Process for conversion of natural gas to liquid hydrocarbons and a plant for carrying out the process

Patent metadata

Field	Value
Publication number	US-9683176-B2
Application number	US-201514885550-A
Country	US
Kind code	B2
Filing date	Oct 16, 2015
Priority date	Oct 16, 2015
Publication date	Jun 20, 2017
Grant date	Jun 20, 2017

Abstract

Process and plant for conversion of a feed hydrocarbon stream to liquid hydrocarbon products in a small scale GTL plant, comprising the use of a cryogenic air separation unit (ASU), optionally together with vacuum pressure swing adsorption (VPSA), an autothermal reformer (ATR) or catalytic partial oxidation (CPO), and pressure swing adsorption (PSA) unit to produce a synthesis gas for downstream Fischer-Tropsch (FT) synthesis for production of liquid hydrocarbons.

First claim

The invention claimed is:

1. A process for the conversion of a gas and/or liquid feed hydrocarbon stream into liquid hydrocarbons comprising:
(a) providing oxygen with purity of at least 80% vol. by using a cryogenic air separation unit (ASU);
(b) mixing steam to the feed hydrocarbon stream to form a hydrocarbon-steam stream;
(c1) adding the oxygen of step (a) and the hydrocarbon-steam stream of step (b) to an autothermal reformer (ATR), or catalytic partial oxidation (CPO) unit, or
(c2) combining the oxygen of step (a) with the resulting stream of step (b) and then adding to an autothermal reformer (ATR), catalytic partial oxidation (CPO) unit;

(d) withdrawing from the ATR or CPO a raw synthesis gas which is first dewatered and then split into a first and second raw synthesis gas stream, passing the second raw synthesis gas stream through a pressure swing adsorption (PSA) unit without any water-gas-shift pre-treatment, withdrawing a hydrogen-rich stream and a PSA-off gas stream from the PSA unit;
(e) converting the first raw synthesis gas stream from step (d) into liquid hydrocarbons through Fischer-Tropsch synthesis;
(f) recycling tail gas from the Fischer-Tropsch synthesis to the feed hydrocarbon stream prior to step (b), to step (b), to step (c1), to step (c2), or combinations thereof.

2. A process according to claim 1 , wherein, prior to step (b), the feed hydrocarbon stream is subjected to a desulphurization step.

3. A process according to claim 1 , wherein the hydrocarbon-steam stream is pre-reformed in one or more pre-reformers.

4. A process according to claim 1 , wherein step (a) further comprises using Vacuum Pressure Swing Adsorption (VPSA).

5. A process according to claim 1 , wherein the hydrogen-rich stream of step (d) is used in: hydroprocessing units downstream, desulphurization step, or both.

6. Process according to claim 1 , wherein the feed hydrocarbon stream is natural gas, associated gas, or combinations thereof.

7. Process according to claim 1 , wherein steam is added to the oxygen of step (a).

8. Process according to claim 3 , wherein the first raw synthesis gas stream represents the major portion of raw synthesis gas.

Assignees

• Haldor Topsoe As

Inventors

• Christensen Thomas Sandahl

Classifications

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title

• C01B3/382

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C10G2/30 Primary

  from carbon monoxide with hydrogen · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title

• Y02P10/143

  of methane [CH4] · CPC title