Method of making waterproof magnesium oxychloride refractory brick by fly ash from municipal solid waste incineration

Patent metadata

Field	Value
Publication number	US-11279655-B2
Application number	US-201916448780-A
Country	US
Kind code	B2
Filing date	Jun 21, 2019
Priority date	Jun 21, 2019
Publication date	Mar 22, 2022
Grant date	Mar 22, 2022

Abstract

The invention discloses a method of making waterproof magnesium oxychloride refractory brick using fly ash from municipal solid waste incineration (MSWFA). The solidification and stabilization of heavy metals in MSWFA is achieved by the chemical action of a sulfur-containing compound and a physical wrapping of a geopolymer. The large amount of chloride ions in MSWFA is also reused in the manufacture of magnesium oxychloride refractory brick, which requires a high chlorine environment. This method, with the inclusion of the geopolymer, also produces refractory brick exhibiting improved water resistance relative to traditional magnesium oxychloride refractory brick, thereby allowing the improved magnesium oxychloride refractory brick to be used in a wider range of applications.

First claim

The invention claimed is:

1. A method of making waterproof magnesium oxychloride refractory brick using fly ash from municipal solid waste incineration comprising the steps of:
(1) mixing a sulfur-containing compound and water with the fly ash to form a slurry and stirring the slurry to obtain a stabilized slurry in which heavy metals are stabilized and CaO is converted to Ca(OH) 2 , wherein the sulfur-containing compound is selected from the group consisting of inorganic sulfides, organic sulfides, and mixtures thereof;
(2) adding MgO and an aqueous solution of MgCl 2 into the stabilized slurry and stirring to obtain a magnesium oxychloride slurry;
(3) curing the magnesium oxychloride slurry to obtain a magnesium oxychloride gel;
(4) crushing the magnesium oxychloride gel to obtain a magnesium oxychloride aggregate;
(5) preparing a blended slurry by mixing a metastable material, an alkali metal hydroxide, Na 2 SiO 3 , water, and the magnesium oxychloride aggregate;
(6) shaping and curing the blended slurry to obtain a waterproof magnesium oxychloride refractory brick.

2. The method according to claim 1 , wherein the sulfur-containing compound is Na 2 S.

3. The method according to claim 1 , wherein the added amount of the sulfur-containing compound is 6%˜9% of fly ash dry mass; and the added amount of the water is 40%-50% of fly ash dry mass.

4. The method according to claim 1 , wherein in step (1) the mixing is conducted at a temperature of 40-50° C. and continued for a period of 15-30 minutes.

5. The method according to claim 1 ,
wherein in step (2), the added amount of MgO is 35%-45% of fly ash dry mass;
wherein the added amount of MgCl 2 in the aqueous solution of the MgCl 2 is 13%-16% of fly ash dry mass, and
further wherein the added amount of water is 45%-55% of fly ash dry mass.

6. The method according to claim 1 , wherein in step (2), the stirring is conducted at a temperature of 40-50° C.; and continued for a period of 5-10 minutes.

7. The method according to claim 1 , wherein in step (3), the curing is conducted by placing the magnesium oxychloride slurry in a mold and maintaining the mold in a ventilated enclosure and protected from rain dry conditions, at a curing temperature of 20-25° C.

8. The method according to claim 7 , wherein in step (3), the time of curing in mold is 2-4 days, and the time of the mold-opening curing is 3-5 days after curing in mold.

9. The method according to claim 1 , wherein in step (4), the magnesium oxychloride gel is crushed to a particle size of less than 4 mesh (particle size<4.75 mm).

10. The method according to claim 1 , wherein in step (5), the mass ratio of the magnesium oxychloride aggregate, metastable material, alkali metal hydroxide, Na 2 SiO 3 , and the water is within a range of 100:(40-55):5:1.5:(25-35).

11. The method according to claim 1 , wherein in step (5), the alkali metal hydroxides are selected from the group consisting of NaOH, KOH, and mixtures thereof; and the metastable material is selected from the group consisting of grade 1 fly ash, grade 2 fly ash, blast furnace slag, metakaolin, and mixtures thereof.

12. The method according to claim 1 , wherein in step (5), the particle size of the metastable material is less than 75 μm; and a mixing duration is 5 to 10 minutes.

13. The method according to claim 1 , wherein in step (6), the curing in mold is in the condition of 70-80° C. and <20% relative humidity; the time of curing in mold is 1 day; the mold-opening curing is in the condition of 50-60° C. and <20% relative humidity; and the time of mold-opening curing is 6-8 days.

Assignees

• Univ Tsinghua

Inventors

• Li Jinhui
• Li Yang
• Tan Quanyin

Classifications

• C04B33/1352

  Fuel ashes, e.g. fly ash · CPC title

• C04B2235/9669

  Resistance against chemicals, e.g. against molten glass or molten salts · CPC title

• C04B2235/94

  Products characterised by their shape · CPC title

• C04B2235/72

  Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics · CPC title

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title