Method and system for producing high-carbon DRI using syngas

Patent metadata

Field	Value
Publication number	US-10927424-B2
Application number	US-201616063604-A
Country	US
Kind code	B2
Filing date	Dec 21, 2016
Priority date	Dec 28, 2015
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

Producing direct reduced iron (DRI) having chemically-combined carbon includes providing DRI at a temperature above 400° C., providing a first gas stream including hydrogen and carbon monoxide, passing the first gas stream through a methane forming process to yield a second gas stream containing a higher concentration of methane than the first gas stream; and contacting the second gas stream with the DRI. A system for producing the DRI includes a vessel for containing DRI at a temperature above 400° C., a methane forming reactor containing a catalyst bed for producing methane from a first gas stream containing hydrogen and carbon monoxide, a first conduit to feed a gas stream including hydrogen and carbon monoxide to the methane forming reactor, and a second conduit to feed the second gas stream to the vessel containing the DRI.

First claim

What is claimed is:

1. A process for producing direct reduced iron (DRI) having chemically-combined carbon in a direct reduction reactor for the production of said DRI, said direct reduction reactor having at least a reduction zone, a lower zone, and a transition zone between said reduction zone and said lower zone, the process comprising:
providing a first portion of a first gas stream comprising hydrogen and carbon monoxide to said reduction zone, said first gas stream being a syngas with less than 5 vol % methane, to produce said DRI in said reduction zone;
providing said DRI at a temperature above 400° C. to said transition zone, said lower zone, or both;
passing a second portion of said first gas stream through a methane-forming reactor where methane is produced from said hydrogen and carbon monoxide resulting in a second gas stream containing a higher concentration of methane than said first gas stream; and
contacting said second gas stream with said DRI in said transition zone, said lower discharge zone, or both to increase the carbon content of said DRI in said transition zone, said lower zone, or both, respectively.

2. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said first gas stream contains hydrogen, carbon monoxide and carbon dioxide and wherein the ratio of H 2 /(CO+CO 2 ) in the gas fed to the methane forming reactor is in the range between 2.5 and 3.5.

3. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said second gas stream contains at least 20% by volume of methane.

4. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said methane forming process is performed isothermically.

5. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said methane forming process is performed adiabatically.

6. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said methane forming process comprises a combination of isothermic and adiabatic methane forming processes.

7. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said first gas stream fed to the methane forming process is syngas derived from gasification of hydrocarbons.

8. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 7 , wherein said first gas stream of syngas is reacted with H 2 O to increase its content of H 2 and CO 2 in a catalytic water gas shift reactor prior to being fed to said methane forming process.

9. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 8 , wherein the syngas from said catalytic water gas shift reactor is treated in a CO 2 removal unit.

10. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 9 , wherein said CO 2 removal unit is of the chemical absorption type.

11. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 9 , wherein said CO 2 removal unit is of the physical adsorption type or gas separation membranes.

12. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said first gas stream containing hydrogen and carbon monoxide is syngas from a coal gasifier.

13. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said first gas stream containing hydrogen and carbon monoxide is a combination of syngas from a coal gasifier and recycled upgraded reducing gas effluent from a direct reduction reactor.

14. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said second gas stream is fed to the transition zone of the direct reduction reactor.

15. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said second gas stream is fed to a lower zone of a direct reduction reactor.

16. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein a cooling gas stream is circulated through said lower zone of the direct reduction reactor and said second gas stream is fed to the cooling gas circuit comprising said lower zone of the direct reduction reactor.

17. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said DRI contains 2% by weight or more of combined carbon.

18. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said DRI contains from 2% by weight to 4.5% by weight of combined carbon.

19. A process for producing DRI having a controlled amount of chemically-combined carbon, according to claim 1 , wherein said second gas stream is treated to remove water before contacting said DRI.

20. A system for producing direct reduced iron (DRI) having chemically-combined carbon, the system comprising:
a direct reduction reactor for the production of said DRI having at least a reduction zone, a lower zone, and a transition zone between the reduction zone and the lower zone, said transition zone, said lower zone, or both containing DRI at a temperature above 400° C.;
a methane forming reactor containing a catalyst bed for producing methane from a first portion of first gas stream containing hydrogen and carbon monoxide resulting in a second gas stream having a higher content of methane than said first gas stream;
a first conduit to feed the first portion of the first gas stream to said methane forming reactor;
a second conduit to feed said second gas stream to said transition zone, said lower zone, or both; and
a third conduit to feed a second portion of the first gas stream to the direct reduction reactor for the production of said DRI.

21. A system for producing DRI according to claim 20 , further comprising a water removal unit fluidly connected with said methane forming reactor and with said transition zone, said lower zone, or both.

22. A system for producing DRI according to claim 21 , further comprising a source of syngas containing less than 10% methane as source of said first gas stream.

23. A system for producing DRI according to claim 22 , wherein said source of syngas is a coal gasifier.

24. A system for producing DRI according to claim 22 , wherein said source is a coal gasifier comprising a gas cleaning system to lower the sulfur content of the gas stream.

25. A system for producing DRI according to claim 21 , further comprising a conduit to feed at least a portion of said methane containing second gas stream from said water removal unit to said transition zone.

26. A system for producing DRI according to claim 21 , further comprising a conduit to feed at least a portion of said methane containing second gas stream from said water removal unit to said lower zone.

Assignees

• Hyl Tech S A De C V
• Danieli Off Mecc

Inventors

• Zendejas-Martinez Eugenio

Classifications

• C21B13/0073 Primary

  Selection or treatment of the reducing gases · CPC title

• Y02P10/122

  by capturing or storing CO2 · CPC title

• C07C9/04

  Methane (production by treatment of sewage C02F11/04; natural gas, synthetic natural gas C10L3/06) · CPC title

• Y02P10/143

  of methane [CH4] · CPC title

• C21B2100/24

  by shift reactions · CPC title