System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-10857744-B2
Application number	US-201816172037-A
Country	US
Kind code	B2
Filing date	Oct 26, 2018
Priority date	Apr 3, 2018
Publication date	Dec 8, 2020
Grant date	Dec 8, 2020

Abstract

A thermoplastic prepreg includes a web or mesh of fibers in which the web or mesh of fibers includes chopped fibers. The thermoplastic prepreg also includes a thermoplastic material that fully impregnates the web or mesh of fibers so that the thermoplastic prepreg has a void content of less than 5%. The thermoplastic material is polymers that are formed by in-situ polymerization of monomers or oligomers in which greater than 90% of the monomers or oligomers react to form the thermoplastic material. The thermoplastic prepreg includes between 5 and 95 weight percent of the thermoplastic material and the chopped fibers that form the web or mesh of fibers are un-bonded.

First claim

What is claimed is:

1. A method of forming a thermoplastic prepreg comprising:
moving a fiber mesh atop a lower belt of a double belt press mechanism;
drying the fiber mesh via a drying mechanism that is positioned atop the lower belt to remove residual moisture from the fiber mesh;
applying monomers or oligomers to the fiber mesh via a resin application die that is positioned atop the lower belt;
passing the fiber mesh and the applied monomers or oligomers between the lower belt and an upper belt of the double belt press mechanism to press the monomers or oligomers through the fiber mesh and thereby fully saturate the fiber mesh with the monomers or oligomers; and
passing the fully saturated fiber mesh through a curing oven that is configured to fully polymerize the monomers or oligomers as the coated fiber mesh is moved through the curing oven and thereby form the thermoplastic prepreg; wherein:
the fiber mesh includes chopped fibers;
the fiber mesh is fully impregnated with the thermoplastic polymer upon polymerization of the monomers or oligomers; and
the fiber mesh is in substantially constant movement atop the lower belt between the drying mechanism and the curing oven.

2. The method of claim 1 , further comprising mixing the monomers or oligomers with at least one of a catalyst or an activator to form a reactive resin mixture, the catalyst and activator facilitating in polymerizing the monomers or oligomers to form the thermoplastic polymer.

3. The method of claim 1 , further comprising applying a moisture-free gas onto the fiber mesh after application of the monomers or oligomers to substantially prevent exposure of the monomers or oligomers to ambient moisture in the surrounding environment.

4. The method of claim 1 , wherein the top belt of the double belt mechanism is fully enclosed within the curing oven.

5. The method of claim 1 , further comprising cutting fiber strands or rovings via a fiber chopper positioned above the lower belt to form the chopped fibers, the fiber chopper being positioned so that as the fibers strands or rovings are cut, the chopped fibers fall atop the lower belt and form the fiber mesh.

6. The method of claim 1 , further comprising passing the thermoplastic prepreg through a cooling mechanism after polymerization of the monomers or oligomers.

7. The method of claim 5 , wherein the fiber chopper is a first fiber chopper and the chopped fibers are first chopped fibers, and wherein the method further comprises cutting second fiber strands or rovings via a second fiber chopper positioned above the lower belt to form second chopped fibers, the second fiber chopper being positioned so that as the second fibers strands or rovings are cut, the second chopped fibers fall atop the first chopped fibers and form a layered or hybrid fiber mesh.

8. The method of claim 5 , further comprising drying the fiber strands or rovings via a second drying mechanism as the fiber strands or rovings are unwound from one or more spools and before the fiber strands or rovings are cut to form the chopped fibers.

9. The method of claim 5 , further comprising unwinding a fabric or nonwoven mat from a roller and moving the fabric or nonwoven mat atop the lower belt so that the chopped fibers are positioned above or below the fabric or nonwoven mat and form a layered or hybrid fiber mesh comprising the chopped fibers and the fabric or nonwoven mat, wherein the layered or hybrid fiber mesh is subjected to the drying mechanism, the resin application die, the double belt mechanism, and the curing oven such that the monomers or oligomers fully saturate the layered or hybrid fiber mesh and the thermoplastic polymer fully impregnates the layered or hybrid fiber mesh upon polymerization of the monomers or oligomers.

10. The method of claim 1 , further comprising applying a sizing composition to fibers of the fiber mesh, the sizing composition having a coupling agent that promotes bonding between the fibers and the thermoplastic polymer.

11. The method of claim 1 , wherein the fiber mesh includes glass fibers, carbon fibers, basalt fibers, metal fibers, ceramic fiber, natural fibers, synthetic organic fibers, aramid fibers, inorganic fibers, or combinations thereof.

12. The method of claim 1 , further comprising winding the thermoplastic prepreg into a roll product.

13. The method of claim 1 , further comprising cutting the thermoplastic prepreg into sheets.

14. The method of claim 1 , wherein the monomers or oligomers comprises lactams, lactones, cyclic butylene terephthalate (CBT), methyl methacrylate, precursors of thermoplastic polyurethane, or mixtures thereof.

15. The method of claim 14 , wherein the lactams comprise caprolactam, laurolactam, or mixtures thereof.

16. The method of claim 1 , further comprising scattering or dispersing pre-cut chopped fibers via a fiber scattering device positioned above the lower belt to form the chopped fibers.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Sandoval Christopher
• Asrar Jawed

Classifications

• C08J5/248

  using pre-treated fibres · CPC title

• C08J5/0405

  with inorganic fibres · CPC title

• B05D3/0218

  Pretreatment, e.g. heating the substrate · CPC title

• B29C70/504 Primary

  using rollers or pressure bands (for corrugating B29C53/22) · CPC title

• B29B15/14

  of filaments or wires · CPC title