Method for producing fine catalyst particles and method for producing carbon-supported catalyst

US2017028385A1 · US · A1

Patent metadata
FieldValue
Publication numberUS-2017028385-A1
Application numberUS-201515303877-A
CountryUS
Kind codeA1
Filing dateApr 3, 2015
Priority dateApr 18, 2014
Publication dateFeb 2, 2017
Grant date

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  1. Title

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  2. Abstract

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  5. First independent claim

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Abstract

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The present invention is to provide fine catalyst particles to which sulfate ions are less likely to be adsorbed, and a carbon-supported catalyst to which sulfate ions are less likely to be adsorbed. Disclosed is a method for producing fine catalyst particles comprising a fine palladium-containing particle and a platinum-containing outermost layer covering at least part of the fine palladium-containing particle, wherein the method comprises: a copper covering step of covering at least part of the fine palladium-containing particle with copper by preparing a second dispersion by mixing a first dispersion comprising fine palladium-containing particles being dispersed in an acid solution with a copper-containing solution, and applying a potential that is nobler than the oxidation reduction potential of copper to the fine palladium-containing particles in the second dispersion, and a platinum covering step of covering at least part of the fine palladium-containing particle with platinum by substituting the copper covering at least part of the fine palladium-containing particle with platinum by mixing the second dispersion and a platinum-containing solution after the copper covering step, with applying a constant potential that is in a range between a potential that is nobler than the oxidation reduction potential of copper and a potential that is less than the oxidation reduction potential of platinum, to the fine palladium-containing particles.

First claim

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1 . A method for producing fine catalyst particles comprising a fine palladium-containing particle and a platinum-containing outermost layer covering at least part of the fine palladium-containing particle, wherein the method comprises: a copper covering step of covering at least part of the fine palladium-containing particle with copper by preparing a second dispersion by mixing a first dispersion comprising fine palladium-containing particles being dispersed in an acid solution with a copper-containing solution, and applying a potential that is nobler than the oxidation reduction potential of copper to the fine palladium-containing particles in the second dispersion, and a platinum covering step of covering at least part of the fine palladium-containing particle with platinum by substituting the copper covering at least part of the fine palladium-containing particle with platinum by mixing the second dispersion and a platinum-containing solution after the copper covering step, with applying a constant potential that is in a range between a potential that is nobler than the oxidation reduction potential of copper and a potential that is less than the oxidation reduction potential of platinum, to the fine palladium-containing particles. 2 . The method for producing the fine catalyst particles according to claim 1 , wherein, the second dispersion and the platinum-containing solution are mixed in the platinum covering step, with applying a constant potential that is in a range of from 0.37 to 0.70 V (vs. RHE) to the fine palladium-containing particles. 3 . A method for producing a carbon-supported catalyst in which the fine catalyst particles defined by claim 1 are supported on a carbon support, wherein fine palladium-containing particles configured for use in the copper covering step are supported on a carbon support.

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Classifications

  • Scanning electron microscopy; Transmission electron microscopy · CPC title

  • Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

  • with a non-spherical or unspecified core-shell structure · CPC title

  • Carbon · CPC title

  • Impregnation, coating or precipitation ({B01J37/0009 and B01J37/0018 take precedence } ; protection by coating B01J33/00) · CPC title

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What does patent US2017028385A1 cover?
The present invention is to provide fine catalyst particles to which sulfate ions are less likely to be adsorbed, and a carbon-supported catalyst to which sulfate ions are less likely to be adsorbed. Disclosed is a method for producing fine catalyst particles comprising a fine palladium-containing particle and a platinum-containing outermost layer covering at least part of the fine palladium-co…
Who is the assignee on this patent?
Toyota Motor Co Ltd
What technology area does this patent fall under?
Primary CPC classification B01J23/44. Mapped technology areas include Operations & Transport.
When was this patent published?
Publication date Thu Feb 02 2017 00:00:00 GMT+0000 (Coordinated Universal Time) (A1). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 1 related publication on this page (citations in our corpus or others sharing the same primary CPC).