Electrolyte for lithium air battery and lithium air battery including the same

Patent metadata

Field	Value
Publication number	US-9680191-B2
Application number	US-201213616774-A
Country	US
Kind code	B2
Filing date	Sep 14, 2012
Priority date	Oct 27, 2011
Publication date	Jun 13, 2017
Grant date	Jun 13, 2017

Abstract

A lithium air battery including an electrolyte including lithium ion conductive polymers and lithium salts between a positive electrode and a lithium ion conductive solid electrolyte membrane. The lithium ion conductive polymers are hydrophilic matrix polymers.

First claim

What is claimed is:

1. A lithium air battery comprising:
a negative electrode;
a lithium ion conductive solid electrolyte membrane; and
a positive electrode using oxygen as a positive electrode active material,
wherein a first electrolyte comprising lithium ion conductive polymers having a weight average molecular weight greater than 2000 grams per mole, compounds represented by Formula 1 below, and lithium salts are included between the lithium ion conductive solid electrolyte membrane and the positive electrode:

wherein R 1 and R 6 each independently represents a hydrogen atom, a nitro group, an amino group, a halogen atom, a cyano group, a carboxyl group, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C3-C20 heteroaryl group, or a substituted or unsubstituted C3-C20 carbocyclic group,
R 2 through R 5 each independently represents a hydrogen atom, a nitro group, an amino group, a hydroxy group, a halogen atom, a cyano group, a carboxyl group, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C2-C20 alkoxy carbonyl group, a substituted or unsubstituted C6-C30 aryl, a substituted or unsubstituted C3-C20 carbocylic group, a substituted or unsubstituted C3-C30 heteroaryl group, a substituted or unsubstituted C2-C20 alkylcarbonyl group, a substituted or unsubstituted C7-C30 arylcarbonyl group, or a substituted or unsubstituted C4-C30 heteroarylcarbonyl group, and
n is in a range of 1 to 20, wherein the amount of the lithium ion conductive polymers is in a range of about 1 to about 90 parts by weight based on 100 parts by weight of the compounds of Formula 1 in the electrolyte; and the lithium ion conductive polymer is one or more polymers selected from the group consisting of polypropylene oxide, polyethylene oxide, polyethylene oxide/polypropylene oxide copolymer.

2. The lithium air battery of claim 1 , wherein each of the compounds of Formula 1 comprises:
R 1 and R 6 that are each a hydrogen atom or an alkyl group of C1-C10;
R 2 through R 5 that are each a hydrogen atom or an alkyl group of C1-C10; and
n is in a range of 1 to 8.

3. The lithium air battery of claim 1 , wherein the compounds of Formula 1 are tetraglyme (CH 3 O—(CH 2 CH 2 O) 4 —CH 3 ).

4. The lithium air battery of claim 1 , wherein the first electrolyte further comprises one or more solvents selected from the group consisting of an aprotic solvent and water.

5. The lithium air battery of claim 1 , wherein the amount of the lithium salts is in a range of about 0.1 to about 70 parts by weight based on 100 parts by weight of the total weight of the compounds of Formula 1 and the lithium ion conductive polymers.

6. The lithium air battery of claim 1 , wherein the lithium ion conductive solid electrolyte membrane is disposed between the negative electrode and the positive electrode or formed on one surface of the negative electrode.

7. The lithium air battery of claim 1 , wherein a part of the first electrolyte is impregnated in the positive electrode.

8. The lithium air battery of claim 1 , wherein the lithium ion conductive solid electrolyte membrane comprises one or more selected from the group consisting of an inorganic material and a solid polymer electrolyte component.

9. The lithium air battery of claim 1 , wherein the lithium ion conductive solid electrolyte membrane is a glass-ceramic solid electrolyte or a stack structure of the glass-ceramic solid electrolyte and a solid polymer electrolyte.

10. The lithium air battery of claim 1 , wherein a second electrolyte may be further disposed between the negative electrode and the lithium ion conductive solid electrolyte membrane.

11. The lithium air battery of claim 10 , wherein the second electrolyte is a liquid electrolyte comprising a non-aqueous solvent and lithium salts, an inorganic solid electrolyte membrane, a solid polymer electrolyte membrane, or a combination thereof.

12. The lithium air battery of claim 1 , wherein a separator is further disposed between the lithium ion conductive solid electrolyte membrane and the positive electrode.

13. The lithium air battery of claim 1 , wherein the positive electrode comprises a porous carbon material.

14. The lithium air battery of claim 1 , wherein the first electrolyte is a product obtained by mixing the lithium ion conductive polymers, the compounds of Formula 1, and the lithium salts at a temperature within a range of about 40 to about 80° C.

15. An electrolyte for a lithium air battery, the electrolyte comprising lithium ion conductive polymers having a weight average molecular weight greater than 2000 grams per mole, compounds represented by Formula 1 below and lithium salts:

wherein R 1 and R 6 each independently represents a hydrogen atom, a nitro group, an amino group, a halogen atom, a cyano group, a carboxyl group, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C3-C20 heteroaryl group, or a substituted or unsubstituted C3-C20 carbocyclic group,
R 2 through R 5 each independently represents a hydrogen atom, a nitro group, an amino group, a hydroxy group, a halogen atom, a cyano group, a carboxyl group, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C2-C20 alkoxy carbonyl group, a substituted or unsubstituted C6-C30 aryl, a substituted or unsubstituted C3-C20 carbocylic group, a substituted or unsubstituted C3-C30 heteroaryl group, a substituted or unsubstituted C2-C20 alkylcarbonyl group, a substituted or unsubstituted C7-C30 arylcarbonyl group, or a substituted or unsubstituted C4-C30 heteroarylcarbonyl group, and
n is in a range of 1 to 20; wherein the amount of the lithium ion conductive polymers is in a range of about 1 to about 90 parts by weight based on 100 parts by weight of the compounds of Formula 1 in the electrolyte; and the lithium ion conductive polymer is one or more polymers selected from the group consisting of polypropylene oxide, polyethylene oxide, polyethylene oxide/polypropylene oxide copolymer.

16. The electrolyte for the lithium air battery of claim 15 , wherein the compounds of Formula 1 are tetraglyme (CH 3 O—(CH 2 CH 2 O) 4 —CH 3 ).

17. A lithium air battery, wherein the battery comprises the electrolyte of claim 15 .

Assignees

• Lee Dong-Joon
• Roev Victor
• Ryu Young-Gyoon
• Im Dong-Min
• Park Min-Sik
• Ma Sang-Bok
• Yamamoto Osamu
• Imanishi Nobuyuki
• Takeda Yasuo
• Samsung Electronics Co Ltd
• Nat Univ Corp Mie Univ

Inventors

• Lee Dong-Joon
• Roev Victor
• Ryu Young-Gyoon
• Im Dong-Min
• Park Min-Sik
• Ma Sang-Bok
• Yamamoto Osamu
• Imanishi Nobuyuki
• Takeda Yasuo

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/366

  as layered products · CPC title

• H01M12/06 Primary

  with one metallic and one gaseous electrode · CPC title

• H01M4/364

  as mixtures · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title