Elastomer and molded body

Patent metadata

Field	Value
Publication number	US-12325784-B2
Application number	US-201917059521-A
Country	US
Kind code	B2
Filing date	Apr 19, 2019
Priority date	Jun 8, 2018
Publication date	Jun 10, 2025
Grant date	Jun 10, 2025

Abstract

An elastomer of the present invention is used for a molded body for low temperature environments, includes a silicone rubber, and has a characteristic in which the expression ((tensile stress M 100 −tensile stress M 100 0)/tensile stress M 100 0)×100 is equal to or more than a predetermined value and equal to or less than a predetermined value, where the tensile stress M 100 and the tensile stress M 100 0 are respectively obtained under two different measurement conditions of performing or not performing a cooling treatment of maintaining −40° C. for 30 minutes.

First claim

The invention claimed is:

1. An elastomer used for a molded body for low temperature environments, the elastomer comprising:
silicone rubber which is composed of a cured product of a silicone rubber-based curable composition including a vinyl group-containing organopolysiloxane (A), organohydrogenpolysiloxane (B), silica particles (C) and, silane coupling agent (D), and platinum or a platinum compound (E),
wherein, the vinyl group-containing organopolysiloxane (A) includes a vinyl group-containing linear organopolysiloxane (A1-1) having a content of vinyl groups equal to or less than 0.4 mol % and vinyl group-containing linear organopolysiloxane (A1-2) in which a content of the vinyl groups is 0.5 to 15 mol %,
wherein, a content of the silica particles (C) is equal to or less than 35 parts by weight, with respect to 100 parts by weight as a total amount of the vinyl group-containing organopolysiloxane (A),
wherein a content of the organohydrogenpolysiloxane (B) is equal to or more than 0.5 parts by weight and equal to or less than 20 parts by weight with respect to 100 parts by weight as a total amount of the vinyl group-containing organopolysiloxane (A), the silica particles (C), and the silane coupling agent (D),
the silane coupling agent (D) includes a silane coupling agent having a hydrophobic group (D-1) which is different from the vinyl groups and a silane coupling agent (D-2) having a vinyl group,
wherein ((tensile stress M 100 −tensile stress M 100 0)/tensile stress M 100 0)×100 measured under the following conditions is equal to or more than −20% and equal to or less than 13%,
(conditions)
tensile stress M 100 at a given elongation: a stress at 100% elongation of the elastomer which is measured at −40° C. according to JIS K 6251 (2004) after maintaining the elastomer at −40° C. for 30 minutes, and
tensile stress M 100 0 at a given elongation: a stress at 100% elongation of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment.

2. The elastomer according to claim 1 ,
wherein ((elongation at break BE−elongation at break BEO)/elongation at break BEO)×100 measured under the following conditions is equal to or more than −40% and equal to or less than 20%,
(conditions)
elongation at break BE: an elongation at break of the elastomer which is measured at −40° C. according to JIS K 6251 (2004) after maintaining the elastomer at −40° C. for 30 minutes, and
elongation at break BEO: an elongation at break of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment.

3. The elastomer according to claim 1 ,
wherein ((tensile strength S−tensile strength S0)/tensile strength S0)×100 measured under the following conditions is equal to or more than −20% and equal to or less than 80%,
(conditions)
tensile strength S: a tensile strength of the elastomer which is measured at −40° C. according to JIS K 6251 (2004) after maintaining the elastomer at −40° C. for 30 minutes, and
tensile strength S0: a tensile strength of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment.

4. The elastomer according to claim 1 ,
wherein ((tear strength TS−tear strength TS0)/tear strength TS0)×100 measured under the following conditions is equal to or more than −20% and equal to or less than 120%,
(conditions)
tear strength TS: a tear strength of the elastomer which is measured at −40° C. according to JIS K 6252 (2001) after maintaining the elastomer at −40° C. for 30 minutes, and
tear strength TS0: a tear strength of the elastomer which is measured at 25° C. according to JIS K 6252 (2001) without subjecting the elastomer to a further cooling treatment.

5. The elastomer according to claim 1 ,
wherein a hardness AC measured under the following conditions is equal to or more than 20 and equal to or less than 80,
(conditions)
hardness A0: a durometer hardness of the elastomer which is obtained at 25° C. without subjecting the elastomer to a further cooling treatment, where the durometer hardness is defined by JIS K 6253 (1997).

6. The elastomer according to claim 1 ,
wherein the elastomer is used for the molded body having a cool tolerance temperature of −40° C.

7. The elastomer according to claim 1 ,
wherein the molded body is a wearable device.

8. A molded article for low temperature environments, comprising:
the elastomer according to claim 1 .

9. The elastomer according to claim 1 ,
wherein the silane coupling agent having the hydrophobic group includes methyltrimethoxysilane, dimethyldimethoxysilane, phenyltrimethoxysilane, methyltriethoxysilane, dimethyldiethoxysilane, phenyltriethoxysilane, n-propyltrimethoxysilane, n-propyltriethoxysilane, hexyltrimethoxysilane, hexyltriethoxysilane, and decyltrimethoxysilane, methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, phenyltrichlorosilane, or hexamethyldisilazane.

10. The elastomer according to claim 1 ,
wherein the silane coupling agent having the vinyl group includes methacryloxypropyltriethoxysilane, methacryloxypropyltrimethoxysilane, methacryloxypropylmethyldiethoxysilane, methacryloxypropylmethyldimethoxysilane, vinyltriethoxysilane, vinyltrimethoxysilane, and vinylmethyldimethoxysilane, vinyltrichlorosilane, vinylmethyldichlorosilane, or divinyltetramethyldisilazane.

11. The elastomer according to claim 1 ,
wherein, tensile stress M 100 0 at a given elongation: a stress at 100% elongation of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment is 1.1 MPa or more.

12. The elastomer according to claim 1 ,
wherein, tensile strength S0: a tensile strength of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment is 9.7 MPa or more.

13. The elastomer according to claim 1 ,
wherein, elongation at break BEO: an elongation at break of the elastomer which is measured at 25° C. according to JIS K 6251 (2004) without subjecting the elastomer to a further cooling treatment is 335% or more.

14. The elastomer according to claim 1 ,
wherein the content of the silica particles (C) is equal to or less than 25 parts by weight, with respect to 100 parts by weight as a total amount of the vinyl group-containing organopolysiloxane (A).

Assignees

• Sumitomo Bakelite Co

Inventors

• Okada Jun
• Otani Mariko
• Sato Motoki

Classifications

• C08L83/04 Primary

  Polysiloxanes · CPC title

• C08K3/013

  Fillers, pigments or reinforcing additives · CPC title

• C08G77/20

  containing silicon bound to unsaturated aliphatic groups · CPC title

• C08K3/36 Primary

  Silica · CPC title

• C08L21/00

  Compositions of unspecified rubbers · CPC title