Thermosetting resin composition, prepreg, laminate and multilayer printed wiring board

Patent metadata

Field	Value
Publication number	US-11359055-B2
Application number	US-201916676501-A
Country	US
Kind code	B2
Filing date	Nov 7, 2019
Priority date	Apr 30, 2015
Publication date	Jun 14, 2022
Grant date	Jun 14, 2022

Abstract

Provided are a thermosetting resin composition having especially good compatibility and having dielectric properties (low dielectric constant and low dielectric dissipation factor) in a high frequency range, high adhesion to conductor, excellent heat resistance, high glass transition temperature, low thermal expansion coefficient and high flame retardancy, and a prepreg, a laminate and a multilayer printed wiring board using the resin composition. Specifically, the thermosetting resin composition contains (A) a polyphenylene ether derivative having an N-substituted maleimide structure-containing group and a structural unit represented by the following general formula (I) in one molecule, (B) at least one thermosetting resin selected from the group consisting of epoxy resins, cyanate resins and maleimide compounds, and (C) a phosphorus flame retardant:wherein R1 each independently represents an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, and x represents an integer of 0 to 4.

First claim

The invention claimed is:

1. A thermosetting resin composition comprising:
(A) a polyphenylene ether derivative having an N-substituted maleimide structure-containing group and a structural unit represented by the following general formula (I) in one molecule,
(B) at least one thermosetting resin selected from the group consisting of an epoxy resin, a cyanate resin and a maleimide compound, and
(C) a phosphorus flame retardant:

wherein R 1 each independently represents an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, and x represents an integer of 0 to 4.

2. The thermosetting resin composition according to claim 1 , wherein the N-substituted maleimide structure-containing group is a group represented by the following general formula (Z):

wherein R 2 each independently represents an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, y represents an integer of 0 to 4, and A 1 represents a group represented by the following general formula (II), (III), (IV) or (V):

wherein R 3 each independently represents an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, and p represents an integer of 0 to 4:

wherein R 4 and R 5 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, A 2 represents an alkylene group having 1 to 5 carbon atoms, an alkylidene group having 2 to 5 carbon atoms, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group, a single bond, or a group represented by the following general formula (III-1), and q and r each independently represent an integer of 0 to 4:

wherein R 6 and R 7 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, A 3 represents an alkylene group having 1 to 5 carbon atoms, an isopropylidene group, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group or a single bond, and s and t each independently represent an integer of 0 to 4:

wherein n represents an integer of 0 to 10:

wherein R 8 and R 9 each independently represent a hydrogen atom, or an aliphatic hydrocarbon group having 1 to 5 carbon atoms, and u represents an integer of 1 to 8.

3. The thermosetting resin composition according to claim 1 , wherein the structural unit represented by the general formula (I) is a structural unit represented by the following formula (I′):

4. The thermosetting resin composition according to claim 2 , wherein A 1 in the general formula (Z) is a group represented by any of the following formulae:

5. The thermosetting resin composition according to claim 1 , wherein the phosphorus flame retardant (C) is at least one selected from an aromatic phosphate, and a metal salt of a disubstituted phosphinic acid.

6. The thermosetting resin composition according to claim 5 , wherein the aromatic phosphate is represented by the following general formula (C-1) or (C-2), and the metal salt of a disubstituted phosphinic acid is represented by the following general formula (C-3):

wherein R C1 to R C5 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, A c represents an alkylene group having 1 to 5 carbon atoms, an alkylidene group having 2 to 5 carbon atoms, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group, or a single bond, e and f each independently represent an integer of 0 to 5, g, h and i each independently represent an integer of 0 to 4,
R C6 and R C7 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or an aromatic hydrocarbon group having 6 to 14 carbon atoms, M represents a lithium atom, a sodium atom, a potassium atom, a calcium atom, a magnesium atom, an aluminum atom, a titanium atom or a zinc atom, and m1 represents an integer of 1 to 4.

7. The thermosetting resin composition according to claim 1 , wherein the maleimide compound as the component (B) is a polymaleimide compound (a) having at least two N-substituted maleimide groups in one molecule, or a polyaminobismaleimide compound (c) represented by the following general formula (VI):

wherein A 4 has the same definition as that of A 1 in the general formula (Z), and A 5 represents a group represented by the following general formula (VII):

wherein R 17 and R 18 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, a hydroxyl group or a halogen atom, A 8 represents an alkylene group having 1 to 5 carbon atoms, an alkylidene group having 2 to 5 carbon atoms, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group, a fluorenylene group, a single bond, or a group represented by the following general formula (VII-1) or (VII-2), and q′ and r′ each independently represent an integer of 0 to 4:

wherein R 19 and R 20 each independently represent an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, A 9 represents an alkylene group having 1 to 5 carbon atoms, an isopropylidene group, an m-phenylenediisopropylidene group, a p-phenylenediisopropylidene group, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group or a single bond, and s′ and t′ each independently represent an integer of 0 to 4:

wherein R 21 represents an aliphatic hydrocarbon group having 1 to 5 carbon atoms, or a halogen atom, A 10 and A 11 each independently represent an alkylene group having 1 to 5 carbon atoms, an isopropylidene group, an ether group, a sulfide group, a sulfonyl group, a carbonyloxy group, a keto group, or a single bond, and w represents an integer of 0 to 4.

8. The thermosetting resin composition according to claim 1 , wherein the content ratio of the component (A) to the component (B) [(A)/(B)] is from 5/95 to 80/20 by mass.

9. The thermosetting resin composition according to claim 1 , further comprising an inorganic filler (D).

10. The thermosetting resin composition according to claim 1 , further comprising a curing accelerator (E).

11. The thermosetting resin composition ac

Assignees

• Hitachi Chemical Co Ltd
• Showa Denko Materials Co Ltd

Inventors

• Tanigawa Takao
• Mizuno Yasuyuki
• Fukuda Tomio
• Nagai Yuki
• Murai Hikari

Classifications

• C08L71/126

  modified by chemical after-treatment · CPC title

• C08J2479/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2471/12

  Polyphenylene oxides · CPC title

• C08J2379/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08J2371/12

  Polyphenylene oxides · CPC title