System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-9815954-B2
Application number	US-201514880307-A
Country	US
Kind code	B2
Filing date	Oct 12, 2015
Priority date	Nov 22, 2013
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

Fiber-containing polymethyl methacrylate (PMMA) prepregs are described that include a first and second plurality of fibers. The second plurality of fibers is made from a different material than the first plurality of fibers. The PMMA prepregs also contain a polymerized resin that includes polymethyl methacrylate that has been formed from a reactive resin composition that includes methyl methacrylate. Methods of making fiber-containing PMMA prepregs are also described.

First claim

What is claimed is:

1. A method of making a fiber-containing polymethyl methacrylate prepreg, the method comprising:
forming a stack of fiber mats in contact with a reactive resin composition comprising methyl methacrylate monomers, wherein the stack of fiber mats comprises layers of a first fiber mat and a second fiber mat stacked on top of each other, and wherein the first fiber mat comprises a first plurality of fibers, and the second fiber mat comprises a second plurality of fibers made of a different material than the first plurality of fibers; and
curing the reactive resin composition in the stack of fiber mats to form the fiber-containing polymethyl methacrylate prepreg, wherein the curing comprises pressing and heating the stack of fiber mats such that the reactive resin composition is heated to a polymerization temperature for the reactive resin composition.

2. The method of claim 1 , wherein the first plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

3. The method of claim 1 , wherein the second plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

4. The method of claim 1 , wherein the first plurality of fibers comprises glass fibers and the second plurality of fibers comprises carbon fibers.

5. The method of claim 1 , wherein at least one of the first plurality of fibers and the second plurality of fibers are reactive fibers that have a reactive agent present on the surface of the fibers, wherein the reactive agent comprises:
a silane coupling moiety, and
a reactive acrylate or methacrylate moiety.

6. The method of claim 1 , wherein the reactive resin composition further comprises an initiator.

7. The method of claim 1 , wherein the initiator further comprises an organic peroxide.

8. A method of making a fiber-containing polymethyl methacrylate prepreg, the method comprising:
forming one or more layers of fiber mat in contact with a reactive resin composition comprising methyl methacrylate monomers, wherein the one or more layers of fiber mat comprise a first plurality of fibers and a second plurality of fibers made of a different material than the first plurality of fibers; and
curing the reactive resin composition in the one or more layers of the fiber mat to form the fiber-containing polymethyl methacrylate prepreg, wherein the curing comprises pressing and heating the one or more layers of the fiber mats such that the reactive resin composition is heated to a polymerization temperature for the reactive resin composition.

9. The method of claim 8 , wherein the first plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

10. The method of claim 8 , wherein the second plurality of fibers comprises fibers selected from the group consisting of glass fibers, inorganic fibers, carbon fibers, metal fibers, organic polymer fibers, and mineral fibers.

11. The method of claim 8 , wherein the first plurality of fibers comprises glass fibers and the second plurality of fibers comprises carbon fibers.

12. The method of claim 8 , wherein at least one of the first plurality of fibers and the second plurality of fibers are reactive fibers that have a reactive agent present on the surface of the fibers, wherein the reactive agent comprises:
a silane coupling moiety, and
a reactive acrylate or methacrylate moiety.

13. The method of claim 8 , wherein the reactive resin composition further comprises an initiator.

14. The method of claim 13 , wherein the initiator comprises an organic peroxide.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Gleich Klaus Friedrich
• Yohannes Asheber
• Block Michael John
• Asrar Jawed
• Bristol Derek Cooper
• Sandoval Christopher P

Classifications

• C08J5/24 Primary

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title

• C08J2333/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08J5/06

  using pretreated fibrous materials · CPC title

• C08J5/047 Primary

  with mixed fibrous material · CPC title

• C08J2377/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2377/10 takes precedence) · CPC title