps of:
bringing pulp into continuous contact with an alkali metal hydroxide solution in a screw conveyor contactor to generate a contact mixture;
draining the contact mixture; and
etherifying the alkali cellulose prepared in the draining step with an etherifying agent to produce cellulose ether, and wherein a weight ratio of alkali metal hydroxide contained by a cake obtained in the draining step to a solid portion contained by the pulp is 0.3 to 1.5.

2. The method for preparing a cellulose ether according to claim 1 , wherein a weight ratio of alkali metal hydroxide contained by a cake obtained in the draining step to a solid portion contained by the pulp is controlled by changing at least one factor selected from the group consisting of a rotation speed of a screw conveyor in the screw conveyor type contactor, a screw pitch, and a length of a contact zone.

3. The method for preparing a cellulose ether according to claim 1 , wherein the pulp is in the form of chips.

4. The method for preparing a cellulose ether according to claim 1 , wherein the screw conveyor contactor has an inlet, an outlet, and a screw with a shaft extending from the inlet to the outlet; and the contact mixture in the screw conveyor contactor has a liquid level that does not exceed a top line of the screw shaft, the top line of the screw shaft being defined by a line connecting highest points of cross-sections of the shaft.

5. The method for preparing a cellulose ether according to claim 1 , wherein the screw conveyor has a screw with a shaft having a screw pitch from 10-500 mm.

Assignees

• Narita Mitsuo
• Tabata Masaki
• Yoshida Atsushi
• Umezawa Hiroshi
• Shinetsu Chemical Co

Inventors

• Narita Mitsuo
• Tabata Masaki
• Yoshida Atsushi
• Umezawa Hiroshi

Classifications

• C08B1/08 Primary

  Alkali cellulose · CPC title

• C08B1/10

  Apparatus for the preparation of alkali cellulose · CPC title

• C08B11/193

  Mixed ethers, i.e. ethers with two or more different etherifying groups · CPC title

• C08B11/00 Primary

  Preparation of cellulose ethers {(rendering cellulose suitable for etherification C08B1/06)} · CPC title