METAL AND TIN ALLOY HAVING LOW alpha-RAY EMISSION, AND METHOD FOR PRODUCING SAME

Patent metadata

Field	Value
Publication number	US-2020385843-A1
Application number	US-201816638770-A
Country	US
Kind code	A1
Filing date	Aug 13, 2018
Priority date	Aug 17, 2017
Publication date	Dec 10, 2020
Grant date	—

Abstract

Any metal having a low α-ray emission, the metal being any one of tin, silver, copper, zinc, or indium, wherein an emission of an α-ray after heating the metal at 100° C. in an atmosphere for six hours is 0.002 cph/cm2 or less. Any metal of tin, silver, copper, zinc and indium each including lead as an impurity is dissolved to prepare a hydrosulfate aqueous solution of the metal and lead sulfate is precipitated and removed in the solution. The lead sulfate is precipitated in the hydrosulfate aqueous solution by adding a lead nitrate aqueous solution including lead having an a-ray emission of 10 cph/cm2 or less to the hydrosulfate aqueous solution, from which the lead sulfate has been removed, and, at the same time, the solution is circulated while removing the lead sulfate to electrowinning the metal using the hydrosulfate aqueous solution as an electrolytic solution.

First claim

1 . A metal having a low α-ray emission, the metal being any one of tin, silver, copper, zinc, or indium,
wherein an emission of an α-ray after heating the metal at 100° C. in an atmosphere for six hours is 0.002 cph/cm 2 or less.

2 . A tin alloy having a low α-ray emission, the tin alloy being an alloy of the tin having a low α-ray emission according to claim 1 and one or more metals selected from a group consisting of silver, copper, zinc, indium, bismuth, nickel, and germanium,
wherein an emission of an α-ray after heating the tin alloy at 100° C. in an atmosphere for six hours is 0.002 cph/cm 2 or less.

3 . The tin alloy having a low α-ray emission according to claim 2 ,
wherein the metal that forms the tin alloy with the tin having a low α-ray emission is one or more metals selected from a group consisting of silver, copper, zinc, and indium.

4 . The metal or the tin alloy having a low α-ray emission according to claim 1 ,
wherein the emission of an α-ray of the metal or the tin alloy after heating the metal or the tin alloy at 200° C. in an atmosphere for six hours is 0.002 cph/cm 2 or less.

5 . A method for producing a metal having a low α-ray emission, the method including:
a step (a) of dissolving any metal of tin, silver, copper, zinc and indium each including lead as an impurity in a sulfuric acid aqueous solution to prepare a hydrosulfate aqueous solution of the metal and precipitating lead sulfate in the hydrosulfate aqueous solution;
a step (b) of filtering the hydrosulfate aqueous solution of the step (a) to remove the lead sulfate from the hydrosulfate aqueous solution;
a step (c) of precipitating lead sulfate in the hydro sulfate aqueous solution by adding a lead nitrate aqueous solution of a predetermined concentration including lead having an α-ray emission of 10 cph/cm 2 or less to the hydrosulfate aqueous solution of the step (b), from which the lead sulfate has been removed, at a predetermined addition rate for 30 minutes or longer while stirring the hydrosulfate aqueous solution at a rotation rate of at least 100 rpm in a first tank, and, at the same time, circulating the hydrosulfate aqueous solution in the first tank at a proportion at which a circulation flow rate reaches at least 1% by volume of a total liquid amount while filtering the hydrosulfate aqueous solution to remove the lead sulfate from the hydrosulfate aqueous solution; and
a step (d) of transferring the hydrosulfate aqueous solution of the step (c) to a separate second tank from the first tank and then electrowinning the metal using the hydrosulfate aqueous solution as an electrolytic solution.

6 . The method for producing a metal having a low α-ray emission according to claim 5 ,
wherein the predetermined concentration of lead nitrate in the lead nitrate aqueous solution of the step (c) is 10% by mass to 30% by mass.

7 . The method for producing a metal having a low α-ray emission according to claim 5 ,
wherein the predetermined addition rate of the lead nitrate aqueous solution of the step (c) is 1 mg/second to 100 mg/second with respect to one liter of the hydrosulfate aqueous solution.

8 . A method for producing a tin alloy having a low α-ray emission, the method including the step of producing the tin alloy having a low α-ray emission by adding one or more metals selected from a group consisting of silver, copper, zinc, indium, bismuth, nickel, and germanium to metallic tin and mixing thereof to obtain a mixture, and casing the mixture,
wherein the metallic tin is metallic tin produced using the method according to claim 5 , and
the metal being added to the metallic tin has an α-ray emission of 0.002 cph/cm 2 or less.

9 . A method for producing a tin alloy having a low α-ray emission, the method including the step of producing the tin alloy having a low α-ray emission by adding one or more metals selected from a group consisting of silver, copper, zinc, and indium to metallic tin and mixing thereof to obtain a mixture, and casing the mixture,
wherein each of the metallic tin and the one or more metals added to the metallic tin is the metal produced using the method according to claim 5 .

Assignees

• Mitsubishi Materials Corp

Inventors

• Hirano Hirotaka
• Yoshida Yoshihiro
• Katase Takuma

Classifications

• C25C1/22

  of metals not provided for in groups C25C1/02 - C25C1/20 · CPC title

• C25C1/20

  of noble metals · CPC title

• C25C1/14

  of tin · CPC title

• C25C1/12

  of copper · CPC title

• C22B58/00

  Obtaining gallium or indium {(treatment or purification of solutions by liquid-liquid extraction, by ion-exchange or by adsorption C22B3/20)} · CPC title