Reduction gas extraction from saturated top gas

Patent metadata

Field	Value
Publication number	US-11078549-B2
Application number	US-201816644418-A
Country	US
Kind code	B2
Filing date	Aug 23, 2018
Priority date	Sep 6, 2017
Publication date	Aug 3, 2021
Grant date	Aug 3, 2021

Abstract

The invention relates to a method for reducing metal oxides to metallized material by means of contact with reduction gas, wherein an accumulated top gas is dry dedusted and reformed in a raw gas mixture together with gaseous hydrocarbons. The water vapor content of the dry dedusted top gas designated for the preparation of the raw gas mixture is adjusted in a saturator in the countercurrent by means of saturation water, wherein the temperature of the saturation water is adjusted, by mixing cold water with a hot water having a higher temperature than the cold water, in order to produce the saturation water at a target value. The invention further relates to a device for carrying out such a method, having corresponding conduits.

First claim

The invention claimed is:

1. A process for reducing metal oxides to metallized material by contact with hot reduction gas, thereby producing a top gas, comprising:
dry dedusting the top gas;
guiding a first portion of the dry-dedusted top gas intended for preparation of a crude gas mixture in a bypass past a saturator;
adjusting a temperature of saturation water, by mixing cold water with hot water having a higher temperature than the cold water, to a target value;
adjusting a water vapor content of a second portion of the dry-dedusted top gas intended for preparation of the crude gas mixture in the saturator in countercurrent with the saturation water;
combining subsequently the first portion of the dry-dedusted top gas and the second portion of the dry-dedusted top gas to form a third portion of the dry-dedusted top gas; and
catalytic reforming of the crude gas mixture to obtain the reduction gas, the crude gas mixture being formed at least based on gaseous hydrocarbons and at least the third portion of the dry-dedusted top gas;
wherein a second target value for the water vapor content of the second portion of the dry-dedusted top gas is 10-20% by volume.

2. The process as claimed in claim 1 , wherein the gaseous hydrocarbons comprise natural gas.

3. The process as claimed in claim 1 , wherein the cold water and the hot water are mixed under closed-loop control based on:
at least one of a measurement of the temperature of the saturation water and a measurement of a temperature of the second portion of the dry-dedusted top gas; and
At least one of a third target value set for a temperature of the second portion of the dry-dedusted top gas and the target value set for the temperature of the saturation water.

4. The process as claimed in claim 1 , wherein at least some of the hot water is saturator wastewater removed from the saturator.

5. The process as claimed in claim 1 , wherein the top gas is desulfurized at least one of during and after the dry dedusting.

6. The process as claimed in claim 1 , wherein the dry dedusting is preceded by reducing a temperature of the top gas.

7. The process as claimed in claim 1 , wherein a fourth portion of the dry-dedusted top gas is sent to a reformer for catalytic reforming as a fuel gas component.

8. The process as claimed in claim 7 , wherein the fourth portion of the dry-dedusted top gas is sent to the reformer after desulfurization.

9. The process as claimed in claim 1 , wherein the dry-dedusted top gas has a water vapor content less than 30%.

10. The process as claimed in claim 1 , wherein the target value for the temperature of the saturation water is in a range of 323 K to 373 K.

11. The process as claimed in claim 10 , wherein the target value for the temperature of the saturation water is in a range of 338 K to 363 K.

12. The process as claimed in claim 10 , wherein the adjusting of the water vapor content of the second portion of the dry-dedusted top gas is performed at 1 bar g .

13. The process as claimed in claim 10 , wherein the adjusting of the water vapor content of the second portion of the dry-dedusted top gas is performed at 2 bar g .

14. The process as claimed in claim 1 , further comprising desulfurizing at least a proportion of the dry-dedusted top gas using zinc oxide.

15. The process as claimed in claim 14 , wherein the zinc oxide used in the desulfurizing operation is in a range of 473 K to 723 K.

16. The process as claimed in claim 15 , wherein the zinc oxide used in the desulfurizing operation is in a further range of 623 K to 723 K.

17. The process as claimed in claim 14 , wherein a temperature of the top gas is reduced prior to dedusting such that a further temperature of the dry dedusted top gas subjected to desulfurization is in a range of 473 K to 533 K.

18. The process as claimed in claim 6 , wherein the temperature of the top gas is reduced to a range of 423 K to 533 K prior to the dry dedusting operation.

Assignees

• Primetals Technologies Austria GmbH

Inventors

• Steinwandter Andreas
• Millner Robert
• Ofner Hanspeter

Classifications

• C21B13/0073 Primary

  Selection or treatment of the reducing gases · CPC title

• Y02P10/122

  by capturing or storing CO2 · CPC title

• C21B13/0033 Primary

  In fluidised bed furnaces or apparatus containing a dispersion of the material · CPC title

• C21B2100/22

  by reforming · CPC title

• C21B2100/44

  Removing particles, e.g. by scrubbing, dedusting · CPC title