System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-9993945-B2
Application number	US-201514794634-A
Country	US
Kind code	B2
Filing date	Jul 8, 2015
Priority date	Nov 22, 2013
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

According to one embodiment, a system for manufacturing a fully impregnated thermoplastic prepreg includes a mechanism for moving a fabric or mat and a drying mechanism that removes residual moisture from at least one surface of the fabric or mat. The system also includes a resin application mechanism that applies a reactive resin to the fabric or mat and a press mechanism that presses the coated fabric or mat to ensure that the resin fully saturates the fabric or mat. The system further includes a curing oven through which the coated fabric or mat is moved to polymerize the resin and thereby form a thermoplastic polymer so that upon exiting the oven, the fabric or mat is fully impregnated with the thermoplastic polymer. During at least a portion of the process, humidity in the vicinity of the coated fabric or mat is maintained at substantially zero.

First claim

What is claimed is:

1. A system for manufacturing a fully impregnated thermoplastic prepreg in a continuous process, the system comprising:
a mechanism for moving a fabric or mat from a starting point to an ending point, the fabric or mat being subjected to a plurality of processes between the starting point and the ending point and the fabric or mat being in substantially constant movement between the starting point and ending point;
a fabric or mat drying mechanism that is configured to remove residual moisture from the fabric or mat as the fabric or mat is moved past the drying mechanism;
a mixing component that mixes a liquid or molten lactam with a catalyst and an activator, wherein the catalyst and activator facilitate in polymerizing the lactam to form a thermoplastic polymer;
a resin application die that is positioned atop the fabric or mat and that is configured to apply the lactam to the fabric or mat as the fabric or mat is passed under the resin application die;
a gas application mechanism that is positioned to blow a moisture-free gas onto one or more surfaces of the fabric or mat between the resin application die and a curing oven in order to substantially prevent exposure of the lactam to ambient moisture in a surrounding environment;
a press mechanism that is configured to press the lactam through the fabric or mat as the fabric or mat is moved past or through the press mechanism such that the lactam fully saturates the fabric or mat; and
the curing oven having a temperature of greater than 120 degrees Celsius, the curing oven being configured to effect polymerization of the lactam to form the thermoplastic polymer as the fabric or mat is moved through the curing oven such that the fabric or mat is fully impregnated with the thermoplastic polymer;
wherein the mixing component and resin application die are heated to maintain a temperature of the lactam to between 70 and 120 degrees Celsius prior to passing the fabric or mat through the curing oven wherein the resin application die is positioned above a bottom belt of the press mechanism so that the lactam is applied to the fabric or mat as the fabric or mat is passed under the resin application die and atop the bottom belt.

2. The system of claim 1 , wherein a distal end of the resin application die is positioned within 1 inch of an inlet of the curing oven.

3. The system of claim 2 , further comprising a first holding tank and a second holding tank that is separate from the first holding tank, wherein the first holding tank comprises a first mixture that includes the lactam and the catalyst and wherein the second holding tank comprises a second mixture that includes the lactam and the activator, wherein the first holding tank and the second holding tank are heated to maintain a temperature of the lactam to between 70 and 120 degrees Celsius.

4. The system of claim 3 , wherein the first mixture and the second mixture are mixed in the mixing component.

5. The system of claim 1 , wherein the lactam comprises caprolactam, laurolactam, or a mixture of caprolactam and laurolactam.

6. The system of claim 1 , wherein the gas application mechanism blows nitrogen gas onto one or more surfaces of the moving fabric or mat.

7. The system of claim 1 , further comprising a winding mechanism that is configured to wind the fully impregnated fabric or mat into a roll product after the fully impregnated fabric or mat exits the curing oven.

8. The system of claim 1 , wherein the press mechanism is a double belt compression press that sandwiches the fabric or mat between two belts.

9. The system of claim 1 , wherein the lactam has a viscosity of 10 centipoises or less.

10. The system of claim 1 , wherein the fabric or mat includes multiple layers of woven materials, and wherein each layer of woven material is fully impregnated with the thermoplastic polymer.

11. A system for manufacturing a prepreg comprising:
a mechanism for moving a fabric or mat along the system;
a drying mechanism that removes residual moisture from the fabric or mat;
a resin application mechanism that applies a liquid or molten resin to the fabric or mat;
a gas application mechanism that is separate from the resin application mechanism and that blows a moisture-free gas onto one or more surfaces of the fabric or mat to maintain a moisture free environment in the vicinity of the fabric or mat prior to subjecting the fabric or mat to a curing oven in order to substantially prevent exposure of the resin to ambient moisture in a surrounding environment, wherein the gas application mechanism is positioned such that the moisture-free gas is blown onto the fabric or mat between the resin application mechanism and the curing oven;
a press mechanism that presses the fabric or mat subsequent to application of the resin to ensure that the resin fully saturates the fabric or mat; and
the curing oven through which the fabric or mat is moved to polymerize the resin and thereby form a thermoplastic polymer so that upon exiting the curing oven, the fabric or mat is fully impregnated with the thermoplastic polymer wherein the resin application mechanism is positioned above a bottom belt of the press mechanism so that the liquid or molten resin is applied to the fabric or mat when the fabric or mat is positioned atop the bottom belt.

12. The system of claim 11 , further comprising a mixing mechanism that mixes the resin with a catalyst and an activator prior to application of the resin to the fabric or mat.

13. The system of claim 12 , further comprising a first holding tank and a second holding tank that is separate from the first holding tank, the first holding tank comprising a mixture of the resin and the catalyst and the second holding tank comprising a mixture of the resin and the activator.

14. The system of claim 11 , further comprising a winding mechanism that winds the fully impregnated fabric or mat into a roll product after the fully impregnated fabric or mat exits the curing oven.

15. The system of claim 11 , wherein the resin comprises caprolactam.

16. The system of claim 11 , wherein the fabric or mat includes multiple layers of woven materials, and wherein each layer of woven material is fully impregnated with the thermoplastic polymer.

17. A system for manufacturing a fully impregnated thermoplastic prepreg in a continuous process, the system comprising:
a mechanism for moving a fabric or mat from a starting point to an ending point, the fabric or mat being subjected to a plurality of processes between the starting point and the ending point and the fabric or mat being in substantially constant movement between the starting point and ending point;
a fabric or mat drying mechanism that is configured to remove residual moisture from the fabric or mat as the fabric or mat is moved past the drying mechanism;
a mixing component that mixes a liquid or molten lactam with a catalyst and an activator, wherein the catalyst and activator facilitate in polymerizing the lactam to form a thermoplastic polymer;
a resin application die that is positioned atop the fabric or mat and that is configured to apply the lactam to the fabric or mat as the fabric or mat is passed under the resin application die;
a gas application mechanism that is separate from the resin application die and that applies a moisture-free gas onto one or more surfaces of the fabric or mat to maintain a moisture free environment in the vicinity of the fabric or mat prior to subjecting the fabric or mat to a curing oven in order to substantially prevent exposure of the lactam to ambient moisture in a

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Gleich Klaus Friedrich
• Yohannes Asheber
• Block Michael John
• Asrar Jawed
• Bristol Derek Cooper
• Sandoval Christopher P

Classifications

• B29K2033/12

  Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate · CPC title

• D06M15/61

  Polyamines {polyimines} · CPC title

• B29B15/14

  of filaments or wires · CPC title

• B05C9/10

  the auxiliary operation being performed before the application (B05C9/14 takes precedence) · CPC title

• B29K2105/0872

  Prepregs · CPC title