Carbon composite, electrode and lithium air battery comprising the carbon composite, and method of preparing the carbon composite

Patent metadata

Field	Value
Publication number	US-11133544-B2
Application number	US-201816106977-A
Country	US
Kind code	B2
Filing date	Aug 21, 2018
Priority date	Aug 25, 2017
Publication date	Sep 28, 2021
Grant date	Sep 28, 2021

Abstract

A carbon composite includes: a carbonaceous core; and a polymer electrolyte membrane disposed on the carbonaceous core, the polymer electrolyte membrane including: a first ionic liquid, a first polymer layer disposed on the carbonaceous core and having a first ionic charge, and a second polymer layer disposed on the first polymer layer and having a second ionic charge opposite to the first charge of the first polymer layer.

First claim

What is claimed is:

1. A carbon composite comprising:
a carbonaceous core; and
a polymer electrolyte membrane disposed on the carbonaceous core, the polymer electrolyte membrane comprising
a first ionic liquid,
a first polymer layer disposed on the carbonaceous core and comprising a polymer having a backbone with a first ionic charge, and
a second polymer layer disposed on the first polymer layer and comprising a polymer having a backbone with a second ionic charge, which is opposite to the first ionic charge of the backbone of the first polymer layer,
wherein the carbonaceous core comprises a carbonaceous nanostructure comprising a first pore having an aspect ratio of about 5 or greater.

2. The carbon composite of claim 1 , wherein the first pore has a diameter of about 0.5 nanometer to about 3 nanometers.

3. The carbon composite of claim 1 , wherein the carbonaceous core is non-spherical and is substantially sulfur free.

4. The carbon composite of claim 1 , wherein the carbon composite further comprises a second ionic liquid disposed on the carbonaceous core.

5. The carbon composite of claim 4 , wherein the second ionic liquid is between the carbonaceous core and the first polymer layer.

6. The carbon composite of claim 1 , wherein the polymer electrolyte membrane has a thickness of about 0.5 nanometer to about 1,000 nanometers.

7. The carbon composite of claim 1 , wherein the polymer electrolyte membrane comprises a polymer bilayer comprising the first polymer layer and the second polymer layer in contact with each other, and the polymer bilayer has a thickness of about 0.5 nanometer to about 5 nanometers.

8. The carbon composite of claim 7 , wherein the polymer electrolyte membrane comprises a plurality of polymer bilayers.

9. The carbon composite of claim 7 , wherein the number of polymer bilayers in the plurality of polymer bilayers is linearly proportional to an amount of the polymer electrolyte membrane in the carbon composite.

10. The carbon composite of claim 1 , wherein an amount of the polymer electrolyte membrane is about 0.1 part to about 100 parts by weight with respect to 100 parts by weight of the carbonaceous core.

11. The carbon composite of claim 1 , wherein the polymer electrolyte membrane comprises a polymer which is electrochemically stable in a voltage range of about 1 volt to about 4.5 volts with respect to lithium metal and is substantially inert to lithium peroxide.

12. The carbon composite of claim 1 , wherein the polymer electrolyte membrane comprises a polymer comprising a cationic polymeric ionic liquid, an anionic polymeric ionic liquid, a zwitterionic polymeric ionic liquid, a fluorine polymer, or a combination thereof.

13. An electrode comprising:
a porous layer comprising a plurality of carbon composites, a carbon composite of the plurality of carbon composites comprising
a carbonaceous core; and
a polymer electrolyte membrane disposed on the carbonaceous core, the polymer electrolyte membrane comprising
a first ionic liquid,
a first polymer layer disposed on the carbonaceous core and comprising a polymer having a backbone with a first ionic charge, and
a second polymer layer disposed on the first polymer layer and comprising a polymer having a backbone with a second ionic charge, which is opposite to the first ionic charge of the backbone of the first polymer layer,
wherein the carbonaceous core comprises a carbonaceous nanostructure comprising a first pore having an aspect ratio of about 5 or greater.

14. The electrode of claim 13 , wherein the porous layer has a bimodal pore structure comprising a first pore and a second pore, wherein the first pore and the second pore have different sizes.

15. The electrode of claim 13 , wherein the porous layer comprises a first pore present in the carbonaceous core and a second pore present between the plurality of carbon composites.

16. The electrode of claim 15 , wherein the first pore has a diameter smaller than a diameter of the second pore.

17. The electrode of claim 15 , wherein the first pore has a diameter of about 0.5 nanometer to about 2 nanometers, and the second pores have a diameter of about 5 nanometers to about 90 micrometers.

18. The electrode of claim 15 , wherein the first pore has an aspect ratio of about 5 or greater.

19. The electrode of claim 15 , wherein the first pore has a regular shape and the second pore has an irregular shape.

20. The electrode of claim 15 , wherein a shape of the second pore is defined by a first carbon composite arranged in a first direction parallel to a length of the carbonaceous core, a second carbon composite arranged in a second direction different from the first direction and in contact with the first carbon composite, a third carbon composite arranged in a third direction different from the second direction and in contact with the second carbon composite, and a fourth carbon composite arranged in a fourth direction different from the third direction and in contact with the first carbon composite and the third carbon composite.

21. The electrode of claim 15 , wherein the porous layer comprises a plurality of the second pore arranged in a non-periodical and disordered manner.

22. The electrode of claim 13 , wherein the porous layer has a porosity of about 10% to about 90%.

23. The electrode of claim 13 , wherein the plurality of carbon composites of the porous layer have a weight per unit area of about 0.1 milligram per square centimeter to about 20 milligrams per square centimeter.

24. The electrode of claim 13 , wherein the carbonaceous core of the porous layer has a weight per unit area of about 0.1 milligram per square centimeter to about 10 milligrams per square centimeter.

25. The electrode of claim 13 , wherein the polymer electrolyte membrane of the porous layer has a weight per unit area of about 0.01 milligram per square centimeter to about 10 milligrams per square centimeter.

26. The electrode of claim 13 , wherein the porous layer has a thickness of about 10 micrometers or greater.

27. The electrode of claim 13 , wherein a content of the first ionic liquid is about 100 parts by weight to about 200 parts by weight with respect to 100 parts by weight of the carbonaceous core.

28. The electrode of claim 13 , further comprising a porous substrate supporting the porous layer, the porous substrate having a regular structure and a greater mechanical strength than the porous layer.

29. The electrode of claim 13 , wherein the electrode is a cathode and oxygen is used as a cathode active material.

30. A lithium-air battery comprising:
a cathode; and
a lithium-containing anode,
wherein the cathode comprises
a porous layer comprising a plurality of carbon composites, a carbon composite of the plurality of carbon composites comprising
a carbonaceous core; and
a polymer electrolyte membrane disposed on the carbonaceous core, the polymer electrolyte membrane comprising
a first ionic liquid,
a first polymer layer disposed on the carbonaceous core and comprising a polymer having a backbone with a first ionic charge, and
a second polymer layer disposed on the first polymer layer and comprising a polymer having a backbone with a second ionic charge, which is opposite to the first ionic charge of the backbone of the first polymer layer,
wherein the carbonaceous core comprises

Assignees

• Samsung Electronics Co Ltd

Inventors

• Lee Hyunpyo
• Lee Dongjoon
• Kim Mokwon
• Kwon Hyukjae
• Kim Hyunjin
• Lee Heungchan
• Im Dongmin

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M8/1053

  consisting of layers of polymers with at least one layer being ionically conductive · CPC title

• H01M12/02 Primary

  Details (of electrodes H01M4/00; of non-active parts H01M50/00) · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title