Method and apparatus for production of direct reduced iron (DRI) utilizing coke oven gas

Patent metadata

Field	Value
Publication number	US-9725778-B2
Application number	US-201214368258-A
Country	US
Kind code	B2
Filing date	Dec 21, 2012
Priority date	Dec 21, 2011
Publication date	Aug 8, 2017
Grant date	Aug 8, 2017

Abstract

Direct reduction process and plant for producing DRI comprising a reduction reactor and at least one reducing gas heater typically comprising a convective heating section and a radiant heating section for raising the reducing gas temperature to a level adequate for iron oxides reduction to metallic iron, typically above 850° C., wherein the reducing gas fed to the reduction reactor comprises a stream of reducing gas recycled from the reduction reactor and a make-up stream of coke oven gas containing carbon compounds which may form carbon deposits in the heating path of said heater, namely BTX and other complex carbon compounds. The heater is provided with means for feeding oxidizing agents, for example steam, steam and air and/or oxygen at predetermined heating tubes successively for eliminating the carbon deposits which may form inside the heating tubes of said heater without interrupting the operation of the plant. The make-up stream of cold COG can be combined with the recycled gas at a point in the gas heating path of the heater where the tubes have a skin wall temperature of at least 700° C., or when the mixture of recycled gas and COG is at a temperature above 700° C. for minimizing clogging or fouling of heating equipment.

First claim

What is claimed is:

1. A direct reduction process for producing DRI comprising a reduction reactor and at least one gas heater comprising heating tubes forming a heating path for raising the reducing gas temperature to a level adequate for iron oxides reduction to metallic iron, wherein said reducing gas fed to the reduction reactor comprises a first stream of reducing gas comprising hydrogen and carbon monoxide and a second stream of coke oven gas (COG) containing carbon compounds which may form carbon deposits in the heating path of said heater, said direct reduction process being characterized by feeding said first stream of said reducing gas to said heater; mixing said first stream of gas with said second stream comprising coke oven gas at a point in the heating path of said heater where the skin temperature of the tubes of said heater is above 700° C., forming a third gas stream; heating said third gas stream to a temperature above 850° C.; and feeding said hot third stream to the reduction reactor.

2. Direct reduction process according to claim 1 , being further characterized by heating said first stream of said reducing gas to a temperature above 850° C.;
mixing said hot first stream of gas with said second stream comprising coke oven gas at a regulated flow rate so that the resulting mixture forms said third gas stream at a temperature above 700° C.

3. Direct reduction process according to claim 1 , being further characterized by said heater having a convective section and a radiant section, and heating a combined stream of reducing gas and COG in said radiant section and utilizing the heat of the flue gases from said radiant section to produce steam or to preheat whatever other fluid in the convective section of said heater.

4. Direct reduction process according to claim 3 , being further characterized by preheating said first stream of reducing gas in heating tubes located in the convective section of said heater; preheating said second stream of COG in heat exchangers located in the convective section of said heater or located externally of said heater, by means of other heating media different than the flue gases; mixing said preheated first gas stream and said preheated second gas stream to form a third gas stream, heating said third stream to a temperature above 850° C. in the radiant section of the heater and feeding said third gas stream to the reduction reactor.

5. Direct reduction process for producing DRI according to claim 1 , being further characterized by said first stream being recycled off-gas from said reduction reactor.

6. Direct reduction process for producing DRI according to claim 2 , further characterized by heating said third stream to a temperature in the range between 850° C. to 1100° C.

7. Direct reduction process for producing DRI comprising a reduction reactor and at least one gas heater comprising heating tubes forming a heating path for raising the reducing gas temperature to a level adequate for iron oxides reduction to metallic iron, wherein said reducing gas fed to the reduction reactor comprises a first stream of reducing gas comprising hydrogen and carbon monoxide and a second stream of coke oven gas (COG) containing carbon compounds which may form carbon deposits in the heating path of said heater, said direct reduction process characterized by on-line removal of said carbon deposits in the heating path of said COG by injecting steam, or steam and/or air; or steam and/or air and/or oxygen, into the heater tubes for cleaning any carbon deposits that may form in said tubes, thus minimizing the fouling or clogging problems of the heater as a result of heating said gas comprising COG containing BTX and other complex carbon compounds.

8. Direct reduction process for producing DRI according to claim 7 , further characterized by scheduling the feeding of the steam and/or air; or steam and/or air and/or oxygen successively to each tube or group of tubes so that the operation of the reduction process and the heater is not interrupted and so that the overall gas composition of the reducing gas fed to the reduction reactor is suitable for the production of DRI even after the addition of the oxidizing agents to the heater tubes under cleaning of carbon deposits.

9. Direct reduction process according to claim 7 , being further characterized by heating said first stream of said reducing gas to a temperature above 850° C.; mixing said hot first stream of gas with said second stream comprising coke oven gas at a regulated flow rate so that the resulting mixture forms said third gas stream at a temperature above 700° C.

10. Direct reduction process according to claim 7 , being further characterized by said heater having a convective section and a radiant section, and heating a combined stream of reducing gas and COG in said radiant section and utilizing the heat of the flue gases from said radiant section to produce steam or to preheat whatever other fluid in the convective section of said heater.

11. Direct reduction process according to claim 10 , being further characterized by preheating said first stream of reducing gas in heating tubes located in the convective section of said heater; preheating said second stream of COG in heat exchangers located in the convective section of said heater or located externally of said heater, by means of other heating media different than the flue gases; mixing said preheated first gas stream and said preheated second gas stream to form a third gas stream, heating said third stream to a temperature above 850° C. in the radiant section of the heater and feeding said third gas stream to the reduction reactor.

12. Direct reduction process for producing DRI according to claim 7 , being further characterized by said first stream being recycled off-gas from said reduction reactor.

13. Direct reduction process for producing DRI according to claim 9 , further characterized by heating said third stream to a temperature in the range between 850° C. to 1100° C.

Assignees

• Hyl Tech S A De C V
• Danieli Off Mecc

Inventors

• Martinis Alessandro
• Becerra-Novoa Jorge-Octavio
• Condosta Michele
• Zendejas-Martinez Eugenio

Classifications

• C21B13/0073 Primary

  Selection or treatment of the reducing gases · CPC title

• C10G75/00

  Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general (C10G7/10, C10G9/16 take precedence) · CPC title

• Y02P10/265

  Cross-Sectional Technologies · mapped topic

• C01B2203/025

  containing a partial oxidation step · CPC title

• Y02P10/283

  Cross-Sectional Technologies · mapped topic