Electrochemical deposition of nanoscale catalyst particles

Patent metadata

Field	Value
Publication number	US-9299991-B2
Application number	US-201313776260-A
Country	US
Kind code	B2
Filing date	Feb 25, 2013
Priority date	Aug 27, 2010
Publication date	Mar 29, 2016
Grant date	Mar 29, 2016

Abstract

A process for the electrochemical deposition of nanoscale catalyst particles using a sacrificial hydrogen anode as counter electrode for the working electrode is disclosed, whereby a concurrent development of hydrogen at the working electrode is mostly or completely avoided.

First claim

The invention claimed is:

1. A method for electrochemical deposition of nanoscale catalyst particles in a device comprising a working electrode, a counter electrode and
an ionomer membrane between said working electrode and said counter electrode, the method comprising:
a working electrode comprising a precursor layer comprising at least one metal salt that has been previously deposited whereby the catalyst particles are deposited from the precursor layer;
a hydrogen consuming anode which is suitable for hydrogen oxidation and which functions as the counter electrode;
wherein a working electrode potential shows at least mainly positive signs with respect to the hydrogen consuming anode during the deposition process in respect of time; and
an inert gas is applied to the working electrode during the deposition process so that a working electrode-side moisture is reduced and simultaneously formation of hydrogen at the working electrode can be mostly or completely prevented.

2. The method of claim 1 , wherein the working electrode potential with respect to the hydrogen consuming anode is positive at least 90% of the total deposition time.

3. The method of claim 2 , wherein the working electrode potential with respect to the hydrogen consuming anode is always positive in order to completely prevent simultaneous formation of hydrogen at the working electrode during the deposition process.

4. The method of claim 1 , whereby the precursor layer is applied to a gas diffusion layer (GDL).

5. The method of claim 1 , wherein the precursor layer with a simultaneous or subsequent deposition of one or more precursors is applied and dried through an established coating process.

6. The method of claim 5 , wherein the precursor layer includes one or more substrate materials, one or more ionomers, and the precursors.

7. The method of claim 1 , wherein binding agents, dispersion agents, wetting agents, solvent mixtures, thickeners and/or antioxidants are added as additives to a dispersion for the production of the precursor layer so that the application and adhesion of the layer can be improved.

8. The method of claim 1 , wherein grain refiners, surfactants and/or complexing agents are added as additives to the precursor layer, thereby influencing the deposition.

9. The method of claim 1 , wherein the nanoscale catalyst particles are produced electrochemically, and which contain one or more of the elements Pt, Ru, Au, Co, Cr, Fe, Cu, Ni, Zn, Rh, Pd, Sn, Re, Os, Ir, Cd and Ag.

10. The method of claim 1 , wherein the electrochemical deposition is caused at the working electrode by a constant or variable voltage.

11. The method of claim 1 , wherein the electrochemical deposition is caused at the working electrode by a constant or variable current.

12. The method of claim 1 , wherein alkaline and/or acidic polymer electrolytes are introduced as ionomer membranes.

13. The method of claim 1 , wherein the process is performed in batch or continuous operation.

14. The method of claim 1 , wherein the precursor layer is applied to a gas diffusion layer (GDL) consisting of carbon fiber paper, carbon fiber fleece, carbon fiber fabric, carbon fiber netting, metal netting, woven fabrics with conductive properties or plastic substrates with conductive properties, with or without MPL (microporous layer).

15. The method of claim 1 , wherein the electrochemical reduction of the at least one metal salt takes place at temperatures between 0 and 200 ° C.

Assignees

• Univ Saarland
• Uni Des Saarlandes

Inventors

• Mitzel Jens
• Hempelmann Rolf
• Annel Vivien
• Natter Harald
• Stefener Manfred

Classifications

• C25D5/003

  Electroplating using gases, e.g. pressure influence · CPC title

• B01J23/42

  Platinum · CPC title

• H01M4/8807

  Gas diffusion layers · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• H01M8/1007

  with both reactants being gaseous or vaporised (H01M8/12 takes precedence) · CPC title