Synthetic amorphous silica powder and method for producing same

Patent metadata

Field	Value
Publication number	US-9272918-B2
Application number	US-201013520798-A
Country	US
Kind code	B2
Filing date	Dec 24, 2010
Priority date	Jan 7, 2010
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

The synthetic amorphous silica powder of the present invention is characterized in that it comprises a synthetic amorphous silica powder obtained by applying a spheroidizing treatment to a silica powder, and by subsequently cleaning and drying it so that the synthetic amorphous silica powder has an average particle diameter D 50 of 10 to 2,000 μm; wherein the synthetic amorphous silica powder has: a quotient of 1.00 to 1.35 obtained by dividing a BET specific surface area of the powder by a theoretical specific surface area calculated from the average particle diameter D 50 ; a real density of 2.10 to 2.20 g/cm 3 ; an intra-particulate porosity of 0 to 0.05; a circularity of 0.75 to 1.00; and a spheroidization ratio of 0.55 to 1.00.

First claim

The invention claimed is:

1. A method for producing a synthetic amorphous silica powder, comprising, in the recited order:
a granulating step for producing a siliceous gel, drying the siliceous gel to turn it into a dry powder, pulverizing particles of the dry powder, and then classifying the pulverizedly obtained particles to thereby obtain a silica powder;
a spheroidizing step based on a thermal plasma for delivering, at a supplying rate of 4.2 to 8.0 kg/hr, particles of the silica powder obtained in the granulating step into an argon-oxygen plasma in a plasma torch from a starting material supplying tube, in a manner to heat the particles at a temperature from 2,000° C. to a boiling point of silicon dioxide, thereby melting the particles, in which the argon-oxygen plasma is generated by introducing argon as a working gas from a gas introducing tube at a flow rate of 15 to 60 L/min into the plasma torch, while applying a high frequency wave at a frequency of 4 to 5 MHz and at a power of 30 to 80 kw to the plasma torch, and by gradually introducing oxygen at a flow rate of 10 to 80 L/min into the plasma torch after the plasma is stabilized;
a cleaning step for removing fine particles attached to surfaces of the silica powder particles after the spheroidizing step by repetitively conducting ultrasonic cleaning such that the spheroidized silica powder particles after the spheroidizing step and ultrapure water are put into a cleaning vessel, and filtration by using a filter until fine particles of the silica powder are fully filtered out; and
a drying step for drying the silica powder particles after the cleaning step such that the powder is firstly put into a container for drying, and then the container for drying is brought into a drier, in which drying is conducted by flowing nitrogen or argon at a flow rate of 1 to 20 L/min through within the drier, and by holding the powder at a temperature of 100° C. to 400° C. for 12 to 48 hours;
wherein the spheroidizing step is conducted by adjusting a value of A/B (W·hr/kg) to 1.0×10 4 to 1.4×10 4 , where A is the high-frequency power (W), and B is the supplying rate (kg/hr) of the silica powder, thereby obtaining a synthetic amorphous silica powder having:
an average particle diameter D 50 of 10 to 3,000 μm;
a quotient of 1.00 to 1.35 obtained by dividing a BET specific surface area of the powder by a theoretical specific surface area calculated from the average particle diameter D 50 ;
a real density of 2.10 to 2.20 g/cm 3 ;
an intra-particulate porosity of 0 to 0.05;
a circularity of 0.75 to 1.00; and
a spheroidization ratio of 0.55 to 1.00.

2. The method for producing a synthetic amorphous silica powder according to claim 1 , wherein the granulating step is a step for: hydrolyzing silicon tetrachloride to produce a siliceous gel; drying the siliceous gel to turn it into a dry powder; pulverizing particles of the dry powder; and then classifying the pulverizedly obtained particles, to obtain a silica powder having an average particle diameter D50 of 10 to 3,000 μm.

3. The method for producing a synthetic amorphous silica powder according to claim 1 , wherein the granulating step is a step for: hydrolyzing an organic silicon compound to produce a siliceous gel; drying the siliceous gel to turn it into a dry powder; pulverizing particles of the dry powder; and then classifying the pulverizedly obtained particles, to obtain a silica powder having an average particle diameter D50 of 10 to 3,000 μm.

4. The method for producing a synthetic amorphous silica powder according to claim 1 , wherein the granulating step is a step for: using a fumed silica to produce a siliceous gel; drying the siliceous gel to turn it into a dry powder; pulverizing particles of the dry powder; and then classifying the pulverizedly obtained particles, to obtain a silica powder having an average particle diameter D 50 of 10 to 3,000 μm.

Assignees

• Ueda Toshiaki
• Mitsubishi Materials Corp

Inventors

• Ueda Toshiaki

Classifications

• C01P2002/82

  by IR- or Raman-data · CPC title

• C03C2203/27

  the alkoxides containing other organic groups, e.g. alkyl groups · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C03C3/06

  with more than 90% silica by weight, e.g. quartz {(C03C3/045 takes precedence)} · CPC title

• C01P2004/03

  obtained by SEM · CPC title