Hexagonal boron nitride powder, method for producing same, resin composition and resin sheet

Patent metadata

Field	Value
Publication number	US-11577957-B2
Application number	US-201716473455-A
Country	US
Kind code	B2
Filing date	Dec 26, 2017
Priority date	Dec 28, 2016
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

A hexagonal boron nitride powder having an average longer diameter (L) of primary particles in the hexagonal boron nitride powder of more than 10.0 μm and 30.0 μm or less, an average thickness (D) of the primary particles in the hexagonal boron nitride powder of 1.0 μm or more, a ratio of the average longer diameter (L) to the average thickness (D), [L/D], of 3.0 or more and 5.0 or less, and a content of primary particles having a ratio of a longer diameter (1) to a thickness (d), [l/d], of 3.0 or more and 5.0 or less of 25% or more, a method for producing the hexagonal boron nitride powder, and a resin composition and a resin sheet each containing the hexagonal boron nitride powder.

First claim

The invention claimed is:

1. A hexagonal boron nitride powder having: an average longer diameter (L) of primary particles in the hexagonal boron nitride powder of more than 10.0 μm and 30.0 μm or less; an average thickness (D) of the primary particles in the hexagonal boron nitride powder of 1.0 μm or more; a ratio of the average longer diameter (L) to the average thickness (D), [L/D], of 3.0 or more and 5.0 or less; and a content of primary particles having an individual aspect ratio of a longer diameter (l) to a thickness (d), [lid], of 3.0 or more and 5.0 or less of 60% or more.

2. The hexagonal boron nitride powder according to claim 1 , wherein the hexagonal boron nitride powder comprises an aggregate of two or more primary particles, and when the hexagonal boron nitride powder is put through a sieve having an opening of 106 μm, the hexagonal boron nitride powder passing through the sieve has a 50% volume cumulative particle size D 50 (1) of 25 μm or more and 100 μm or less, and a dispersion liquid obtained by dispersing in water the hexagonal boron nitride powder passing through the sieve has a 50% volume cumulative particle size D 50 (2) of 50 μm or less after the dispersion liquid is subjected to an ultrasonic treatment for 3 minutes.

3. The hexagonal boron nitride powder according to claim 1 , having a BET specific surface area of 2.0 m 2 /g or less.

4. A resin composition comprising:
the hexagonal boron nitride powder according to claim 1 ; and
an organic matrix, wherein
the composition has a content of the hexagonal boron nitride powder of 10% by volume or more and 90% by volume or less based on a total amount of the hexagonal boron nitride powder and the organic matrix.

5. A resin sheet comprising the resin composition according to claim 4 or a cured product thereof.

6. A method for producing the hexagonal boron nitride powder according to claim 1 , the method comprising the following steps 1 to 3:
Step 1: a step of firing a boron carbide powder at 1600° C. or more and 2200° C. or less under a nitrogen gas atmosphere;
Step 2: a step of heating a fired product obtained in the step 1 at 500° C. or more and less than 1500° C. under an oxygen-containing gas atmosphere, thereby decarbonizing the fired product; and
Step 3: a step of firing again a product after decarbonization, the product obtained in the step 2, at 1500° C. or more and 2200° C. or less under a nitrogen gas atmosphere.

7. The method for producing the hexagonal boron nitride powder according to claim 6 , wherein 10 parts by mass or more and 80 parts by mass or less of a boron compound represented by a composition formula B 2 O (3+X) H 2X wherein X=0 to 3 based on 100 parts by mass of the product after decarbonization is added in the step 3.

8. The method for producing the hexagonal boron nitride powder according to claim 6 , wherein 10 parts by mass or more and 200 parts by mass or less of a calcium compound based on 100 parts by mass of the product after decarbonization is added in the step 3.

Assignees

• Showa Denko Kk

Inventors

• Otsuka Yuki
• Fukasawa Masaru

Classifications

• C01B21/064 Primary

  with boron · CPC title

• C08K2003/385

  Binary compounds of nitrogen with boron · CPC title

• C01P2004/22

  with a polygonal circumferential shape · CPC title

• C01P2006/12

  Surface area · CPC title

• C01B21/0646 Primary

  Preparation by pyrolysis of boron and nitrogen containing compounds · CPC title