Method and a system for manufacturing cellulosic material

Patent metadata

Field	Value
Publication number	US-9441052-B2
Application number	US-201214126481-A
Country	US
Kind code	B2
Filing date	Jun 13, 2012
Priority date	Jun 15, 2011
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

A method for manufacturing cellulosic material includes: introducing cellulose fibers as cellulosic raw material to a system, conveying the cellulose fibers to an extruder comprising a mixing part and/or a refining part, dosing at least one chemical to the system before the extruder and/or in the extruder and performing a reaction between the cellulose fibers and the chemical(s) at least partly in the extruder, wherein the reaction is performed at a consistency of at least 40%, and/or dosing at least one chemical to the system before the extruder and/or in the extruder and mixing the cellulose fibers and the chemical(s) in the mixing part of the extruder, wherein the mixing step is performed at a consistency of at least 40%, and/or refining the introduced cellulose fibers at least partly in the refining part of the extruder, wherein the refining step is performed at a consistency of at least 5%.

First claim

The invention claimed is:

1. A method for manufacturing nanofibrillar cellulosic material, the method comprising:
introducing cellulose fibers as cellulosic raw material to a system, and
conveying the cellulose fibers to an extruder comprising a mixing part and optionally a refining part,
wherein the method further comprises:
dosing at least one first chemical comprising an alkalizing agent in an amount between 2 and 20% from the used cellulose raw material to the system before the extruder and/or in the extruder and performing a reaction between the cellulose fibers and the first chemical(s) at least partly in the extruder to activate the fibers, wherein the reaction is performed with a dry matter content of the cellulose material of at least 40%, and then
dosing at least one second chemical comprising a carboxymethylating agent in an amount between 2 and 30% from the used cellulose raw material to the system in the extruder and mixing the cellulose fibers and the second chemical(s) in the mixing part of the extruder, wherein the mixing step is performed with a dry matter content of the cellulose material of at least 40%,
heating the mixture to a temperature of at least 60° C., to produce a carboxymethylated cellulose having a degree of substitution between 0.02 and 0.4 carboxymethyl group per anhydroglucose unit, and
refining the cellulose fibers in order to form the nanofibrillar cellulose material.

2. The method according to claim 1 , the method comprising:
dosing the first chemical before the extruder or in the mixing part of the extruder, and
dosing the second chemical in the mixing part of the extruder.

3. The method according to claim 2 , wherein the first chemical is sodium hydroxide and the second chemical is monochloroacetic acid or a salt thereof.

4. The method according to claim 1 , wherein the first and/or second chemical further comprises 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) chemical and that the method comprises:
performing a reaction between the cellulose fibers and the TEMPO-chemical in the extruder in order to manufacture TEMPO-treated cellulosic material.

5. The method according to claim 1 , the method comprising:
refining the cellulose fibers in a prerefiner before conveying the cellulose fibers to the extruder.

6. The method according to claim 1 , wherein the extruder comprises a heating part and the method comprises:
using the heating part of the extruder in order to achieve a predetermined reaction temperature.

7. The method according to claim 6 , wherein the temperature in the heating part is increased by a hot steam circulation.

8. The method according to claim 1 , the method comprising:
diluting and filtrating the mixture comprising the cellulose fibers and the chemical(s) after the chemical mixing part of the extruder.

9. The method according to claim 1 , the method comprising:
refining the produced cellulosic material after extruder in a refiner in order to refine the nanofibrillar cellulosic material.

10. The method according to claim 1 , wherein the extruder comprises a drying part, and the method comprises:
increasing the dry matter content of the mixture in the extruder.

11. The method according to claim 1 , wherein the heating of the mixture is to a temperature of at least 80° C.

12. The method according to claim 1 , wherein in the refining, the dry matter content of the cellulose material is at least 5%.

Assignees

• Tamper Juha
• Nuopponen Markus
• Kosonen Harri
• Upm Kymmene Corp

Inventors

• Tamper Juha
• Nuopponen Markus
• Kosonen Harri

Classifications

• C08B15/02

  Oxycellulose; Hydrocellulose; {Cellulosehydrate, e.g. microcrystalline cellulose} · CPC title

• C08B11/00 Primary

  Preparation of cellulose ethers {(rendering cellulose suitable for etherification C08B1/06)} · CPC title

• D21C9/007

  by mechanical or physical means · CPC title

• C08L2205/16

  Fibres; Fibrils · CPC title

• D21H11/18

  Highly hydrated, swollen or fibrillatable fibres · CPC title