Varistor and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-11908599-B2
Application number	US-202217892711-A
Country	US
Kind code	B2
Filing date	Aug 22, 2022
Priority date	Aug 31, 2021
Publication date	Feb 20, 2024
Grant date	Feb 20, 2024

Abstract

A varistor includes a sintered body, an internal electrode, an insulating layer, and an external electrode. The internal electrode is disposed in an interior of the sintered body. The insulating layer covers at least part of the sintered body and includes Zn 2 SiO 4 . The external electrode is electrically connected to the internal electrode, covers part of the sintered body and part of the insulating layer, and is in contact with the part of the insulating layer. The insulating layer has a region being in contact with the external electrode, the region having a greater average thickness than a region of the insulating layer which is out of contact with the external electrode.

First claim

The invention claimed is:

1. A varistor comprising:
a sintered body;
an internal electrode disposed in an interior of the sintered body;
an insulating layer covering at least part of the sintered body and including Zn 2 SiO 4 ; and
an external electrode electrically connected to the internal electrode, covering part of the sintered body and part of the insulating layer, and being in contact with the part of the insulating layer, wherein:
the insulating layer includes a region in contact with the external electrode, and
the region has a greater average thickness than a region of the insulating layer which is out of contact with the external electrode.

2. The varistor of claim 1 , wherein
the sintered body includes ZnO.

3. The varistor of claim 1 , wherein
the external electrode includes Bi 2 O 3 .

4. The varistor of claim 3 , wherein
the sintered body includes no Bi 2 O 3 , or a mass concentration of Bi 2 O 3 in the sintered body is lower than a mass concentration of Bi 2 O 3 in the external electrode.

5. The varistor of claim 1 , wherein
the external electrode includes
a primary external electrode disposed at a side of the sintered body and being in contact with a first region of the insulating layer, and
a secondary external electrode covering the primary external electrode and being in contact with a second region of the insulating layer, the second region being different from the first region, and

an average thickness of the second region of the insulating layer is greater than an average thickness of the first region of the insulating layer.

6. The varistor of claim 5 , wherein
the primary external electrode includes no Bi 2 O 3 , or a mass concentration of Bi 2 O 3 in the primary external electrode is lower than a mass concentration of Bi 2 O 3 in the secondary external electrode.

7. A method for manufacturing a varistor, the method comprising:
preparing a sintered body including ZnO as a main component and including an internal electrode disposed in an interior of the sintered body;
forming a precursor layer including SiO 2 or silicate such that the precursor layer covers at least part of the sintered body;
applying an external electrode paste including Bi 2 O 3 such that the external electrode paste covers part of the sintered body and is in contact with part of the precursor layer;
performing heat treatment to form an insulating layer including Zn 2 SiO 4 from the precursor layer and to form an external electrode from the external electrode paste.

8. The method of claim 7 , wherein
the insulating layer having a region being in contact with the external electrode, the region having a greater average thickness than a region of the insulating layer which is out of contact with the external electrode.

9. The method of claim 7 , wherein
the sintered body includes substantially no Bi 2 O 3 , or a mass concentration of Bi 2 O 3 in the sintered body is lower than a mass concentration of Bi 2 O 3 in the external electrode paste.

10. The method of claim 7 , wherein
a concentration of Bi 2 O 3 in the external electrode paste is greater than or equal to 3% by mass and less than or equal to 30% by mass.

11. The varistor of claim 1 , wherein
the sintered body on which the insulating layer is formed has a flat surface,
the insulating layer has a thickness from the flat surface of the sintered body in a depth direction of the sintered body.

12. A varistor comprising:
a sintered body;
an internal electrode disposed in an interior of the sintered body;
an insulating layer covering at least part of the sintered body and including Zn 2 SiO 4 ; and
an external electrode electrically connected to the internal electrode, covering part of the sintered body and part of the insulating layer, and being in contact with the part of the insulating layer, wherein:
the sintered body on which the insulating layer is formed has a flat surface, and
the insulating layer includes a region in contact with the external electrode, and the region has a greater average thickness from a surface of the insulating layer than a region of the insulating layer which is out of contact with the external electrode.

13. The varistor of claim 12 , wherein
the sintered body includes ZnO.

14. The varistor of claim 12 , wherein
the external electrode includes Bi 2 O 3 .

15. The varistor of claim 14 , wherein
the sintered body includes no Bi 2 O 3 , or a mass concentration of Bi 2 O 3 in the sintered body is lower than a mass concentration of Bi 2 O 3 in the external electrode.

16. The varistor of claim 12 , wherein
the external electrode includes
a primary external electrode disposed at a side of the sintered body and being in contact with a first region of the insulating layer, and
a secondary external electrode covering the primary external electrode and being in contact with a second region of the insulating layer, the second region being different from the first region, and

an average thickness of the second region of the insulating layer is greater than an average thickness of the first region of the insulating layer.

17. The varistor of claim 16 , wherein
the primary external electrode includes no Bi 2 O 3 , or a mass concentration of Bi 2 O 3 in the primary external electrode is lower than a mass concentration of Bi 2 O 3 in the secondary external electrode.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Kawajiri Keiji
• Mutou Naoki
• Motomitsu Hironori
• WATANABE Michiya
• Yamagishi Yuji

Classifications

• H01C7/102 Primary

  Varistor boundary, e.g. surface layers (H01C7/12 takes precedence) · CPC title

• H01C1/142

  the terminals or tapping points being coated on the resistive element · CPC title

• H01C7/1006

  Thick film varistors · CPC title

• H01C7/112 Primary

  ZnO type · CPC title

• H01C17/06546

  Oxides of zinc or cadmium · CPC title