Method for producing direct reduced iron with limited CO2 emissions
US-8940076-B2 · Jan 27, 2015 · US
US9638468B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9638468-B2 |
| Application number | US-201214350928-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 16, 2012 |
| Priority date | Nov 17, 2011 |
| Publication date | May 2, 2017 |
| Grant date | May 2, 2017 |
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A direct reduced iron manufacturing system includes a gas reformer for supplying steam to reform natural gas, a gas heater being a heating unit for heating a reformed gas reformed by the gas reformer to a predetermined temperature, a direct reduction furnace for reducing iron ore directly into reduced iron using a high-temperature reducing gas, an acid gas removal unit having an acid gas component absorber and a regenerator for releasing the acid gas, and a recovery gas introduction line for supplying a recovery gas released from the regenerator to each of a reforming furnace of the gas reformer and a furnace of the gas heater.
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The invention claimed is: 1. A direct reduced iron manufacturing system comprising: a gas reformer for reforming natural gas; a heating unit for heating a reformed gas reformed by the gas reformer to a predetermined temperature at which the reformed gas is supplied to a reduction furnace to form a reducing gas; a direct reduction furnace for reducing iron ore directly into reduced iron using a high-temperature reducing gas comprising hydrogen and carbon monoxide; an acid gas removal unit including an acid gas component absorber for removing, with an acid gas absorbent, an acid gas component in a reduction furnace flue gas discharged from the direct reduction furnace, and a regenerator for releasing the acid gas component as a recovery gas; and a recovery gas introduction line for supplying the recovery gas released from the regenerator, the recovery gas comprising carbon dioxide and hydrogen sulfide, to a reforming furnace of the gas reformer and a furnace of the heating unit, or only the reforming furnace, wherein the acid gas component absorber includes a first outlet for releasing purified gas comprising H 2 and CO, and a second outlet for releasing the rich solvent comprising absorbent which has absorbed CO 2 and H 2 S in the acid gas component absorber, and the regenerator includes a first outlet for releasing the recovery gas to the recovery gas introduction line, a second outlet for supplying a lean solvent to the acid gas component absorber, and an inlet for receiving a rich solvent from the acid gas component absorber. 2. The direct reduced iron manufacturing system according to claim 1 , further comprising a degradation product removal unit for separating and removing a degradation product in the acid gas absorbent. 3. The direct reduced iron manufacturing system according to claim 1 , further comprising: a bypass circuit for bypassing a part of a lean solvent to be returned from the regenerator to the absorber; and a filter interposed in the bypass circuit. 4. The direct reduced iron manufacturing system according to claim 1 , further comprising: an introduction line for introducing the reduction furnace flue gas into the acid gas removal unit; a heat exchanger, interposed on the introduction line, for heat exchanging the reduction furnace flue gas; a bag filter provided upstream of the heat exchanger; and a scrubber provided downstream of the heat exchanger. 5. A direct reduced iron manufacturing system comprising: a heating unit for heating coal gasification gas or coke oven gas to a predetermined temperature at which the coal gasification gas or the coke oven gas is supplied to a reduction furnace to form a reducing gas; a direct reduction furnace for reducing iron ore directly into reduced iron using a high-temperature reducing gas comprising hydrogen and carbon monoxide; an acid gas removal unit including an acid gas component absorber for removing, with an acid gas absorbent, an acid gas component in a reduction furnace flue gas discharged from the direct reduction furnace, and a regenerator for releasing the acid gas component as a recovery gas; and a recovery gas introduction line for supplying the recovery gas released from the regenerator, the recovery gas comprising carbon dioxide and hydrogen sulfide to the furnace of the heating unit, wherein the acid gas component absorber includes a first outlet for releasing purified gas comprising H 2 and CO, and a second outlet for releasing rich solvent comprising absorbent which has absorbed CO 2 and H 2 S in the acid gas component absorber, and the regenerator includes a first outlet for releasing the recovery gas to the recovery gas introduction line, a second outlet for supplying a lean solvent to the acid gas component absorber, and an inlet for receiving a rich solvent from the acid gas component absorber. 6. The direct reduced iron manufacturing system according to claim 5 , further comprising a degradation product removal unit for separating and removing a degradation product in the acid gas absorbent. 7. The direct reduced iron manufacturing system according to claim 5 , further comprising: a bypass circuit for bypassing a part of a lean solvent to be returned from the regenerator to the absorber; and a filter interposed in the bypass circuit. 8. The direct reduced iron manufacturing system according to claim 5 , further comprising: an introduction line for introducing the reduction furnace flue gas into the acid gas removal unit; a heat exchanger, interposed on the introduction line, for heat exchanging the reduction furnace flue gas; a bag filter provided upstream of the heat exchanger; and a scrubber provided downstream of the heat exchanger.
by capturing or storing CO2 · CPC title
Recovery of products · CPC title
Amines · CPC title
from metallurgy plants · CPC title
Carbon monoxide · CPC title
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